File name: Pandora179s1_CornwallCT_20241127_L2Fit_fwvt1c40d20221201p1-8.txt
File generation date: 20241128T045335.5Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c40p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 179
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora179_OF_v3d20220331.txt
Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt
Level 1 file used: Pandora179s1_CornwallCT_20241127_L1_smca1c40d20221201p1-8.txt
Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005)
Short location name: CornwallCT
Country of location: United States
Location latitude [deg]: 41.8213
Location longitude [deg]: -73.2973
Location altitude [m]: 505
Local noon date: 20241127
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1622 1771
Nominal wavelengths inside fitting window [nm]: 492.0217 492.1431 492.2644 492.3857 492.5071 492.6283 492.7496 492.8709 492.9921 493.1133 493.2345 493.3557 493.4769 493.5981 493.7192 493.8403 493.9614 494.0825 494.2036 494.3246 494.4457 494.5667 494.6877 494.8087 494.9297 495.0506 495.1716 495.2925 495.4134 495.5343 495.6551 495.7760 495.8968 496.0176 496.1384 496.2592 496.3800 496.5007 496.6215 496.7422 496.8629 496.9836 497.1042 497.2249 497.3455 497.4661 497.5867 497.7073 497.8279 497.9484 498.0689 498.1895 498.3100 498.4304 498.5509 498.6713 498.7918 498.9122 499.0326 499.1529 499.2733 499.3936 499.5140 499.6343 499.7546 499.8748 499.9951 500.1153 500.2356 500.3558 500.4760 500.5961 500.7163 500.8364 500.9566 501.0767 501.1967 501.3168 501.4369 501.5569 501.6769 501.7969 501.9169 502.0369 502.1568 502.2768 502.3967 502.5166 502.6365 502.7563 502.8762 502.9960 503.1158 503.2356 503.3554 503.4752 503.5949 503.7146 503.8343 503.9540 504.0737 504.1934 504.3130 504.4326 504.5523 504.6718 504.7914 504.9110 505.0305 505.1500 505.2695 505.3890 505.5085 505.6280 505.7474 505.8668 505.9862 506.1056 506.2250 506.3443 506.4637 506.5830 506.7023 506.8216 506.9408 507.0601 507.1793 507.2985 507.4177 507.5369 507.6561 507.7752 507.8943 508.0135 508.1325 508.2516 508.3707 508.4897 508.6088 508.7278 508.8468 508.9657 509.0847 509.2036 509.3225 509.4414 509.5603 509.6792 509.7981 509.9169
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20241127T120446.5Z 9097.503316 135 1 48.01 2 89.63 119.50 58.88 148.61 0.00 1 0.00 1 0 22 9.632e-03 9.501e-03 1.118e-03 1.112e-03 8.443171e+03 7.346389e+01 5.353661e+02 -6.000000e+00 5.396379e+02 275.38 -2.00 20.00 -2.00 505.44 0.00e+00 2.849774e-03 3.094183e-05 1.550605e-04 -6.000000e+00 2.698755e-04 275.38 -2.00 20.00 -2.00 501.18 0.00e+00 1.037680e+00 2.163793e-02 8.187072e-02 -6.000000e+00 1.941926e-01 222.64 -2.00 3.52 -2.00 502.66 0.00e+00 20.169 0.153 489.00 513.00 1 5.2574e+00 1.6537e-03 3.4965e-02 -6.0000e+00 1.4894e-02 -4.2593e-02 4.1137e-04 2.5677e-03 -6.0000e+00 3.8174e-03 6.0345e-04 9.9675e-04 1.2077e-04 8.8022e-05 -6.0000e+00 1.0993e-03 3.3024e-04 1.0207e-04 12 9 8 11 32 0 99.58 22.75 6.12 0.00033 0.00724 15 4 1 4 0 3199.920 25.90 19.99 22.75 5.15 32.8 894.82 -2779 -2513 -1666 -505 203 822 1883 1493 1116 553 178 3 -487 -739 -1081 -1119 -543 -107 411 373 815 985 172 942 1065 1038 564 621 -355 -827 -1249 -973 -844 206 618 406 385 281 -10 -70 84 635 892 1391 1031 998 843 560 16 67 -1229 -1061 -1829 -1372 -642 402 319 750 523 839 1207 1280 1265 1220 683 492 51 -450 -1023 -903 -1183 -622 -351 -419 -698 -576 -1054 -1192 -1404 -1602 -1180 -1219 -580 -957 -505 -830 -970 -489 -389 207 -9 800 1258 872 863 518 -107 -664 -964 -1543 -1988 -1717 -575 -151 -227 -403 -533 -668 -551 -308 37 309 1099 1486 1752 2436 2027 1641 1552 1056 739 257 659 382 450 670 492 503 342 590 60 -54 -883 -894 -980 -473 -274 -372 592 373 353 456 -2 390 278 -305 -306 -1065 -1503 -1736 -2458 -2246 -1469 -455 187 774 1729 1393 1047 519 165 3 -445 -671 -982 -1023 -501 -101 394 351 771 934 166 904 1028 1006 548 597 -338 -774 -1196 -903 -799 199 610 394 374 272 -10 -69 81 614 872 1372 1033 1005 849 560 16 65 -1181 -1031 -1781 -1302 -620 395 322 741 520 835 1202 1281 1272 1229 688 491 51 -442 -1002 -903 -1181 -620 -342 -413 -695 -570 -1037 -1159 -1358 -1549 -1140 -1188 -567 -950 -505 -839 -984 -494 -393 209 -9 796 1258 874 879 518 -105 -640 -914 -1456 -1890 -1663 -571 -151 -232 -418 -552 -690 -568 -320 38 320 1143 1556 1845 2572 2169 1723 1627 1132 784 272 691 404 479 715 513 525 359 616 62 -57 -937 -947 -1018 -498 -294 -407 635 406 389 505 -2 437 311 -341 -337 -1164 -1635 -1900
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SQ 20241127T121110.2Z 9097.507758 143 1 48.50 2 88.60 120.57 58.31 150.28 0.00 1 0.00 1 0 22 5.477e-03 5.430e-03 4.067e-04 4.058e-04 6.943851e+03 2.638405e+01 4.650127e+02 -6.000000e+00 3.068586e+02 275.38 -2.00 20.00 -2.00 505.39 0.00e+00 1.999491e-03 1.125279e-05 1.118508e-04 -6.000000e+00 1.534765e-04 275.38 -2.00 20.00 -2.00 500.94 0.00e+00 1.202662e+00 7.979941e-03 6.160225e-02 -6.000000e+00 1.104612e-01 222.64 -2.00 3.52 -2.00 502.46 0.00e+00 17.818 0.105 489.00 513.00 1 3.6543e+00 6.1050e-04 2.8482e-02 -6.0000e+00 8.4712e-03 -2.6757e-02 1.5284e-04 2.0555e-03 -6.0000e+00 2.1723e-03 4.1075e-03 8.6043e-04 4.4176e-05 7.1242e-05 -6.0000e+00 6.2510e-04 -6.2341e-03 1.1127e-04 12 8 8 10 0 0 99.44 22.76 3.41 -0.00623 -0.00027 63 15 1 4 0 769.740 26.00 20.00 22.76 5.15 32.9 895.12 -1372 -1171 -740 -188 43 549 951 872 817 582 208 -10 -287 -406 -500 -548 -364 -77 283 148 376 496 443 559 698 545 329 193 -85 -542 -572 -562 -471 70 244 73 1 131 -1 -109 226 174 316 612 712 578 470 321 -22 -247 -808 -919 -996 -882 -369 14 120 327 371 521 697 715 686 672 537 162 -1 -185 -223 -505 -496 -459 -546 -333 -235 -390 -761 -745 -820 -793 -722 -741 -680 -459 -376 -356 -438 -275 -308 -122 100 493 547 573 546 412 -13 -335 -634 -839 -1195 -962 -495 -285 -354 -464 -394 -366 -235 -28 76 268 646 782 1041 1256 1405 1135 805 560 364 262 350 524 378 368 443 278 224 240 11 -177 -294 -472 -394 -204 -172 -180 107 148 196 274 271 221 81 -59 -284 -650 -866 -849 -1242 -1071 -675 -176 41 528 906 842 790 561 199 -9 -276 -387 -475 -523 -343 -74 278 144 369 489 438 556 697 546 330 191 -83 -520 -553 -546 -455 69 242 73 1 130 -1 -107 223 173 318 608 714 584 474 321 -22 -245 -786 -898 -967 -862 -360 14 119 330 376 529 708 730 688 674 536 165 -1 -183 -219 -493 -481 -447 -536 -331 -234 -388 -751 -725 -793 -765 -698 -722 -668 -455 -376 -352 -434 -273 -305 -122 100 497 557 583 549 406 -13 -324 -603 -808 -1132 -927 -481 -287 -357 -474 -401 -370 -237 -28 77 273 665 811 1086 1292 1455 1183 840 579 380 270 360 541 393 376 454 285 231 247 11 -183 -301 -483 -406 -209 -179 -188 113 158 208 292 292 238 87 -63 -300 -693 -916 -900
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