File name: Pandora120s1_Davos_20161224_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251201T235618.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20161224_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20161224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161224T071141.0Z 6202.299780 432 1 32.00 2 89.79 125.74 57.82 172.61 0.00 1 0.00 1 0 29 2.197e-01 1.733e-01 2.288e-01 2.090e-01 5.936305e+03 1.293697e+04 7.236262e+02 -6.000000e+00 1.097941e+04 262.36 -2.00 20.00 -2.00 505.25 0.00e+00 -4.878901e-03 5.462382e-03 3.175867e-04 -6.000000e+00 5.824880e-03 262.36 -2.00 20.00 -2.00 500.02 0.00e+00 1.153854e+00 4.177822e+00 1.110706e-01 -6.000000e+00 4.332904e+00 221.38 -2.00 3.62 -2.00 501.67 0.00e+00 20.796 0.179 489.00 513.00 1 5.2441e+00 3.1782e-01 3.3822e-02 -6.0000e+00 3.2951e-01 8.5433e-02 8.1939e-02 2.0376e-03 -6.0000e+00 8.6707e-02 8.5526e-04 9.5481e-03 1.7381e-02 1.4889e-04 -6.0000e+00 2.0235e-02 -1.0035e-02 12 8 8 10 0 0 5.67 14.57 10.78 -0.01004 0.05619 8 1 1 2 0 4000.000 15.26 14.57 19.64 19.75 8681 -8205 9175 -7069 10200 -12345 9388 -9935 59135 -15435 3448 -7941 3743 44838 2420 18298 -9285 -1872 -7940 2742 -6856 10226 10843 1045 1791 -9961 21058 -5655 18621 -20829 13426 -1233 32722 6695 28517 -3772 7633 -3722 791 -18962 22742 -11127 -4497 11702 -1763 4569 -1041 -4384 -6270 -4161 -8401 -19892 -1660 15174 -2163 22885 -4781 10077 -11612 41272 33004 44229 12256 5187 28003 -20490 -2300 5563 6451 -16971 34770 -24551 2516 -21306 -18834 -408 21700 -7948 1399 20299 57755 -7268 27893 5048 -10196 11142 -9717 12384 8623 12073 -461 8656 -2948 22458 -5122 43725 -21398 -1572 26210 -3386 35937 -30000 -12977 -11745 -7719 13671 22986 22305 3896 -27650 8300 21862 25947 49200 40028 -13928 44522 86101 -25295 42352 -9984 30727 4870 35510 -20996 55222 10022 40314 -14077 -1345 -17677 28228 -2243 9415 -548 -5427 -4477 -8900 3071 -21491 -5725 17580 41090 -12357 18067 -22119 10006 42980 20382 7885 -8862 8863 -8069 10024 -15545 9659 -12459 37876 -20068 3671 -9349 3870 31309 2527 16579 -11407 -2204 -10120 3159 -8491 10940 11544 1200 2040 -12685 19941 -6665 17062 -27044 12404 -1348 26473 7255 25064 -4540 8081 -4349 873 -24774 20102 -13561 -5301 11805 -1985 4906 -1137 -4852 -6878 -4321 -8846 -23177 -1627 12946 -2267 19078 -5290 9580 -13643 28571 24939 29971 11412 5133 21706 -24782 -2343 5180 5881 -18990 23900 -30279 2465 -26073 -22241 -392 16820 -8024 1286 15562 31534 -7510 20586 4760 -11312 10028 -10780 11027 8006 10922 -478 8243 -3045 17965 -5124 26650 -23799 -1405 17971 -3089 23443 -38950 -14915 -13664 -8621 12151 18291 17749 3753 -36107 7802 18006 20526 30908 27754 -16350 29834 38538 -32341 27592 -10584 22163 4476 24621 -25029 31351 8710 26452 -15501 -1285 -19545 19523 -2102 7968 -526 -5605 -4665 -9841 3046 -26880 -6167 