File name: Pandora179s1_CornwallCT_20230727_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20260624T055137.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20230727_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20230727 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230727T144836.2Z 8608.617086 238 1 47.85 2 35.84 119.10 139.66 72.81 0.00 1 0.00 1 0 17 4.115e-02 2.010e-02 1.351e-02 6.637e-03 1.956461e-01 3.417124e-03 2.247309e-03 -6.000000e+00 2.396286e-02 232.23 -2.00 3.52 -2.00 316.31 0.00e+00 -1.027916e-03 3.819204e-04 4.443627e-05 -6.000000e+00 1.059487e-03 286.74 -2.00 20.00 -2.00 315.52 0.00e+00 1.233 0.000 302.00 328.00 3 7.4574e+00 8.9681e-03 1.5495e-02 -6.0000e+00 6.0096e-02 9.8676e-02 1.0003e-02 1.0028e-02 -6.0000e+00 6.5009e-02 -3.4632e-02 5.7448e-03 4.8266e-03 -6.0000e+00 3.8690e-02 8.3611e-03 2.6229e-03 1.5199e-03 -6.0000e+00 1.6249e-02 7.5217e-05 -6.4929e-04 1.9305e-04 1.6003e-05 -6.0000e+00 1.1236e-03 -1.7373e-04 0.0000e+00 12 9 8 11 8 0 99.99 22.76 1.34 -0.00017 -0.00505 29 7 1 5 0 1648.900 25.90 20.01 22.76 29.44 24.4 1003.07 -3335 5453 2473 -4870 -2259 -3985 11799 -12878 7772 5681 -14239 -8983 -14489 -2371 2353 1868 292 4017 -3658 6044 4078 1155 9996 -2698 10009 4251 2797 -3484 2133 -8865 7891 -4992 3439 16010 -165 2665 -8608 2552 -927 8736 -4244 2332 -2151 -289 -6060 -1141 -3206 -1600 1871 -6073 2937 2944 275 952 -842 5838 790 1471 1270 2019 -1685 1591 -140 1694 -1181 -1409 -1650 -1483 -1109 251 2906 585 2148 -729 86 -1648 1332 -1888 127 -802 -4696 -239 -2822 -2911 -413 2619 110 2146 -1 -1659 2445 -1610 2000 -1222 1631 -1912 380 920 717 -659 671 -501 -496 -1204 -671 1509 -386 187 -1944 -124 879 604 -289 -158 15 -1078 317 -214 -87 -906 2145 -1832 1801 1703 -1201 4976 -2526 1522 -425 1054 -221 -938 -1249 90 -2268 1692 531 -305 602 -344 182 -1042 196 -694 1140 547 -1103 -440 -722 1862 -2872 1579 1259 -3821 -2241 -4054 -653 689 599 98 1326 -1339 2058 1446 417 3315 -1060 3643 1700 1139 -1426 816 -3297 2724 -2065 1389 5915 -68 1008 -3849 1169 -483 4854 -2962 1593 -1572 -209 -4586 -814 -2276 -1074 1169 -4034 1837 1954 197 709 -658 4328 626 1156 979 1525 -1345 1301 -125 1575 -1130 -1246 -1329 -1136 -875 219 2721 589 2143 -726 79 -1399 1062 -1443 96 -678 -4255 -228 -2944 -3174 -468 3090 140 2782 -2 -2171 2844 -1770 2079 -1243 1666 -2035 436 1155 957 -881 831 -580 -543 -1361 -818 1909 -519 261 -2882 -190 1396 970 -448 -227 20 -1328 381 -268 -117 -1316 3114 -2747 2537 2300 -1578 6320 -3273 1881 -564 1352 -300 -1308 -1768 131 -3549 2674 872 -516 1016 -574 291 -1632 297 SS 20230727T151237.2Z 8608.633764 251 1 1.58 2 32.08 126.72 135.58 77.93 0.00 1 0.00 1 0 17 8.276e-03 6.353e-03 1.678e-03 1.225e-03 1.606544e-01 6.399248e-04 1.959538e-03 -6.000000e+00 4.819848e-03 232.23 -2.00 3.52 -2.00 314.58 0.00e+00 2.825759e-04 5.114341e-05 1.724905e-05 -6.000000e+00 2.131071e-04 286.74 -2.00 20.00 -2.00 313.97 0.00e+00 1.180 0.000 302.00 328.00 3 1.7997e+00 1.6500e-03 1.4046e-02 -6.0000e+00 1.2088e-02 1.8256e-02 1.8254e-03 8.4264e-03 -6.0000e+00 1.3076e-02 -3.9570e-03 1.0426e-03 4.0886e-03 -6.0000e+00 7.7822e-03 -1.9551e-03 4.4960e-04 1.1325e-03 -6.0000e+00 3.2680e-03 2.4766e-02 -2.6593e-04 3.4813e-05 1.5425e-05 -6.0000e+00 2.2602e-04 