File name: Pandora179s1_CornwallCT_20260227_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20260302T154724.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20260227_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20260227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260227T130803.9Z 9554.547267 228 1 49.78 2 73.76 117.40 112.34 350.51 0.00 1 0.00 1 0 17 3.460e-01 1.700e-02 1.239e-01 4.129e-03 6.283065e-01 2.126035e-03 7.192809e-03 -6.000000e+00 1.958057e-01 225.14 -2.00 3.52 -2.00 320.19 0.00e+00 3.845700e-03 7.127082e-04 7.091457e-04 -6.000000e+00 8.600785e-03 272.35 -2.00 20.00 -2.00 319.71 0.00e+00 3.519 0.001 302.00 328.00 3 4.6123e+00 6.0950e-03 4.6635e-02 -6.0000e+00 4.8515e-01 1.9801e-01 7.5917e-03 3.3391e-02 -6.0000e+00 5.2931e-01 -1.8364e-01 7.2662e-03 1.6830e-02 -6.0000e+00 3.1459e-01 7.2474e-02 3.7326e-03 6.6702e-03 -6.0000e+00 1.3330e-01 8.3474e-05 -1.0073e-03 1.1105e-04 6.2065e-05 -6.0000e+00 9.5504e-03 1.5752e-02 0.0000e+00 12 9 8 11 40 0 50.56 22.70 0.45 0.01575 0.00818 13 3 1 5 0 3828.730 25.90 20.00 22.70 3.08 36.5 961.64 -63025 900000 -112287 900000 52855 -85551 -81177 -164155 -102968 -981 -153424 -60043 -118105 31556 27906 -11020 126933 12306 -23355 52328 -26598 3990 95526 -37135 41005 -13796 -16176 -7087 -22064 -25629 15223 -7484 2326 91052 -8546 16328 -28378 14412 15217 23546 649 9870 9805 4479 21072 -138 4488 5095 9257 1383 7238 15713 -1026 8075 751 15847 1011 -2709 -4065 3855 -1512 1899 4407 3725 4783 -8477 2015 -2815 1625 260 3602 2185 1872 -984 -4277 -2045 27 -1576 -3297 -2054 -5901 776 -2185 -3853 -475 1297 785 -693 1289 -1950 1706 -1506 2017 1353 -8 809 -1308 1699 -501 -181 -711 195 -217 -401 -1327 352 -253 -589 -1001 -433 612 -161 -26 274 760 60 110 182 177 -733 314 14 -42 1565 -327 1445 28 1831 825 138 188 -184 3 -526 -153 379 -311 30 -203 -100 113 -262 -742 -689 900000 -2615 900000 229 -1304 -1237 -6371 -2427 -10 -6749 -1227 -4957 410 475 -310 1100 370 -1007 1199 -1277 151 1479 -2157 1257 -714 -874 -366 -1291 -1643 759 -519 169 3186 -727 1132 -3076 1281 1514 2579 101 1504 1570 777 3126 -26 815 945 1711 293 1592 3537 -298 2319 245 4606 349 -965 -1421 1218 -517 685 1638 1564 2094 -4138 864 -1294 780 145 2138 1372 1164 -593 -2426 -1014 12 -723 -1707 -1238 -4039 565 -1791 -3393 -430 1155 736 -676 1227 -1839 1530 -1298 1603 1108 -7 803 -1530 2073 -676 -242 -892 231 -235 -438 -1566 430 -310 -772 -1438 -652 952 -266 -42 451 1167 88 164 282 289 -1190 523 23 -66 2287 -466 2048 39 2617 1266 226 336 -349 6 -1051 -310 797 -669 66 -436 -205 228 -497 -1376 SS 20260227T131413.2Z 9554.551541 232 1 47.33 2 72.75 118.59 112.52 351.92 0.00 1 0.00 1 0 25 3.181e-01 1.524e-02 1.058e-01 3.675e-03 5.938882e-01 1.877458e-03 6.805367e-03 -6.000000e+00 1.800440e-01 225.14 -2.00 3.52 -2.00 320.00 0.00e+00 2.733490e-03 5.972485e-04 3.417545e-04 -6.000000e+00 7.824908e-03 272.35 -2.00 20.00 -2.00 319.50 0.00e+00 3.324 0.001 302.00 328.00 3 4.6015e+00 5.3271e-03 4.3774e-02 -6.0000e+00 4.4610e-01 1.4283e-01 6.5082e-03 3.0702e-02 -6.0000e+00 4.8669e-01 -1.2649e-01 5.9699e-03 1.5765e-02 -6.0000e+00 2.8901e-01 4.8226e-02 3.0892e-03 5.7064e-03 -6.0000e+00 1.2160e-01 1.0667e-04 -3.7112e-04 1.0002e-04 5.7310e-05 -6.0000e+00 8.7796e-03 