File name: Pandora229s1_Daegu_20251208_L2Fit_fout2c4d20221031p1-8.txt File generation date: 20251208T152623.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Sunyoung Park Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 229 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora229_OF_v3d20220728.txt Instrument calibration file used: Pandora229s1_CF_v4d20221031.txt Level 1 file used: Pandora229s1_Daegu_20251208_L1_smca1c4d20221031p1-8.txt Full location name: Kyungpook National University Short location name: Daegu Country of location: Korea, Republic of Location latitude [deg]: 35.8869 Location longitude [deg]: 128.6061 Location altitude [m]: 44 Local noon date: 20251208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 3 adding wavelength change parameters to OoB First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0286 305.1698 305.3110 305.4522 305.5934 305.7346 305.8758 306.0170 306.1581 306.2993 306.4404 306.5815 306.7226 306.8637 307.0048 307.1459 307.2869 307.4280 307.5690 307.7100 307.8511 307.9921 308.1331 308.2740 308.4150 308.5560 308.6969 308.8379 308.9788 309.1197 309.2606 309.4015 309.5424 309.6833 309.8241 309.9650 310.1058 310.2466 310.3874 310.5282 310.6690 310.8098 310.9506 311.0913 311.2321 311.3728 311.5135 311.6543 311.7950 311.9356 312.0763 312.2170 312.3576 312.4983 312.6389 312.7795 312.9202 313.0608 313.2013 313.3419 313.4825 313.6230 313.7636 313.9041 314.0446 314.1851 314.3256 314.4661 314.6066 314.7470 314.8875 315.0279 315.1684 315.3088 315.4492 315.5896 315.7299 315.8703 316.0107 316.1510 316.2914 316.4317 316.5720 316.7123 316.8526 316.9929 317.1331 317.2734 317.4136 317.5538 317.6941 317.8343 317.9745 318.1146 318.2548 318.3950 318.5351 318.6753 318.8154 318.9555 319.0956 319.2357 319.3758 319.5159 319.6559 319.7960 319.9360 320.0760 320.2160 320.3560 320.4960 320.6360 320.7759 320.9159 321.0558 321.1958 321.3357 321.4756 321.6155 321.7554 321.8952 322.0351 322.1749 322.3148 322.4546 322.5944 322.7342 322.8740 323.0138 323.1535 323.2933 323.4330 323.5727 323.7125 323.8522 323.9919 324.1315 324.2712 324.4109 324.5505 324.6901 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251207T233304.4Z 9472.981302 290 1 51.70 2 79.00 128.77 67.74 283.77 0.00 1 0.00 1 0 25 2.947e-01 9.990e-03 1.867e-01 3.454e-03 5.126406e-01 1.800941e-03 5.920465e-03 -6.000000e+00 1.669781e-01 223.87 -2.00 3.41 -2.00 320.97 0.00e+00 2.374443e-03 8.090239e-04 3.363770e-03 -6.000000e+00 7.616819e-03 281.96 -2.00 20.00 -2.00 320.35 0.00e+00 5.054 0.002 302.00 328.00 3 2.1798e+00 5.8644e-03 5.7812e-02 -6.0000e+00 4.1101e-01 -2.8970e-02 7.6870e-03 3.1687e-02 -6.0000e+00 4.4837e-01 -3.4371e-02 7.4538e-03 1.6518e-02 -6.0000e+00 2.6800e-01 8.2336e-03 3.6460e-03 4.8916e-03 -6.0000e+00 1.1337e-01 