15438 28605 -14300 15537 -27174 8729 27379 16415 SO 20161224T071743.0Z 6202.303970 438 1 32.01 2 88.96 126.85 57.72 174.32 0.00 1 0.00 1 0 22 1.419e-01 1.295e-01 1.330e-01 1.271e-01 8.906639e+02 6.890618e+03 2.471847e+02 -6.000000e+00 7.093361e+03 262.36 -2.00 20.00 -2.00 505.19 0.00e+00 7.987434e-03 3.372595e-03 3.773044e-04 -6.000000e+00 3.760632e-03 262.36 -2.00 20.00 -2.00 499.99 0.00e+00 -2.846963e-01 2.598010e+00 9.395508e-02 -6.000000e+00 2.787221e+00 221.38 -2.00 3.62 -2.00 501.64 0.00e+00 19.081 0.138 489.00 513.00 1 4.8838e+00 1.9909e-01 2.9748e-02 -6.0000e+00 2.1210e-01 1.6171e-01 5.1471e-02 1.8979e-03 -6.0000e+00 5.5537e-02 1.4354e-03 3.6836e-03 1.1323e-02 1.3350e-04 -6.0000e+00 1.3037e-02 3.8058e-02 12 8 8 10 0 0 5.33 14.56 -0.86 0.03806 0.06361 8 1 1 2 0 4000.000 15.05 14.56 19.54 19.75 21401 6488 5419 -13586 2616 -9312 5941 2476 21455 -20269 32824 -9599 -55 3919 -10873 3321 5057 -7880 -10896 -661 -14166 11664 -3768 9428 -6618 30770 -7093 -6208 -4246 3447 522 -8099 -2702 18984 2342 24096 4914 12082 21690 11652 26522 -13876 -4257 -14093 13638 -12691 1074 -1544 10318 7938 -17392 -3581 111 36419 3823 35304 -12744 9086 -4179 26391 -10035 13633 5276 6413 8176 11557 -6651 15474 32069 -12438 13814 7221 25553 -267 16885 -17521 -990 -27259 11518 -12437 -2008 -20561 21093 -13514 -4623 -1345 5884 7811 -2995 25474 -7787 17435 -12148 2691 -6679 28969 3544 -5028 -11223 20087 8619 -16152 9741 7216 28117 2510 8753 10552 28326 -18047 15912 -10969 5686 -5770 27741 -7466 -8490 326 13684 2178 3562 4384 -3734 15531 -15274 9364 -1899 -4125 1885 -716 13948 4866 -9259 -4630 -7058 4468 18167 -5314 26754 -11297 -1923 -17869 17708 -11309 13821 -9118 28562 5726 -11493 17727 6445 5653 -17641 2949 -12034 6642 2853 20110 -27525 26371 -11285 -58 3917 -12586 3370 5147 -9336 -13440 -735 -17989 11445 -4338 9595 -7942 25333 -8425 -7111 -4593 3372 526 -9104 -2988 17417 2494 20936 4984 11562 18780 10954 22319 -17366 -4924 -18223 13428 -16184 1179 -1708 9884 7557 -20837 -3707 112 26461 3979 27431 -15763 9243 -4733 22619 -12180 13111 5502 6539 8052 10813 -7360 13537 23410 -14051 12044 6798 20281 -275 14478 -20758 -978 -33953 9943 -13379 -2001 -24155 16802 -14958 -4686 -1313 5314 6899 -2959 19182 -8355 14807 -13927 2635 -7071 20994 3221 -4839 -11246 14670 7173 -17741 8466 6455 20137 2281 7384 8782 20127 -20430 13125 -12054 5351 -6133 21193 -8122 -9259 320 11552 2032 3254 3992 -3721 12811 -16791 8217 -1861 -4133 1769 -678 11157 4189 -8900 -4275 -6804 3907 14331 -5223 19550 -11807 -1833 -20031 13905 -11759 10928 -8789 18407 4605 -11110 SO 20161224T072336.0Z 6202.308056 444 1 32.00 2 88.16 127.94 57.65 176.00 0.00 1 0.00 1 0 15 7.594e-02 7.432e-02 7.722e-02 7.586e-02 3.722230e+03 4.404176e+03 4.066327e+01 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