3.3665e-04 0.0000e+00 12 1 1 12 1 1 99.38 22.76 0.33 0.00034 -0.00166 17 147 1 5 0 78.300 26.00 19.98 22.76 29.81 24.4 1004.85 428 -548 -137 -1473 -3041 -1044 -753 1004 1203 1047 -1841 -1153 -475 -364 524 385 -573 388 645 858 1204 193 1006 1077 748 654 510 -176 -240 953 1700 1712 1995 537 -2698 -1612 -1850 -1352 -316 -530 -970 -960 -650 -1148 -290 -599 -751 -752 -615 -209 720 422 652 906 466 595 742 400 585 439 550 1323 1313 1103 500 -325 58 -773 677 701 219 181 -50 270 33 108 -146 -573 -54 -172 -1161 -1161 -1833 -1460 -892 -827 -323 -134 333 83 420 71 199 826 794 271 777 764 0 -304 -162 -542 -265 104 -543 -1046 -570 -641 -386 127 -9 78 -3 88 363 402 491 306 227 -172 -281 4 -138 427 632 734 439 1274 514 450 136 -153 -3 77 -34 -328 -210 244 -378 -282 56 -442 -442 151 -214 -55 -566 -1133 -349 -255 367 451 417 -744 -452 -197 -167 247 198 -307 209 355 483 690 111 572 593 431 390 305 -101 -134 499 894 945 1163 306 -1605 -901 -1097 -852 -219 -406 -775 -800 -553 -991 -247 -507 -621 -633 -497 -164 577 359 549 794 421 543 687 371 532 397 508 1220 1302 1099 499 -316 54 -686 613 673 221 192 -54 281 34 100 -129 -496 -47 -156 -1125 -1172 -1983 -1565 -1015 -965 -397 -163 406 103 501 77 205 840 834 296 885 913 0 -384 -192 -624 -303 116 -636 -1307 -708 -830 -519 171 -13 110 -4 115 447 484 585 381 290 -228 -384 5 -183 564 786 907 516 1474 630 557 176 -202 -4 102 -47 -464 -305 361 -544 -414 79 -610 -626 SS 20230727T151631.0Z 8608.636470 254 1 27.69 2 31.50 128.09 134.91 78.71 0.00 1 0.00 1 0 17 1.642e-02 1.017e-02 5.895e-03 3.726e-03 1.691248e-01 1.930792e-03 2.014621e-03 -6.000000e+00 9.563088e-03 232.23 -2.00 3.52 -2.00 315.26 0.00e+00 -1.555754e-04 1.756082e-04 4.550246e-05 -6.000000e+00 4.228354e-04 286.74 -2.00 20.00 -2.00 314.57 0.00e+00 1.172 0.000 302.00 328.00 3 6.5784e+00 5.0131e-03 1.4227e-02 -6.0000e+00 2.3983e-02 5.6289e-02 5.5722e-03 8.7572e-03 -6.0000e+00 2.5945e-02 -2.9881e-03 3.1727e-03 4.2456e-03 -6.0000e+00 1.5441e-02 -1.5206e-03 1.3976e-03 1.1741e-03 -6.0000e+00 6.4834e-03 2.0302e-04 -1.6192e-04 1.0607e-04 1.4860e-05 -6.0000e+00 4.4848e-04 1.1308e-03 0.0000e+00 12 9 9 12 41 1 99.99 22.76 -0.01 0.00113 -0.00009 6 3 1 5 0 3931.450 26.00 20.01 22.76 30.04 24.5 1007.12 -3531 -1757 -1771 -245 -4858 -161 -683 -4674 -2629 5385 -1246 -5092 -3683 -2653 3968 -943 2832 1928 903 1662 1094 611 3747 2418 2144 2527 499 -280 -864 -2504 1355 149 2384 4053 -331 -2034 -3640 -670 -1415 -1012 -2453 -178 126 806 -2664 -1040 -915 -775 -278 -1894 351 2115 358 1556 396 2418 1801 63 1188 -510 280 582 2033 1241 546 -2160 -308 -1423 -1259 851 1572 1970 -124 1122 -680 190 -1102 -1697 -777 -1280 -2019 -738 -1104 -2429 -436 -921 272 519 861 -121 1228 -43 -1294 -269 -30 367 23 1173 121 153 -133 -1045 -1435 -778 -527 -145 792 -10 -282 -2 1019 255 207 254 -776 216 -266 189 -660 110 284 -235 947 695 59 1317 442 764 733 363 -626 -625 -472 127 267 215 -33 77 -302 465 -199 -669 -950 -1016 -544 -561 -73 -1329 -41 -180 -1314 -807 1621 -396 -1645 -1247 -988 1541 -418 1249 870 422 792 535 297 1769 1203 1119 1358 256 -146 -416 -1159 611 71 1185 2046 -165 -977 -1883 -386 -910 -711 -1921 -142 103 657 -2231 -850 -728 -591 -203 -1376 256 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