2.5303e-04 4.1064e-04 1.0620e-04 7.8725e-05 -6.0000e+00 8.3456e-03 2.2205e-02 8.7496e-05 12 9 8 11 16 0 99.60 22.77 0.41 0.02220 0.02529 79 13 1 8 0 654.330 25.47 20.21 22.77 11.68 5.0 907.55 -66321 262466 -83076 900000 -87201 -42332 -91020 13353 -32294 77862 -2334 12828 -54645 -21124 -11334 -34057 -31144 13387 -23231 -11615 -24904 -12695 -25872 -16822 3793 1487 -22256 -23486 18484 -16258 -20524 -16958 -7833 -9831 -12576 -10164 -15928 -11014 -1981 -3964 6788 1139 4334 4192 2772 -146 4750 -997 2915 -235 4499 -418 2054 5661 4540 2063 233 1294 3070 -1246 3857 2783 4368 2078 3228 -85 -577 -240 -289 876 1120 2114 1732 53 -2453 -3068 -4521 -5230 -2242 -1543 -1922 -1277 -2026 -1066 -645 1017 469 1864 1886 1783 -170 -1172 -2021 -1348 -1949 -622 238 1464 67 442 -968 -1601 -1381 -408 -564 -1047 -200 -374 674 1367 1997 1199 557 -464 -1604 -1538 -649 -413 696 128 895 968 974 585 348 -1246 -780 -957 271 -302 -243 -1083 -794 -93 441 -81 558 901 615 297 -215 -622 -757 -467 884 -865 900000 -854 -259 -975 57 -247 262 -15 79 -803 -278 -167 -740 -734 221 -597 -281 -709 -323 -784 -505 100 42 -818 -933 473 -624 -947 -880 -422 -573 -728 -575 -1057 -827 -166 -403 695 132 512 510 347 -19 605 -137 399 -35 706 -76 399 1144 979 474 56 307 701 -296 910 732 1272 682 1077 -28 -189 -80 -107 366 511 995 809 24 -1042 -1184 -1657 -1953 -905 -724 -1045 -778 -1348 -747 -483 801 391 1573 1587 1440 -130 -846 -1411 -965 -1560 -563 244 1675 75 533 -1105 -1674 -1362 -412 -616 -1216 -244 -490 866 1924 3023 1885 865 -692 -2271 -2103 -897 -600 1066 204 1414 1486 1451 843 530 -1856 -1133 -1475 418 -517 -447 -2110 -1613 -198 1003 -194 1356 2221 1508 702 -485 -1349 -1636 SS 20251207T233837.6Z 9472.985157 293 1 51.91 2 78.13 129.72 68.81 284.43 0.00 1 0.00 1 0 25 2.749e-01 9.825e-03 1.927e-01 4.336e-03 4.883381e-01 2.223662e-03 5.397910e-03 -6.000000e+00 1.568969e-01 223.87 -2.00 3.41 -2.00 320.79 0.00e+00 6.642054e-04 9.527040e-04 2.119569e-03 -6.000000e+00 7.021404e-03 281.96 -2.00 20.00 -2.00 320.17 0.00e+00 4.712 0.002 302.00 328.00 3 2.8740e+00 7.1105e-03 5.3303e-02 -6.0000e+00 3.8623e-01 -4.7425e-02 9.2153e-03 2.7503e-02 -6.0000e+00 4.2150e-01 6.5891e-04 8.7822e-03 1.3667e-02 -6.0000e+00 2.5095e-01 -5.8448e-03 4.3314e-03 3.8028e-03 -6.0000e+00 1.0548e-01 1.7870e-04 2.4536e-04 1.3282e-04 5.2474e-05 -6.0000e+00 7.7528e-03 2.2446e-02 7.8409e-05 12 9 8 11 16 0 99.82 22.77 0.31 0.02245 0.02429 54 9 1 8 0 961.230 25.47 20.20 22.77 11.88 5.0 908.67 -69581 -74588 196062 -62784 116442 -51174 900000 -74670 -33761 -58890 122007 -15157 -37014 -18399 9122 -26861 -8053 7784 -35592 1717 -17402 -28066 -11413 -18868 -14850 -14923 -16971 4792 -17541 -12932 -14586 -15820 -6895 -7341 436 -7925 -972 -1912 -3917 -2075 1868 4362 6078 5870 -1026 6570 -1442 1867 -952 -784 8492 