File name: Pandora179s1_CornwallCT_20230615_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20260624T054819.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20230615_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20230615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230615T114122.8Z 8566.487069 171 1 48.39 2 66.09 79.39 43.64 106.62 0.00 1 0.00 1 0 17 2.101e-01 8.149e-03 9.787e-02 3.559e-03 4.001399e-01 1.825054e-03 4.639486e-03 -6.000000e+00 1.225309e-01 232.61 -2.00 3.52 -2.00 319.26 0.00e+00 5.954624e-04 4.608129e-04 4.772908e-04 -6.000000e+00 5.340444e-03 283.64 -2.00 20.00 -2.00 318.52 0.00e+00 2.450 0.000 302.00 328.00 3 3.8401e+00 5.1339e-03 3.1667e-02 -6.0000e+00 3.0791e-01 4.5136e-02 5.9861e-03 2.1429e-02 -6.0000e+00 3.3313e-01 1.2789e-02 4.5057e-03 1.0337e-02 -6.0000e+00 1.9783e-01 -1.3583e-02 2.3610e-03 3.0217e-03 -6.0000e+00 8.2792e-02 6.4396e-04 -2.6296e-04 1.0452e-04 3.0131e-05 -6.0000e+00 5.7366e-03 -2.0728e-03 0.0000e+00 11 8 0 10 0 0 100.00 22.78 0.29 -0.00207 -0.00405 105 25 2 5 0 460.800 26.00 19.99 22.78 18.17 21.3 972.58 -11078 215173 -34240 54691 -27553 64501 -3635 17157 18975 36524 -6920 8287 -3904 -14753 20194 -10308 18854 -8342 12467 6382 1777 5377 12546 -825 2962 8375 -10113 7991 -8209 6363 3181 -6123 6279 13215 1506 -1479 -4195 -4996 3295 -1105 -1137 -4076 -254 -2624 -1719 597 -5911 1535 -2696 849 -1059 4672 -2170 2719 -11 1095 395 -1374 2692 -1200 1801 -438 2129 912 693 -1341 547 -188 -372 2465 138 990 5 603 -408 -5 -289 1839 89 -167 -1928 -1420 -1371 -2487 -198 -160 -147 -57 628 157 482 536 653 1961 788 892 -297 674 47 405 -297 -842 673 -25 11 -700 118 -1248 -824 -65 140 81 -385 264 -533 829 -243 574 -91 -10 -793 -434 74 23 -78 1320 270 852 829 101 507 -552 -213 -217 -603 369 191 487 -47 27 -490 73 -360 -269 747 -1307 918 -883 840 -90 389 481 919 -255 272 -166 -835 960 -768 1148 -711 919 525 158 464 1028 -83 307 868 -1288 819 -934 622 348 -827 837 1761 218 -212 -663 -926 681 -285 -331 -1301 -81 -879 -572 196 -2063 494 -907 282 -382 1737 -930 1185 -5 525 196 -694 1278 -584 869 -232 1212 532 417 -784 318 -108 -229 1552 99 737 4 434 -276 -3 -172 1024 53 -114 -1419 -1165 -1217 -2351 -195 -168 -164 -65 719 175 495 505 570 1655 719 909 -344 869 66 559 -388 -1009 740 -28 13 -903 158 -1787 -1165 -98 227 136 -631 406 -820 1185 -349 852 -136 -16 -1270 -679 112 35 -115 1833 362 1151 1214 162 808 -924 -366 -390 -1153 735 390 1012 -98 54 -952 134 -649 SS 20230615T115616.3Z 8566.497411 182 1 18.49 2 63.36 81.66 41.03 109.91 0.00 1 0.00 1 0 17 2.202e-01 1.523e-02 1.051e-01 8.579e-03 3.754063e-01 4.392410e-03 4.386654e-03 -6.000000e+00 1.283758e-01 232.61 -2.00 3.52 -2.00 318.55 0.00e+00 -1.160392e-03 9.001160e-04 4.475325e-04 -6.000000e+00 5.595539e-03 283.64 -2.00 20.00 -2.00 317.79 0.00e+00 2.217 0.000 302.00 328.00 3 6.0885e+00 1.2042e-02 2.9082e-02 -6.0000e+00 3.2260e-01 1.0916e-01 1.3780e-02 1.9776e-02 -6.0000e+00 3.4906e-01 -1.5079e-02 9.4107e-03 9.6937e-03 -6.0000e+00 2.0729e-01 -8.1591e-04 4.8794e-03 2.7204e-03 -6.0000e+00 8.6720e-02 8.5093e-05 -1.2308e-04 2.4876e-04 2.8552e-05 -6.0000e+00 6.0119e-03 -1.9022e-04 0.0000e+00 12 9 9 12 9 1 99.99 22.79 0.03 -0.00019 -0.00112 6 4 1 5 0 2616.500 26.00 19.97 22.79 