File name: Pandora179s1_CornwallCT_20240310_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240311T050804.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240310_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240310 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240310T124923.1Z 8835.534295 86 1 33.92 2 73.27 111.19 76.98 109.78 0.00 1 0.00 1 0 17 5.113e-01 2.050e-02 2.138e-01 7.183e-03 6.344767e-01 3.770566e-03 7.175621e-03 -6.000000e+00 2.909956e-01 225.65 -2.00 3.52 -2.00 320.51 0.00e+00 4.557772e-03 1.384519e-03 1.011934e-03 -6.000000e+00 1.294513e-02 273.18 -2.00 20.00 -2.00 320.03 0.00e+00 3.421 0.001 302.00 328.00 3 4.8974e+00 1.1103e-02 4.6679e-02 -6.0000e+00 7.2284e-01 2.2747e-01 1.4093e-02 3.4735e-02 -6.0000e+00 7.8858e-01 -1.9545e-01 1.3694e-02 1.7114e-02 -6.0000e+00 4.6710e-01 7.9248e-02 6.9177e-03 7.3914e-03 -6.0000e+00 1.9936e-01 6.5957e-05 -6.3542e-04 1.9963e-04 6.5766e-05 -6.0000e+00 1.4125e-02 4.1304e-03 0.0000e+00 12 9 9 12 1 1 100.00 22.66 0.73 0.00413 -0.00064 20 7 1 5 0 1615.080 25.90 20.00 22.66 7.29 28.9 963.55 900000 900000 -129790 -70948 -180667 -49524 -118164 -158393 -58249 900000 -189055 214673 -84114 -16030 900000 -53985 46702 -51132 38379 66429 155896 -7481 900000 -36845 126530 37714 -19156 45547 -12785 18697 11668 8023 2727 295674 1449 38399 -27222 -2190 4111 34403 2420 4306 19641 12160 -1138 4409 2966 16717 9126 6549 11197 31037 -860 11517 1928 16818 -304 1292 1859 4400 2391 -1347 6476 870 9500 -6965 11403 -1129 1045 -135 1669 2659 934 -3363 -6056 -530 -390 2501 -784 2271 -6259 -2425 -1597 -6530 504 345 581 1026 1274 -2269 2453 -2756 473 2281 -1371 517 -1886 574 -1251 758 -140 16 27 -1724 -514 228 1155 -2799 -689 -1092 2273 -823 -100 286 247 287 331 -49 -890 131 -261 -205 709 2732 -1299 3268 -324 1539 1605 18 79 -608 631 167 -535 178 469 543 -378 -509 -702 -466 -749 900000 900000 -3049 -993 -6412 -480 -2354 -4830 -784 900000 -9828 1502 -2219 -276 900000 -2092 754 -2422 806 1109 1091 -266 900000 -1904 1362 1035 -949 1152 -564 634 496 423 176 2069 101 1778 -2594 -189 403 2982 327 614 2527 1735 -187 700 487 2457 1503 1170 2098 5313 -206 2631 513 3985 -87 364 504 1137 644 -410 2062 330 3500 -2963 3933 -449 441 -66 886 1461 517 -1832 -3091 -229 -155 964 -345 1140 -3995 -1697 -1214 -5146 421 287 504 911 1124 -1995 2048 -2251 357 1718 -1187 472 -2035 689 -1662 987 -172 18 27 -1752 -551 257 1352 -3636 -954 -1585 3514 -1381 -166 454 369 436 503 -73 -1410 213 -422 -317 1114 4043 -1913 4410 -437 2119 2473 29 141 -1161 1243 328 -1126 389 1039 1216 -846 -1091 -1411 -931 -1455 SS 20240310T131637.8Z 8835.553215 101 1 6.13 2 68.62 116.44 72.33 114.61 0.00 1 0.00 1 0 17 1.148e-01 7.020e-03 5.233e-02 3.505e-03 5.017604e-01 1.769908e-03 5.864080e-03 -6.000000e+00 6.516865e-02 225.65 -2.00 3.52 -2.00 319.34 0.00e+00 1.876123e-03 4.604018e-04 2.548230e-04 -6.000000e+00 2.793155e-03 273.18 -2.00 20.00 -2.00 318.83 0.00e+00 2.718 0.000 302.00 328.00 3 3.0906e+00 4.8770e-03 3.6414e-02 -6.0000e+00 1.6162e-01 8.0537e-02 5.6966e-03 2.5696e-02 -6.0000e+00 1.7617e-01 -1.6266e-02 4.6454e-03 1.3028e-02 -6.0000e+00 1.0456e-01 -5.0271e-03 2.4731e-03 4.2285e-03 -6.0000e+00 4.3903e-02 9.3018e-04 -7.3498e-04 9.7716e-05 4.4114e-05 -6.0000e+00 3.1289e-03 7.2769e-03 0.0000e+00 12 9 1 12 1 1 99.99 22.68 0.42 0.00728 0.00175 18 36 1 5 0 322.370 25.90 19.99 22.68 7.84 28.9 966.60 -47173 18566 -31284 -37679 -39462 -41604 -25228 -63824 16193 -42175 -3965 -34931 -11261 -25477 6175 -5322 -403 938 -6579 7184 -15494 1605 -6247 964 -7406 9022 -2663 -937 2980 -8646 4894 -4167 4955 -213 3554 -5564 250 358 -771 2202 -2543 1819 -2403 382 -3185 1052 -1385 3045 -960 -486 3113 1271 2401 570 1643 -584 1753 -936 1679 1289 1256 2188 1879 2911 -120 225 -608 222 -498 1866 712 1111 914 -423 332 -1189 516 -1760 88 -1280 -979 -951 -1616 -1762 -858 -914 -916 -536 293 323 -66 1142 -157 316 85 191 924 515 47 -273 -76 -553 -24 -301 -241 -1015 -582 -747 -457 391 186 154 -67 392 99 279 479 327 398 -283 -16 18 323 -68 419 619 482 1013 382 -28 62 90 -336 55 -554 -133 -45 307 -381 -10 -65 -537 259 -1000 241 -727 -927 -904 -924 -500 -2094 271 -1384 -92 -1182 -358 -1158 251 -287 -23 58 -470 471 -1319 115 -497 77 -691 755 -257 -86 253 -842 468 -506 625 -31 476 -791 36 55 -145 482 -659 484 -698 111 -963 309 -420 892 -298 -156 1047 481 973 253 698 -262 789 -432 736 608 556 1037 998 1692 -75 135 -351 127 -310 1292 509 828 679 -304 235 -768 300 -1025 54 -926 -752 -823 -1530 -1763 -841 -956 -1007 -604 327 347 -66 1122 -147 294 86 204 1112 655 64 -374 -97 -691 -28 -349 -300 -1255 -752 -1024 -671 586 302 260 -112 616 146 414 707 504 610 -456 -25 28 486 -105 614 865 648 1393 582 -44 106 161 -585 101 -1081 -255 -89 609 -758 -19 -124 -978 455 SS 20240310T133033.9Z 8835.562893 112 1 2.84 2 66.32 119.27 70.01 117.20 0.00 1 0.00 1 0 17 4.034e-02 5.851e-03 8.372e-03 9.934e-04 4.583345e-01 4.976086e-04 5.416524e-03 -6.000000e+00 2.290065e-02 225.65 -2.00 3.52 -2.00 318.55 0.00e+00 9.270382e-04 1.020688e-04 1.687291e-04 -6.000000e+00 9.814386e-04 273.18 -2.00 20.00 -2.00 318.01 0.00e+00 2.472 0.000 302.00 328.00 3 3.8996e-01 1.3413e-03 3.3139e-02 -6.0000e+00 5.6794e-02 5.5958e-02 1.5309e-03 2.3339e-02 -6.0000e+00 6.1903e-02 -2.6702e-02 1.0960e-03 1.1682e-02 -6.0000e+00 3.6742e-02 3.2087e-03 5.8350e-04 3.4578e-03 -6.0000e+00 1.5430e-02 1.8685e-02 -5.5062e-04 2.7703e-05 3.7137e-05 -6.0000e+00 1.0993e-03 5.9830e-03 0.0000e+00 12 1 1 12 1 1 99.72 22.67 0.31 0.00598 0.00185 72 296 1 5 0 38.780 25.90 20.00 22.67 8.45 29.2 971.49 -8678 -14730 -6609 -14456 -12220 -19736 -12148 -17332 -10321 -9615 -13889 -8987 -9630 -1181 -3080 84 -2613 -355 -1108 -99 146 -1511 851 -1189 1068 -1390 -570 -2461 -1261 -1944 555 1151 1550 535 -3113 -2092 -2919 -1006 -718 -353 -1420 -170 -482 -608 621 46 104 -334 -93 128 1344 932 1309 1159 742 1034 666 816 131 829 854 1558 1601 1720 791 342 173 -427 929 844 172 284 82 166 -115 -178 -284 -913 -137 -444 -1292 -1068 -2187 -1818 -1104 -769 -639 -156 392 108 510 600 425 661 773 289 672 638 32 -340 -170 -748 -160 377 -664 -1082 -880 -653 -308 238 101 -77 134 51 208 471 683 356 375 -211 -443 103 92 347 550 533 416 1159 421 125 91 -186 -127 33 -252 -258 66 226 -244 -254 -30 -370 -147 -259 -545 -243 -566 -425 -700 -419 -709 -447 -451 -701 -455 -574 -79 -253 8 -275 -39 -120 -11 17 -178 110 -153 145 -204 -85 -360 -173 -271 84 196 297 111 -648 -417 -629 -248 -214 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