File name: Pandora120s1_Davos_20161224_L2Fit_fwvt1c6d20160404p1-8.txt File generation date: 20260127T144452.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v6d20160404.txt Level 1 file used: Pandora120s1_Davos_20161224_L1_smca1c6d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20161224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.1047 492.2266 492.3485 492.4704 492.5923 492.7141 492.8359 492.9577 493.0795 493.2013 493.3231 493.4448 493.5665 493.6883 493.8100 493.9316 494.0533 494.1749 494.2966 494.4182 494.5398 494.6614 494.7829 494.9045 495.0260 495.1475 495.2690 495.3905 495.5120 495.6334 495.7549 495.8763 495.9977 496.1191 496.2404 496.3618 496.4831 496.6044 496.7257 496.8470 496.9683 497.0895 497.2108 497.3320 497.4532 497.5744 497.6955 497.8167 497.9378 498.0590 498.1801 498.3011 498.4222 498.5433 498.6643 498.7853 498.9063 499.0273 499.1483 499.2692 499.3902 499.5111 499.6320 499.7529 499.8738 499.9946 500.1155 500.2363 500.3571 500.4779 500.5986 500.7194 500.8401 500.9608 501.0816 501.2022 501.3229 501.4436 501.5642 501.6848 501.8054 501.9260 502.0466 502.1671 502.2877 502.4082 502.5287 502.6492 502.7697 502.8901 503.0105 503.1310 503.2514 503.3718 503.4921 503.6125 503.7328 503.8531 503.9734 504.0937 504.2140 504.3342 504.4545 504.5747 504.6949 504.8151 504.9352 505.0554 505.1755 505.2957 505.4158 505.5358 505.6559 505.7760 505.8960 506.0160 506.1360 506.2560 506.3759 506.4959 506.6158 506.7357 506.8556 506.9755 507.0954 507.2152 507.3351 507.4549 507.5747 507.6944 507.8142 507.9340 508.0537 508.1734 508.2931 508.4128 508.5324 508.6521 508.7717 508.8913 509.0109 509.1305 509.2500 509.3696 509.4891 509.6086 509.7281 509.8476 509.9670 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 99-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-396: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161224T071141.0Z 6202.299780 432 1 32.00 2 89.79 125.74 57.82 172.61 0.00 1 0.00 1 0 29 2.198e-01 1.734e-01 2.289e-01 2.091e-01 6.193913e+03 1.291366e+04 8.059069e+02 -6.000000e+00 1.098902e+04 262.36 -2.00 20.00 -2.00 505.26 0.00e+00 -4.930238e-03 5.465704e-03 3.323949e-04 -6.000000e+00 5.828312e-03 262.36 -2.00 20.00 -2.00 500.05 0.00e+00 1.076835e+00 4.178140e+00 1.020594e-01 -6.000000e+00 4.329393e+00 221.38 -2.00 3.62 -2.00 501.70 0.00e+00 20.796 0.179 489.00 513.00 1 1.0844e+01 3.1784e-01 3.3745e-02 -6.0000e+00 3.2933e-01 8.6689e-02 8.1927e-02 1.9322e-03 -6.0000e+00 8.6476e-02 3.1819e-06 6.5249e-03 1.7409e-02 1.6388e-04 -6.0000e+00 2.0233e-02 -1.3703e-02 2.4517e-05 12 8 8 10 0 0 5.67 14.57 10.78 -0.01370 0.03156 8 1 1 2 0 4000.000 15.26 14.57 19.64 19.75 8673 -8742 9114 -7099 10178 -12355 9416 -9868 59241 -15325 3555 -7821 3848 44916 2453 18285 -9330 -1895 -7908 2805 -6789 10297 10897 1103 1862 -9883 20623 -5510 18778 -20746 13444 -1281 32653 6682 28576 -3679 7732 -3624 867 -19284 22770 -11113 -4487 11726 -1715 4637 -960 -4284 -6146 -4036 -8305 -19845 -1683 15119 -2201 22888 -4741 10131 -11561 41304 33033 44270 12318 5270 28099 -20398 -2215 5651 6542 -16905 34817 -24903 2561 -21220 -19109 -272 21815 -7853 1469 20351 57811 -7207 27957 4625 -10092 11255 -9606 12480 8705 12143 -400 8726 -2876 22503 -5117 43701 -21439 -2138 26140 -3488 35828 -30086 -12985 -11661 -7987 13850 23155 22443 4009 -27553 8378 21919 25988 49220 40046 -13876 44615 86217 -25182 42440 -9937 30739 4877 35527 -20977 55239 10033 40315 -14073 -1336 -17675 28235 -2723 8873 -560 -5439 -4487 -8901 3082 -21470 -5703 17593 41107 -12341 18097 -22081 10048 43011 20393 7882 -9491 8809 -8107 10009 -15566 9693 -12382 37965 -19936 3787 -9213 3981 31380 2563 16576 -11468 -2232 -9838 3232 -8413 11022 11609 1268 2121 -12592 19166 -6497 16795 -26951 12427 -1401 26431 7245 25130 -4430 8191 -4237 958 -25303 20138 -13552 -5291 11835 -1932 4863 -1048 -4743 -6745 -4193 -8750 -23135 -1650 12906 -2308 19090 -5250 9636 -13590 28608 24974 30015 11476 5219 21792 -24684 -2258 5265 5967 -18927 23945 -30847 2452 -25982 -22669 -262 16919 -7931 1351 15610 31582 -7451 20645 4385 -11203 10135 -10663 11118 8087 10992 -415 8315 -2972 18011 -5122 26650 -23857 -1921 17933 -3183 23385 -39082 -14933 -13573 -8962 12317 18435 17868 3864 -36000 7880 18064 20570 30937 27781 -16298 29912 38611 -32214 27664 -10541 22184 4485 24646 -25020 31377 8724 26466 -15505 -1277 -19553 19538 -2566 7554 -538 -5621 -4677 -9847 3059 -26868 -6147 15458 28632 -14290 15571 -27141 8771 27413 16433 SO 20161224T071743.0Z 6202.303970 438 1 32.01 2 88.96 126.85 57.72 174.32 0.00 1 0.00 1 0 22 1.419e-01 1.295e-01 1.330e-01 1.272e-01 8.839394e+02 6.881193e+03 2.233642e+02 -6.000000e+00 7.090474e+03 262.36 -2.00 20.00 -2.00 505.18 0.00e+00 7.989088e-03 3.371027e-03 3.757203e-04 -6.000000e+00 3.759815e-03 262.36 -2.00 20.00 -2.00 499.97 0.00e+00 -2.883988e-01 2.598451e+00 9.238320e-02 -6.000000e+00 2.790561e+00 221.38 -2.00 3.62 -2.00 501.62 0.00e+00 19.081 0.138 489.00 513.00 1 1.0478e+01 1.9909e-01 2.9713e-02 -6.0000e+00 2.1229e-01 1.6188e-01 5.1519e-02 1.8945e-03 -6.0000e+00 5.5696e-02 5.3391e-06 5.4939e-03 1.1313e-02 1.3291e-04 -6.0000e+00 1.3049e-02 6.4578e-02 -3.9451e-04 12 8 8 10 0 0 5.33 14.56 -0.86 0.06458 0.10269 8 1 1 2 0 4000.000 15.05 14.56 19.54 19.75 21404 6485 5417 -13583 2618 -9308 5951 2492 21477 -20247 32845 -9578 -38 3931 -10868 3317 5047 -7887 -10891 -652 -14159 11667 -3769 9426 -6614 30780 -7071 -6170 -4208 3463 513 -8130 -2740 18966 2350 24114 4931 12094 21691 11642 26505 -13895 -4275 -14103 13640 -12677 1098 -1512 10363 7982 -17611 -3581 75 36365 3779 34901 -12744 9093 -4176 26383 -10043 13634 5289 6442 8210 11589 -6625 15506 32098 -12430 13803 7199 25536 -255 16925 -17476 -963 -27246 11521 -12444 -2012 -20564 21081 -13521 -4617 -1331 5899 7815 -3010 25434 -7836 17411 -12136 2729 -6626 29042 3313 -4953 -11177 20078 8564 -16228 9703 7234 28163 2554 8768 10516 28262 -18113 15855 -11010 5663 -5785 27729 -7460 -8457 379 13734 2218 3564 4355 -3756 15523 -15277 9371 -1899 -4125 1918 -650 14010 4908 -9258 -4684 -7134 4410 18126 -5338 26746 -11305 -1943 -17884 17709 -11264 13912 -9018 28614 5700 -11574 17731 6443 5651 -17640 2951 -12030 6654 2872 20132 -27498 26390 -11262 -39 3930 -12581 3366 5137 -9345 -13434 -725 -17982 11449 -4339 9594 -7938 25343 -8400 -7067 -4551 3388 517 -9139 -3031 17402 2502 20953 5001 11574 18782 10945 22306 -17391 -4945 -18238 13431 -16167 1205 -1673 9927 7599 -21154 -3707 76 26425 3934 27224 -15764 9250 -4730 22614 -12190 13113 5516 6569 8086 10844 -7331 13565 23432 -14044 12036 6778 20270 -263 14513 -20707 -951 -33940 9946 -13387 -2005 -24161 16794 -14967 -4680 -1300 5327 6903 -2974 19154 -8408 14787 -13915 2673 -7016 21048 3020 -4767 -11202 14666 7128 -17826 8433 6472 20172 2321 7397 8753 20083 -20508 13079 -12099 5330 -6149 21186 -8116 -9223 373 11595 2069 3256 3966 -3743 12805 -16796 8223 -1860 -4044 1800 -615 11208 4225 -8900 -4326 -6877 3858 14300 -5248 19546 -11817 -1852 -20050 13908 -11714 11001 -8694 18442 4585 -11190 SO 20161224T072336.0Z 6202.308056 444 1 32.00 2 88.16 127.94 57.65 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