1.5693e-02 0.0000e+00 12 9 8 11 40 0 24.32 22.70 0.87 0.01569 0.01290 14 3 1 5 0 3380.200 25.90 20.00 22.70 3.72 36.7 965.41 -81703 105757 -113205 900000 -80662 -49338 -126102 -123234 -110254 -28936 -140334 -70601 -113104 -35729 28652 -21105 27226 20879 4758 11374 13271 -15573 60186 -27212 13733 5219 -15800 2468 -20941 131 -2916 15147 -711 63437 -11136 9135 -17655 -169 7896 10347 5032 5485 9317 8094 -1708 137 2169 1500 5699 132 6178 15727 -2523 6414 2162 11123 1891 -2349 -216 920 -961 -11 4814 2989 5104 -7121 4143 -1478 -296 259 2574 1004 505 845 -3536 649 181 -2167 -1214 -859 -4913 -1333 -1413 -3758 734 -414 -219 -8 1630 -680 665 -524 1066 728 -508 501 -1139 1297 -151 -320 -885 -173 -382 -1200 -905 -166 -765 -822 -189 -310 1005 -10 265 -86 248 361 238 592 3 -386 -273 311 87 960 -41 1680 92 1632 1036 341 246 -265 92 -307 -191 -102 -263 57 -38 233 -244 -224 -908 -1239 379 -3027 900000 -1401 -648 -3476 -3703 -3282 -449 -6383 -1897 -5269 -1056 556 -807 724 648 188 442 519 -809 1510 -1763 636 277 -1057 133 -1388 7 -197 1009 -64 3239 -1157 756 -2067 -20 1023 1567 836 974 1669 1504 -353 28 445 317 1196 31 1497 3850 -808 2031 755 3676 703 -906 -79 326 -357 -5 2078 1362 2383 -3647 1987 -709 -153 153 1632 674 336 530 -2111 332 93 -1140 -650 -538 -3720 -1030 -1191 -3425 681 -387 -214 -8 1599 -655 624 -463 884 618 -485 509 -1352 1603 -204 -429 -1112 -206 -419 -1343 -1084 -208 -954 -1094 -272 -468 1638 -17 426 -139 376 523 347 898 5 -648 -453 494 133 1402 -61 2361 127 2321 1566 578 427 -487 177 -593 -392 -207 -546 119 -79 484 -478 -435 -1737 SS 20260227T131940.8Z 9554.555334 235 1 47.90 2 71.86 119.65 112.65 353.18 0.00 1 0.00 1 0 17 2.106e-01 9.867e-03 1.345e-01 3.282e-03 5.736544e-01 1.681344e-03 6.618067e-03 -6.000000e+00 1.197810e-01 225.14 -2.00 3.52 -2.00 319.84 0.00e+00 1.591087e-03 5.147760e-04 1.050948e-03 -6.000000e+00 5.275087e-03 272.35 -2.00 20.00 -2.00 319.35 0.00e+00 3.171 0.001 302.00 328.00 3 4.6036e+00 4.7272e-03 4.2288e-02 -6.0000e+00 2.9647e-01 8.6767e-02 5.7450e-03 3.0410e-02 -6.0000e+00 3.2352e-01 -2.6013e-02 5.3700e-03 1.4992e-02 -6.0000e+00 1.9167e-01 7.4413e-04 2.8116e-03 4.8428e-03 -6.0000e+00 8.0513e-02 1.2543e-04 -6.3717e-04 9.0404e-05 4.9060e-05 -6.0000e+00 5.8161e-03 1.5850e-02 0.0000e+00 12 9 8 11 8 0 30.37 22.71 0.28 0.01585 0.01106 15 4 1 5 0 3192.530 25.90 19.99 22.71 4.26 36.5 968.03 64346 16110 -67412 900000 -28298 900000 -18141 -109906 97165 25454 -94997 2615 -54061 -18241 55635 10496 54164 24300 -7014 42306 -7148 25552 33555 -8668 33254 7521 -12639 -6370 -20456 -15662 2238 -9210 10128 39381 229 -2265 -13740 -3044 5371 9117 -2919 1828 3223 2330 -7344 1460 -2074 3527 1047 -2521 3455 8299 -1345 4104 334 6852 164 -1486 -1300 -1077 -2716 740 1945 2473 1172 -6011 1598 -1081 -644 910 1278 1180 55 -706 -2332 -277 609 -1565 171 -901 -3089 -1140 -934 -2271 -281 922 558 -454 1678 -203 1861 -124 1018 972 -320 1324 -276 1061 -146 -470 103 -118 163 -316 -244 -272 607 -959 -1014 -49 719 143 -442 569 146 605 -121 -517 -7 -572 -410 -356 357 433 30 -405 424 942 282 193 200 -239 -361 61 -447 132 140 330 -42 -19 108 -88 -372 222 107 -1128 900000 -293 900000 -174 -3002 383 226 -2946 33 -1490 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