File name: Pandora120s1_Davos_20161121_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251201T234537.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20161121_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20161121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161121T064135.0Z 6169.278877 4 1 31.99 2 89.47 120.67 40.30 212.68 0.00 1 0.00 1 0 36 6.372e-02 6.213e-02 5.210e-02 5.131e-02 3.289806e+03 3.010459e+03 1.278905e+02 -6.000000e+00 3.228776e+03 265.76 -2.00 20.00 -2.00 505.27 0.00e+00 1.594133e-03 1.351015e-03 1.152527e-04 -6.000000e+00 1.703029e-03 265.76 -2.00 20.00 -2.00 500.10 0.00e+00 2.315213e+00 1.027249e+00 6.659817e-02 -6.000000e+00 1.252562e+00 221.24 -2.00 3.62 -2.00 501.76 0.00e+00 20.175 0.163 489.00 513.00 1 3.7116e+00 7.8569e-02 3.1012e-02 -6.0000e+00 9.5375e-02 7.4094e-02 2.0155e-02 2.0330e-03 -6.0000e+00 2.5040e-02 3.7003e-03 7.5983e-03 4.5447e-03 3.6711e-05 -6.0000e+00 5.8658e-03 3.6564e-03 12 8 8 10 0 0 -9.05 11.81 0.04 0.00366 0.05636 8 1 1 2 0 4000.000 -99.00 11.81 20.04 20.25 3585 -10052 1350 -4379 3818 -1773 11363 -1244 -219 2195 -917 3120 -756 7666 -11766 1636 -6063 6354 -5469 4070 -1809 2378 -5496 9918 592 464 4270 -8068 4583 -10409 -2100 -9951 3436 -5610 3363 1192 5648 2461 12073 1930 1160 3913 -47 -636 3910 3282 -4475 5543 -11053 7937 -6240 6288 969 4021 -3228 4465 10402 -1032 5421 2113 2683 -2846 10827 -3290 4391 -8624 2042 -2161 634 -12291 1588 3040 3044 310 -75 4560 395 1213 -5452 -2480 -3241 5566 -4908 5325 -9787 9251 -12428 9207 1374 10979 -3975 7273 -4211 5779 -5111 -2304 -1538 -2875 -1455 -8913 18230 3229 11019 -3337 9556 -1367 9608 -7246 2550 -3812 6053 2864 4384 4592 -4551 2721 -6909 3451 -10907 10806 -6199 -4113 -6287 9942 -8577 10571 -6670 4961 2528 -174 6575 871 4172 -3916 2066 -4821 18048 -10396 9243 -8181 7526 -6357 4869 -2596 11078 -627 -3452 -120 -5409 3319 -11006 1371 -4853 3989 -2000 11382 -1416 -244 2349 -999 3213 -798 7378 -13448 1659 -6807 6479 -6375 4326 -2039 2573 -6460 10054 660 517 4528 -9444 4564 -11773 -2190 -11469 3598 -6640 3671 1318 5895 2558 11575 2001 1222 4058 -51 -706 4160 3491 -5075 5580 -12792 7358 -6493 5704 937 3888 -3468 4541 10044 -1089 5469 2156 2737 -3079 10193 -3529 4290 -9429 1979 -2155 607 -13269 1498 2862 2907 306 -73 4173 370 1117 -5357 -2377 -3154 4991 -4825 4777 -10266 8019 -13341 7950 1288 9443 -4036 6679 -4323 5280 -5092 -2175 -1402 -2592 -1273 -8433 13481 2889 9466 -3358 8401 -1291 8190 -7143 2310 -3749 5484 2711 4116 4326 -4730 2646 -7384 3285 -11776 9234 -6218 -4055 -6389 8627 -8779 9126 -6684 4527 2356 -161 5698 772 3566 -3669 1867 -4774 14458 -11208 8255 -8741 6915 -6752 4635 -2649 9692 -601 -3326 -111 -5340 SO 20161121T064229.0Z 6169.279502 5 1 32.00 2 89.33 120.83 40.38 212.99 0.00 1 0.00 1 0 43 1.042e-01 1.621e-01 4.780e-02 4.675e-02 -2.000548e+04 2.492270e+03 1.527322e+03 -6.000000e+00 5.278872e+03 265.76 -2.00 20.00 -2.00 505.44 0.00e+00 8.396726e-03 1.238938e-03 2.545289e-04 -6.000000e+00 2.785216e-03 265.76 -2.00 20.00 -2.00 500.27 0.00e+00 9.890513e+00 9.389439e-01 1.745879e-01 -6.000000e+00 2.051543e+00 221.24 -2.00 3.62 -2.00 501.97 0.00e+00 19.904 0.157 489.00 513.00 1 3.0233e+00 7.1170e-02 3.3812e-02 -6.0000e+00 1.5617e-01 -8.3994e-02 1.8710e-02 4.4469e-03 -6.0000e+00 4.1090e-02 4.0593e-03 -1.2636e-02 3.5678e-03 2.1540e-04 -6.0000e+00 9.6034e-03 -1.8659e-02 12 8 8 10 0 0 -0.47 11.81 2.12 -0.01866 -0.10631 8 1 1 2 0 4000.000 -99.00 11.81 20.04 20.25 -4154 -9599 -9603 -6063 -1027 -5408 -7108 1252 -4133 1252 -4715 8607 -8593 -3413 -3280 197 -8641 -2351 -6319 -1755 -3546 1306 -2010 -4019 6019 1998 485 2914 2005 -8723 4799 -6692 181 -11820 505 390 392 8737 2236 541 -5317 3198 5798 2104 -1538 5471 -474 12278 -198 10423 -802 12291 1236 4792 -577 4879 -1083 3591 5739 10074 12009 9533 7263 6034 14439 2751 17544 -1178 5102 -775 1134 -6226 -1508 -234 11398 -687 452 6252 4347 14136 228 3537 -249 -1821 -7946 -1550 -7316 1702 -6187 -156 -6773 1200 3768 3328 13778 12615 21847 17724 19579 6101 13454 2369 11527 -138 -1555 543 -124 -9771 2837 -7285 4225 -8141 -1798 10833 11663 11863 1382 7031 -1039 4894 -1148 16395 6461 8469 6200 9088 9845 14274 18208 11113 -77241 12357 19211 -643 10165 8155 7068 4815 17246 9858 7349 2221 17782 11008 14574 11112 15662 8422 821 -3921 -9607 -9900 -6292 -1052 -5944 -8130 1339 -4681 1333 -5235 8229 -9389 -3490 -3319 193 -9300 -2425 -6966 -1885 -3898 1368 -2183 -4484 6143 2144 530 3091 2108 -9873 4605 -7158 184 -13672 536 422 423 8561 2312 566 -5906 3301 5928 2272 -1750 5850 -537 12122 -218 10079 -842 11009 1216 4563 -595 4921 -1163 3726 5830 9762 11400 9317 7287 6117 13330 2806 15138 -1204 4821 -763 1078 -6350 -1476 -228 9977 -674 430 5499 3860 11359 212 3192 -228 -1691 -7844 -1436 -7170 1526 -6032 -144 -6775 1133 3574 3278 12619 12016 19254 16054 16857 5818 11693 2288 10171 -133 -1490 490 -109 -9251 2366 -6861 3668 -8356 -1815 10008 10926 11149 1423 6671 -1043 4575 -1144 13874 6149 8036 5933 8484 9161 12768 15808 10427 -171120 11246 15948 -637 8983 7470 6735 4809 15393 9491 7232 2305 15993 10747 13803 10751 14040 7853 796 SO 20161121T064322.0Z 6169.280116 6 1 32.01 2 89.20 121.00 40.47 213.29 0.00 1 0.00 1 0 15 4.175e-02 4.067e-02 4.426e-02 4.372e-02 2.629278e+03 2.560395e+03 8.352698e+01 -6.000000e+00 2.116193e+03 265.76 -2.00 20.00 -2.00 505.27 0.00e+00 5.991735e-04 1.150158e-03 3.043690e-05 -6.000000e+00 1.116288e-03 265.76 -2.00 20.00 -2.00 500.08 0.00e+00 2.172754e+00 8.775023e-01 5.325891e-02 -6.000000e+00 8.216675e-01 221.24 -2.00 3.62 -2.00 501.73 0.00e+00 19.616 0.150 489.00 513.00 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