File name: Pandora120s1_Davos_20161120_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251201T234619.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20161120_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20161120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161120T063941.0Z 6168.277558 4 1 32.00 2 89.54 120.23 42.82 230.20 0.00 1 0.00 1 0 43 9.745e-02 9.483e-02 1.022e-01 9.888e-02 1.470483e+03 5.569515e+03 2.120003e+02 -6.000000e+00 4.940988e+03 265.88 -2.00 20.00 -2.00 505.13 0.00e+00 5.213891e-04 2.607947e-03 9.157212e-05 -6.000000e+00 2.605525e-03 265.88 -2.00 20.00 -2.00 499.72 0.00e+00 1.100370e+00 2.029568e+00 1.978996e-02 -6.000000e+00 1.915992e+00 221.25 -2.00 3.62 -2.00 501.39 0.00e+00 20.308 0.167 489.00 513.00 1 4.4767e+00 1.5560e-01 3.0919e-02 -6.0000e+00 1.4589e-01 1.5475e-01 4.0441e-02 1.7137e-03 -6.0000e+00 3.8309e-02 1.8776e-03 7.7154e-03 8.7701e-03 4.2792e-05 -6.0000e+00 8.9726e-03 1.5378e-03 12 8 8 10 0 0 9.00 11.81 -0.45 0.00154 0.05506 8 1 1 2 0 4000.000 -99.00 11.81 19.85 20.04 -11825 9298 5326 1560 5225 2505 1825 7581 10010 -502 19500 -15988 1008 -2951 6446 -19968 830 -596 -2502 2552 12226 8571 -633 9678 -2115 -630 6988 7996 -5100 10514 -14393 6403 -9597 2875 -9246 3126 -7912 -137 11315 -7720 -7117 2681 15607 10632 10521 -5119 17542 2318 -628 -7553 -1112 -7988 -7275 10344 1540 7305 8212 -14174 1177 10033 -8026 2612 7473 7769 -19171 6614 -12724 17618 -3422 10796 -11435 15856 14100 -10299 2287 7443 10781 -3083 27095 -24079 4371 7003 -5566 -8826 4159 -15385 18189 -12403 345 6753 -3635 4471 10453 -2870 -7693 4511 4258 11566 -13186 -3800 -7768 263 -9611 26864 -1325 15100 -5684 19530 -997 12518 220 -1776 9057 4249 2624 14206 -480 -6232 -10583 -11253 -1539 -6090 3835 5973 16845 9430 3103 -3268 13576 2279 4778 -8325 -12779 16288 -727 4374 16864 -4428 -3603 -8449 -8820 2908 9832 8214 -8493 -775 4327 -2695 7456 -13802 9051 5598 1753 5783 2835 2105 8257 10524 -576 18059 -20775 1088 -3284 6533 -26701 923 -691 -3003 2918 12680 9214 -748 10358 -2548 -744 7561 8350 -5716 10085 -17294 6380 -11642 3176 -11622 3439 -9580 -151 11039 -9098 -8388 2894 14974 10813 10725 -6056 16304 2459 -668 -8327 -1119 -8295 -7571 9519 1562 7142 8010 -17242 1222 9538 -9185 2695 7323 7508 -23839 6242 -14360 14486 -3423 9290 -12338 13180 12102 -11087 2194 6640 9131 -2905 19288 -28095 3869 6075 -5526 -9151 3809 -17138 14456 -13379 328 6095 -3697 4243 9320 -2881 -7943 4022 3702 9115 -12801 -3447 -7341 239 -9951 19989 -1266 12026 -5481 14588 -925 10320 209 -1735 7993 3951 2491 12049 -469 -6358 -11072 -11398 -1432 -5809 3409 5208 13162 7745 2705 -3035 10606 1963 3934 -7696 -12270 11799 -638 3730 12891 -4233 -3436 -8486 -8934 2633 8323 7023 -8424 -692 3581 -2372 5982 SO 20161120T064035.0Z 6168.278183 5 1 32.00 2 89.40 120.39 42.93 230.46 0.00 1 0.00 1 0 71 9.427e-02 8.900e-02 9.080e-02 8.809e-02 2.763495e+03 5.169830e+03 3.557435e+02 -6.000000e+00 4.779682e+03 265.88 -2.00 20.00 -2.00 505.20 0.00e+00 5.728925e-04 2.296449e-03 9.634592e-05 -6.000000e+00 2.520091e-03 265.88 -2.00 20.00 -2.00 499.84 0.00e+00 2.813867e+00 1.760115e+00 3.929884e-02 -6.000000e+00 1.851804e+00 221.25 -2.00 3.62 -2.00 501.50 0.00e+00 20.050 0.160 489.00 513.00 1 4.2553e+00 1.3469e-01 3.0385e-02 -6.0000e+00 1.4102e-01 9.5729e-02 3.4374e-02 1.8808e-03 -6.0000e+00 3.6992e-02 2.1191e-03 2.6768e-02 7.6935e-03 5.3992e-05 -6.0000e+00 8.6762e-03 1.1505e-02 12 8 8 10 0 0 -3.30 11.81 2.31 0.01151 0.19718 8 1 1 2 0 4000.000 -99.00 11.81 19.85 20.04 -4337 -8176 11709 -11339 -7830 -3800 5739 1516 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-867 -12439 9902 -20054 916 -448 15210 210 18596 1751 -694 8563 -12092 859 -13317 4898 911 16144 -4017 7666 14217 -1553 -19753 10366 -13474 -3844 4821 1642 -1166 6218 -4043 -5313 11282 -1278 5426 5738 10521 -12853 -7228 -7283 8425 3803 1273 4589 -2396 134 3010 -868 -15296 2487 -3066 8159 2662 1635 -7358 12268 -8760 3654 -17621 10901 3269 4619 -2756 -3812 -35 -5300 16649 -4854 -811 970 238 -13090 2147 5160 10239 -9935 9634 2154 8348 2507 1131 6853 -3795 -494 -5277 9786 -13047 -3846 -10604 6218 -11757 18162 -7677 8893 14476 2163 -3791 -173 15053 2511 13057 9777 1809 -13890 22892 -1876 5559 -3290 -2018 -8880 -15836 -6604 5466 SO 20161120T064128.0Z 6168.278796 6 1 31.99 2 89.27 120.56 43.05 230.72 0.00 1 0.00 1 0 22 8.960e-02 8.470e-02 8.768e-02 8.492e-02 8.452702e+03 5.664149e+03 1.014027e+03 -6.000000e+00 4.542795e+03 265.88 -2.00 20.00 -2.00 505.21 0.00e+00 2.903773e-03 2.207155e-03 2.127156e-04 -6.000000e+00 2.395319e-03 265.88 -2.00 20.00 -2.00 499.77 0.00e+00 1.633173e+00 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