2499 806 1975 946 2906 -2605 1264 -420 2436 329 2952 2755 4183 928 -1212 -1583 -3219 -1168 1090 2858 1380 252 1173 1027 -1598 -1370 -4627 -2250 -3332 -786 -1251 -738 -1795 141 -307 1693 808 2280 1022 488 -564 -1749 -2056 -334 -1176 397 1311 741 -267 -364 -1376 -1711 -859 -1113 -1330 -550 -473 604 1347 1853 1380 102 -516 -1252 -1125 -736 -234 -461 557 215 1687 460 1021 -365 -698 -1326 454 -453 390 -720 -421 -838 -168 361 292 536 1006 283 206 -153 -808 -765 -615 -803 829 -627 492 -413 900000 -947 -324 -792 516 -151 -555 -283 130 -640 -176 159 -1204 42 -535 -971 -351 -682 -559 -596 -704 155 -756 -558 -728 -923 -417 -472 25 -496 -63 -149 -381 -236 229 559 802 794 -151 908 -218 278 -150 -130 1407 486 173 453 232 726 -707 330 -109 613 88 845 885 1454 341 -438 -558 -1180 -462 482 1362 695 127 558 450 -648 -517 -1815 -954 -1664 -441 -793 -504 -1315 109 -255 1448 716 1984 864 385 -419 -1257 -1520 -269 -1088 413 1518 914 -327 -416 -1449 -1711 -884 -1239 -1569 -681 -624 858 2088 2801 2153 158 -762 -1919 -1660 -1101 -367 -702 874 338 2792 749 1589 -553 -1019 -1902 675 -754 644 -1290 -788 -1640 -346 791 669 1254 2384 671 469 -333 -1696 -1595 SS 20251207T234338.3Z 9472.988638 296 1 51.77 2 77.36 130.60 69.76 285.03 0.00 1 0.00 1 0 17 1.278e-01 8.740e-03 1.742e-01 4.542e-03 4.691763e-01 2.330169e-03 5.310767e-03 -6.000000e+00 7.244600e-02 223.87 -2.00 3.41 -2.00 320.64 0.00e+00 1.789490e-03 9.466732e-04 1.982788e-03 -6.000000e+00 3.253289e-03 281.96 -2.00 20.00 -2.00 320.02 0.00e+00 4.444 0.001 302.00 328.00 3 3.0800e+00 7.3166e-03 5.0359e-02 -6.0000e+00 1.7833e-01 -1.9698e-02 9.3099e-03 2.5693e-02 -6.0000e+00 1.9453e-01 -7.8493e-03 8.6589e-03 1.3550e-02 -6.0000e+00 1.1622e-01 -6.3441e-03 4.3171e-03 4.2496e-03 -6.0000e+00 4.9053e-02 1.8760e-04 5.7718e-04 1.3909e-04 6.4606e-05 -6.0000e+00 3.5731e-03 2.1579e-02 1.1543e-04 11 9 0 11 16 0 99.96 22.77 0.40 0.02158 0.02592 70 11 1 8 0 739.450 25.47 19.88 22.77 12.02 5.0 909.22 47007 10378 -6737 -51614 -63318 -55211 -22959 23435 -36832 -22379 -34395 -22404 -28027 432 -23096 -33960 20596 -27679 -8547 13397 7650 2980 8510 -9438 -9982 -746 1743 -10251 -2487 -22338 5811 387 -3121 -13007 6095 -8595 -1679 -3046 5536 -2365 5317 -4595 2557 1780 4449 -253 3918 3078 -1386 -3941 805 815 -69 1760 89 1098 552 1874 3608 689 -1813 1481 2671 3061 1702 945 -2199 -946 2117 704 15 1308 1126 401 -1989 -375 -4801 -4087 -3479 -1755 -1590 -1160 -1623 -120 -85 437 997 760 1453 845 -94 28 -1444 -2191 -1169 -1169 860 1034 1275 -62 -763 -1639 -1440 -451 -657 -637 -224 -511 817 1654 1284 1082 548 -251 -1354 -1040 -836 -410 152 28 178 527 554 544 42 -646 -736 -390 9 -34 -494 -401 -774 -369 -110 263 662 993 549 390 -226 -441 -956 208 63 -52 -603 -765 -600 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