19.04 21.5 978.54 4765 232941 -41178 33817 -5762 -10554 12980 -32237 30072 31055 -18434 22223 -25191 -16120 1582 -2835 27678 15333 1260 6026 4235 18370 21580 -9144 11985 15199 -8124 -2932 -9927 -5489 4350 -8705 17777 21663 3327 -547 -8111 605 3428 2221 -4924 1024 -2191 -1767 -1686 -3602 -5110 -293 149 -4575 770 5206 -118 4325 1611 3985 -1440 -55 3794 127 -1199 209 747 3755 94 -3731 -464 -3274 -593 -1418 1648 2082 1696 -1707 -2163 -1249 -13 380 364 -1916 -3885 -39 -2548 -1170 -1578 2279 -386 1289 1762 -1447 2611 -1940 1773 1794 1688 965 163 1362 951 -694 381 119 -210 -1049 -319 648 494 -1062 -1458 -635 1010 793 -645 -265 355 -566 -135 68 -498 -295 -216 -343 -70 490 -722 2855 -1988 1665 1206 301 -874 -340 -336 -509 -1721 1074 -91 1387 -7 -245 778 -493 -429 184 1949 -2830 1153 -263 -475 485 -1984 1219 1359 -1352 1116 -2123 -1455 140 -298 2494 1530 153 727 537 2175 2528 -1448 1654 2144 -1471 -482 -1631 -911 700 -1644 3066 3820 628 -111 -1769 141 938 734 -1960 408 -932 -759 -722 -1572 -2242 -121 61 -1988 337 2367 -60 2264 907 2255 -882 -33 2156 73 -717 132 479 2530 67 -2616 -315 -2250 -393 -1073 1336 1765 1445 -1445 -1707 -877 -9 243 244 -1391 -3269 -36 -2548 -1213 -1642 2442 -447 1515 2064 -1687 2890 -2060 1675 1654 1657 1063 190 1752 1314 -966 493 141 -248 -1271 -388 826 659 -1512 -2207 -966 1613 1301 -1044 -402 525 -795 -187 99 -770 -454 -335 -523 -109 731 -1033 3758 -2618 2138 1680 459 -1431 -540 -547 -867 -3146 2004 -175 2689 -13 -467 1402 -859 -729 SS 20230615T130809.8Z 8566.547335 238 1 40.72 2 50.00 93.31 29.51 130.75 0.00 1 0.00 1 0 17 9.030e-03 5.747e-03 5.706e-04 2.465e-04 2.493629e-01 1.267458e-04 2.987092e-03 -6.000000e+00 5.265469e-03 232.61 -2.00 3.52 -2.00 316.53 0.00e+00 2.235583e-04 1.488558e-05 4.267690e-05 -6.000000e+00 2.295084e-04 283.65 -2.00 20.00 -2.00 315.79 0.00e+00 1.553 0.000 302.00 328.00 3 1.2968e+00 3.3357e-04 1.9821e-02 -6.0000e+00 1.3232e-02 3.1582e-02 3.7241e-04 1.3042e-02 -6.0000e+00 1.4317e-02 -4.7822e-03 2.1587e-04 6.3316e-03 -6.0000e+00 8.5020e-03 -2.3241e-03 1.0074e-04 1.7318e-03 -6.0000e+00 3.5572e-03 2.4101e-02 -1.6200e-04 7.0718e-06 2.0112e-05 -6.0000e+00 2.4657e-04 -6.7292e-04 0.0000e+00 12 1 1 12 1 1 100.00 22.76 0.29 -0.00067 -0.00189 1530 415 1 5 0 26.410 26.00 20.01 22.76 22.24 21.9 998.13 -454 -460 -1010 -2183 -4239 -2776 -1720 -206 638 -433 -2115 -2052 -771 -1044 371 -46 -403 287 360 773 851 260 1053 1117 506 988 413 -304 -445 461 1405 1290 2173 496 -2106 -1700 -1614 -1382 -163 -376 -919 -839 -626 -769 -478 -119 -675 -462 -709 -184 768 691 850 1124 622 857 984 475 488 473 853 1168 1318 1389 326 -413 -119 -495 596 797 23 211 -75 267 0 -152 -115 -488 84 -399 -936 -1149 -1945 -1687 -936 -849 -469 -208 198 169 316 485 208 787 746 395 610 734 39 -259 -167 -694 -323 127 -512 -957 -647 -643 -311 250 126 74 73 116 32 424 412 230 260 -107 -412 41 150 224 674 615 460 1189 609 256 182 -215 -67 78 -49 -139 -68 219 -372 -192 -118 -441 -401 -72 -74 -170 -359 -697 -416 -262 -34 118 -87 -431 -417 -153 -237 95 -13 -122 89 116 256 289 88 357 397 191 386 164 -115 -157 155 485 479 865 210 -870 -668 -674 -607 -85 -213 -580 -556 -427 -531 -328 -81 -455 -302 -453 -116 501 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