File name: Pandora179s1_CornwallCT_20230509_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20260624T054435.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20230509_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20230509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230509T105853.7Z 8529.457566 224 1 48.77 2 76.85 78.35 80.24 215.95 0.00 1 0.00 1 0 17 5.235e-01 1.739e-02 2.179e-01 4.463e-03 6.631988e-01 2.393405e-03 7.407953e-03 -6.000000e+00 3.027890e-01 230.23 -2.00 3.52 -2.00 320.73 0.00e+00 3.048015e-03 9.811377e-04 9.543060e-04 -6.000000e+00 1.344408e-02 279.69 -2.00 20.00 -2.00 320.17 0.00e+00 4.286 0.001 302.00 328.00 3 3.8510e+00 7.4519e-03 5.4211e-02 -6.0000e+00 7.5726e-01 1.8463e-01 9.7509e-03 3.6806e-02 -6.0000e+00 8.2143e-01 -2.1212e-01 9.4879e-03 1.8170e-02 -6.0000e+00 4.8861e-01 8.4005e-02 4.6537e-03 7.0264e-03 -6.0000e+00 2.0667e-01 8.7719e-05 -7.1917e-04 1.2306e-04 6.5043e-05 -6.0000e+00 1.4489e-02 2.6596e-03 0.0000e+00 12 8 8 10 0 0 97.73 22.65 0.43 0.00266 -0.00274 23 6 1 5 0 2120.010 25.79 20.00 22.65 13.41 20.0 971.15 -133084 900000 -117115 900000 -81426 23146 -141626 -188970 -6263 210667 -216233 -35661 -137123 83972 900000 -27060 287779 -48503 726 27116 -27873 -49361 900000 -52149 109949 22572 -23035 -13365 -33260 -16798 6852 -15885 20947 188851 -4496 16309 -20818 8284 31683 38696 9120 7755 12384 -2505 6459 5720 6480 9204 10197 370 3337 24243 -575 11895 2752 18002 1595 2616 7033 8661 432 3109 9368 4492 1987 -2987 4359 -2633 2251 1824 4086 3471 1677 -2002 -4351 1104 606 -4170 145 -1507 -5866 -351 -1420 -3498 -968 240 -611 -405 1282 -3395 2252 -1322 1402 -307 298 -794 -1394 261 138 -116 -963 -377 -134 -286 -945 233 1492 -995 -1489 -181 690 -646 -252 -257 655 423 -144 486 -379 -228 -347 -413 845 1425 -139 3037 -244 1210 1184 -132 335 -40 241 -469 396 -121 344 231 44 -321 -112 -440 -1378 -1648 900000 -1646 900000 -736 101 -2322 -5564 -34 916 -10852 -322 -4221 365 900000 -552 1252 -1558 16 472 -867 -1899 900000 -2286 1116 536 -886 -456 -1347 -607 229 -803 855 1711 -254 726 -1442 502 1855 2551 922 859 1380 -334 795 723 830 1183 1355 58 558 3691 -123 2452 662 3873 417 677 1690 2000 111 844 2708 1540 691 -1075 1539 -948 842 788 1917 1720 841 -985 -2004 464 237 -1711 63 -732 -3492 -226 -1019 -2722 -731 191 -515 -351 1091 -2918 1827 -1036 1023 -233 250 -728 -1488 294 170 -144 -1131 -423 -137 -291 -1037 268 1781 -1221 -2007 -269 1061 -1066 -416 -408 973 640 -220 725 -604 -376 -568 -651 1264 2169 -206 4190 -336 1713 1886 -225 623 -75 473 -985 834 -268 774 528 99 -702 -241 -894 -2743 SS 20230509T110903.7Z 8529.464626 227 1 48.31 2 74.99 79.95 81.33 217.83 0.00 1 0.00 1 0 25 1.780e-01 5.345e-03 2.959e-02 1.030e-03 5.880548e-01 5.353277e-04 6.704487e-03 -6.000000e+00 1.028282e-01 230.23 -2.00 3.52 -2.00 320.12 0.00e+00 1.603067e-03 1.828126e-04 4.972321e-04 -6.000000e+00 4.448305e-03 279.69 -2.00 20.00 -2.00 319.52 0.00e+00 3.787 0.001 302.00 328.00 3 1.7234e+00 1.5731e-03 4.7606e-02 -6.0000e+00 2.5723e-01 4.9163e-02 1.9453e-03 3.1408e-02 -6.0000e+00 2.7907e-01 -3.4164e-02 1.7943e-03 1.5538e-02 -6.0000e+00 1.6566e-01 2.3521e-03 9.1604e-04 5.0223e-03 -6.0000e+00 6.9352e-02 1.2955e-03 -5.9019e-04 2.8265e-05 5.0922e-05 -6.0000e+00 4.8566e-03 2.9048e-03 0.0000e+00 10 0 0 10 0 0 88.29 22.65 0.31 0.00290 -0.00153 212 51 1 5 0 227.840 25.79 20.00 22.65 14.04 20.3 977.54 -76931 -35569 -65699 -48372 -72706 -57200 -71440 -64978 -36720 -39292 -57319 -33703 -36260 -28612 -8398 -14768 -18103 -19915 -7888 -7916 -5209 -9227 998 -7547 -4035 -2452 -11566 -8915 -12508 -6591 -3868 -2876 1716 3945 -1357 -3686 -4758 -3499 -1112 141 -1282 -1256 279 121 534 1792 -1770 1065 -456 -77 730 2177 943 2344 1236 2085 738 389 517 123 451 784 2203 2089 1281 -15 756 -147 550 1173 397 593 153 316 -710 -458 -516 -1294 -178 -857 -818 -1085 -1645 -1720 -832 -545 -244 39 807 630 642 801 93 459 554 267 487 821 83 -144 -10 -709 -267 16 -610 -1242 -655 -833 -353 168 115 6 -72 162 64 365 341 240 92 -352 -492 2 178 196 440 602 447 955 403 173 57 -276 -107 10 -277 -33 -29 366 -193 -138 38 -193 -244 -765 -282 -779 -486 -862 -557 -854 -829 -406 -493 -910 -460 -619 -575 -173 -392 -566 -700 -269 -287 -192 -356 36 -323 -182 -116 -620 -456 -642 -332 -218 -191 126 311 -110 -299 -422 -361 -137 21 -200 -212 49 22 97 329 -342 205 -92 -16 170 557 268 714 405 707 262 139 180 42 158 297 929 906 592 -7 333 -67 268 652 247 388 100 197 -410 -237 -246 -617 -92 -521 -579 -810 -1354 -1503 -769 -537 -234 38 790 596 609 705 79 389 517 266 556 992 110 -191 -12 -861 -296 18 -732 -1480 -816 -1109 -508 250 187 9 -116 265 99 531 498 366 150 -598 -833 3 280 296 677 887 636 1399 620 297 101 -517 -197 20 -576 -69 -61 783 -413 -284 79 -374 -460 SS 20230509T111901.3Z 8529.471543 230 1 48.48 2 73.16 81.52 82.45 219.64 0.00 1 0.00 1 0 17 1.045e-01 5.366e-03 2.165e-02 1.062e-03 5.311552e-01 5.479238e-04 6.111907e-03 -6.000000e+00 6.039019e-02 230.23 -2.00 3.52 -2.00 319.71 0.00e+00 1.697715e-03 1.624554e-04 3.542137e-04 -6.000000e+00 2.612455e-03 279.69 -2.00 20.00 -2.00 319.08 0.00e+00 3.399 0.001 302.00 328.00 3 2.2567e+00 1.5631e-03 4.2774e-02 -6.0000e+00 1.5107e-01 4.5166e-02 1.8608e-03 2.8135e-02 -6.0000e+00 1.6389e-01 -2.8448e-02 1.5779e-03 1.3869e-02 -6.0000e+00 9.7293e-02 1.4503e-03 8.2394e-04 4.4351e-03 -6.0000e+00 4.0730e-02 1.1478e-03 -6.7991e-04 2.9760e-05 4.4580e-05 -6.0000e+00 2.8522e-03 2.8822e-03 0.0000e+00 10 0 0 10 0 0 99.65 22.65 0.32 0.00288 -0.00223 152 36 1 5 0 318.900 25.79 20.00 22.65 15.08 20.3 983.13 -34055 -13742 -32277 -32823 -38503 -39132 -30808 -45962 -29800 -24753 -42869 -21659 -28579 -10920 -4337 -2846 -7729 -8153 -3631 344 -2073 -8859 3840 -6957 -1431 -1156 -3509 -6616 -5630 -5856 -403 -3185 1316 3016 -3365 -1690 -5825 -1529 -833 1533 -1602 -872 -440 -1428 485 798 -644 37 749 -935 1709 1477 586 1806 1006 1519 746 87 272 1010 433 953 1743 2001 991 -7 441 -411 1016 1009 735 451 304 58 -241 -299 -473 -1005 -401 -912 -1453 -928 -1944 -1569 -881 -685 -188 -11 543 294 631 711 470 611 691 217 528 680 168 -160 -243 -586 -253 86 -744 -958 -665 -669 -473 176 -5 -183 199 162 100 270 573 100 116 -283 -536 39 150 188 363 692 213 1254 598 184 92 -238 -18 -1 -261 -197 -19 258 -159 -226 91 -236 -172 -409 -161 -498 -510 -582 -567 -434 -852 -537 -467 -1012 -444 -752 -301 -138 -107 -343 -397 -183 18 -113 -521 205 -447 -94 -81 -258 -489 -396 -424 -31 -297 135 331 -384 -184 -712 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