File name: Pandora120s1_Davos_20161205_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251201T234709.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20161205_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20161205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161205T065702.0Z 6183.289606 2508 1 32.00 2 89.81 124.11 128.77 66.94 0.00 1 0.00 1 0 36 1.547e-01 1.201e-01 1.305e-01 1.221e-01 4.997423e+03 7.597800e+03 8.700135e+01 -6.000000e+00 7.786851e+03 264.09 -2.00 20.00 -2.00 505.14 0.00e+00 1.237996e-03 3.217289e-03 1.210064e-04 -6.000000e+00 4.119882e-03 264.09 -2.00 20.00 -2.00 499.80 0.00e+00 2.932653e+00 2.531109e+00 8.449267e-02 -6.000000e+00 3.047895e+00 221.07 -2.00 3.62 -2.00 501.44 0.00e+00 20.792 0.179 489.00 513.00 1 4.4861e+00 1.9432e-01 3.2876e-02 -6.0000e+00 2.3192e-01 9.3574e-02 5.0037e-02 2.2731e-03 -6.0000e+00 6.1008e-02 1.4992e-03 -1.2908e-02 1.0775e-02 4.1454e-05 -6.0000e+00 1.4256e-02 -1.2405e-02 12 8 8 10 0 0 1.93 14.07 0.53 -0.01240 -0.10194 8 1 1 2 0 4000.000 14.64 14.07 19.12 19.23 13429 -4357 20863 -4318 -6192 -969 -6842 -8367 -3616 -2848 -6154 21861 11045 7164 9362 4197 -9144 12997 6611 -6896 -5403 2038 7037 -8654 13094 -15259 23687 -2126 20216 -7293 -15487 -12493 18035 4275 17304 89 -5999 -2766 15041 25618 -10538 -9807 -11555 3052 1306 16439 -11301 14458 -3257 24981 2990 1975 1926 1573 -5584 -4324 13810 10785 9538 -2024 22633 -9880 4953 -3517 7314 4835 5822 -5136 -5426 -5851 -7280 -6744 -7940 -2241 -6401 13947 -8164 15702 -7555 487 -14261 21829 -8507 5476 -8755 4562 -13402 6032 14520 3294 10717 -17843 1187 -12524 15882 -10891 17805 -7341 7104 -11928 27061 -10798 -7484 2348 13929 6833 3128 29645 -6363 188 -3542 9430 -4904 16284 -19060 22355 -1511 8020 -5468 -1055 1572 9754 24537 9412 8782 -13162 14420 -12308 7565 976 106635 -17328 12782 -4545 20161 8760 18737 14573 8538 4052 16051 3022 -17866 25878 -8660 41521 -28906 12561 -15742 11768 -4574 17471 -4830 -7296 -1110 -8285 -10449 -4326 -3358 -7380 20007 10828 7191 9096 4287 -10780 12553 7003 -8532 -6622 2319 7618 -10984 13448 -20882 21910 -2525 18817 -8640 -18881 -14697 16261 4469 16864 102 -7280 -3207 14395 21819 -12847 -11928 -14449 3338 1469 15967 -14421 14085 -3720 20991 3032 1964 1882 1545 -5903 -4668 13060 10382 9288 -2201 19205 -11655 5057 -3904 7224 4815 5637 -5459 -5707 -6088 -7595 -6999 -8417 -2276 -6838 12068 -8631 12800 -7672 454 -15084 16580 -8604 4853 -9046 4155 -14613 5396 11883 3018 9178 -20619 1148 -13893 13041 -11401 13603 -7006 5718 -11383 17438 -10364 -7224 2145 11626 5995 2811 20554 -6141 171 -3409 8098 -4916 13290 -22245 17354 -1503 7270 -5626 -1021 1455 8194 17743 7982 7541 -13795 11731 -12772 6576 886 34792 -18342 10093 -4149 14793 7199 14278 11787 7438 3731 13191 2845 -20863 19584 -9234 26456 -35611 10192 -16388 SO 20161205T065954.0Z 6183.291597 2511 1 32.01 2 89.41 124.64 128.33 67.58 0.00 1 0.00 1 0 15 1.037e-01 9.652e-02 1.075e-01 1.040e-01 -8.118932e+03 5.564966e+03 5.626358e+02 -6.000000e+00 5.221743e+03 264.09 -2.00 20.00 -2.00 505.23 0.00e+00 4.144256e-03 2.709023e-03 2.299300e-04 -6.000000e+00 2.761020e-03 264.09 -2.00 20.00 -2.00 499.85 0.00e+00 5.456749e+00 2.141388e+00 8.915750e-02 -6.000000e+00 2.037347e+00 221.07 -2.00 3.62 -2.00 501.54 0.00e+00 20.097 0.162 489.00 513.00 1 4.2065e+00 1.6344e-01 3.1494e-02 -6.0000e+00 1.5509e-01 6.3785e-02 4.2694e-02 2.5000e-03 -6.0000e+00 4.0652e-02 1.7767e-03 -1.3116e-03 9.1265e-03 1.1487e-04 -6.0000e+00 9.5425e-03 2.3165e-02 12 8 8 10 0 0 -8.88 14.07 0.89 0.02316 0.01407 8 1 1 2 0 4000.000 14.67 14.07 19.23 19.23 10575 -3670 424 16349 -9777 8452 6920 1015 -4875 15566 -6350 30165 -1561 4926 -7848 4284 -7530 -3757 -7209 -9316 -4289 -3831 5654 -11007 17287 -7606 16734 -5656 8089 -4166 8810 -16548 4211 -4705 4923 -823 -658 7052 -2767 8290 9224 4313 -3254 3101 -4365 11783 -9512 15983 -6830 3459 -2853 6352 -16163 9382 -5164 3003 -2538 8535 12230 -4201 10626 -1783 5958 4322 4275 -16442 19073 -4153 13122 -13431 31754 -2960 4919 3220 -10112 4000 -22037 7420 -7062 6523 -16355 1855 -8420 13300 1516 19583 1419 1746 3499 11014 12688 -4916 6706 -5456 1538 -1678 7080 -1110 25741 -6117 1517 -3546 13951 -6070 4161 -636 -7301 -2608 -2597 13821 -5339 7730 -3639 1250 -11850 3633 -9555 18658 1500 7235 4418 7947 -9796 -4608 -742 -11193 16023 -10871 5688 -6488 10904 -21095 -9578 -10168 24754 -2879 15987 -1060 14642 26696 197 9263 -6620 16923 -892 8706 -9022 9728 -8183 9531 -3916 451 15360 -11925 8995 7409 1157 -5849 15338 -7477 24884 -1698 4968 -8967 4374 -8829 -4358 -8829 -11709 -5125 -4558 6138 -14218 16919 -9541 16336 -6772 8158 -4495 8491 -20344 4350 -5510 5324 -938 -738 7234 -3100 8303 9215 4580 -3780 3421 -5218 11943 -11786 15077 -7900 3498 -2982 5946 -18529 8736 -5614 3087 -2790 8390 11528 -4656 10193 -1943 5997 4381 4262 -19783 15811 -4279 11189 -14728 22112 -2938 4567 3066 -10921 3676 -25147 6380 -6833 5654 -17527 1662 -8381 10713 1379 14867 1291 1584 3134 9228 10631 -5018 6194 -5734 1509 -1689 6391 -1056 18232 -5890 1363 -3339 11496 -5976 3625 -567 -6824 -2314 -2333 10792 -5196 6788 -3656 1211 -13142 3437 -10185 14737 1385 6255 3919 6852 -9977 -4479 -695 -11647 12983 -11312 5025 -6421 8908 -23259 -9267 -9883 17264 -2715 12742 -1014 12027 19446 188 8122 -6859 13863 -861 7421 -8909 7840 -7767 SO 20161205T070242.0Z 6183.293542 2514 1 32.00 2 89.02 125.15 127.90 68.20 0.00 1 0.00 1 0 29 1.053e-01 1.013e-01 9.451e-02 9.139e-02 7.284337e+03 5.836171e+03 5.027749e+01 -6.000000e+00 5.298691e+03 264.09 -2.00 20.00 -2.00 505.21 0.00e+00 -3.673822e-03 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