File name: Pandora120s1_Davos_20161226_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251201T235612.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20161226_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20161226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161226T071210.0Z 6204.300116 464 1 32.01 2 89.82 125.61 68.06 150.86 0.00 1 0.00 1 0 22 1.029e-01 9.824e-02 1.075e-01 1.042e-01 6.302615e+03 6.498715e+03 2.026282e+02 -6.000000e+00 5.141375e+03 262.24 -2.00 20.00 -2.00 505.21 0.00e+00 2.985016e-03 2.685687e-03 1.818687e-04 -6.000000e+00 2.727628e-03 262.24 -2.00 20.00 -2.00 499.96 0.00e+00 1.581429e+00 2.120777e+00 2.012626e-01 -6.000000e+00 2.029305e+00 221.47 -2.00 3.62 -2.00 501.60 0.00e+00 20.828 0.180 489.00 513.00 1 4.4044e+00 1.6120e-01 3.5717e-02 -6.0000e+00 1.5433e-01 1.1179e-01 4.1735e-02 3.5284e-03 -6.0000e+00 4.0589e-02 1.7686e-03 -8.5809e-04 9.1627e-03 6.2890e-05 -6.0000e+00 9.4754e-03 -4.4609e-03 12 8 8 10 0 0 -2.85 14.83 6.96 -0.00446 -0.01041 8 1 1 2 0 4000.000 14.79 14.83 19.75 19.96 9520 -4006 22630 -11981 -3005 -11169 2389 571 9218 1565 -5203 -3211 7203 -4764 3196 3319 2239 14113 -6147 1492 -3523 18938 952 -8944 -8192 12819 -8019 7387 -5777 -2188 1115 458 6159 5911 9757 -11964 -8051 185 22579 -4983 14109 -4415 1282 -14671 18397 12046 24531 -7005 -618 6528 4959 9683 -10691 7877 -4287 -2252 -5208 4472 -9661 19638 -8234 17939 -9587 11577 908 -1793 -11639 18023 14936 -7514 11163 -15412 -1786 -859 6107 -9256 10170 -14191 1234 -7953 10249 -1322 3813 -1350 16120 4708 -4388 9994 -12251 20271 -4342 2417 -9828 7682 -14293 -4085 159 -2274 9955 8731 -8652 9111 1736 -524 -3104 2408 8011 -24616 7260 -1587 9386 -6179 20450 -444 30476 -976 12703 10905 3856 6069 12998 5742 -15451 18590 -14181 15047 -7143 6003 2487 7391 -12932 15449 10584 3299 -3176 11625 -8629 -8769 -2436 -5347 10131 -11108 -943 -14370 3293 10522 -1296 1938 13774 8602 -4233 19004 -14381 -3383 -13935 2647 648 9549 1723 -6025 -3590 7139 -5255 3239 3381 2347 13496 -7363 1668 -4141 17779 1071 -11181 -10220 12960 -9688 7708 -6502 -2298 1120 467 6124 6121 9938 -15124 -9668 201 19485 -5644 13273 -5055 1405 -19116 17352 12094 21527 -8293 -672 6411 4798 8757 -11550 7391 -4591 -2433 -5886 4598 -11401 17252 -9599 16185 -11404 11078 952 -1899 -13376 15192 12802 -7958 9781 -17748 -1819 -878 5800 -9836 8911 -15279 1131 -7990 8633 -1258 3468 -1306 13204 4326 -4399 8627 -13190 15852 -4403 2327 -10741 6952 -15721 -3944 143 -2037 7716 6787 -7930 7399 1552 -494 -3029 2202 6816 -28763 6210 -1509 8135 -6337 16193 -435 22057 -976 11154 9699 3622 5467 10735 5067 -16599 14636 -15203 12057 -7134 5249 2252 6316 -13290 11761 8386 2819 -2946 9521 -8810 -9089 -2395 -5448 8882 -12106 -932 -15858 3077 8945 -1209 1721 10883 SO 20161226T071815.0Z 6204.304340 470 1 32.00 2 88.98 126.73 67.58 152.32 0.00 1 0.00 1 0 15 6.023e-02 5.977e-02 6.721e-02 6.595e-02 2.345831e+03 3.710097e+03 1.994351e+02 -6.000000e+00 3.009518e+03 262.24 -2.00 20.00 -2.00 505.18 0.00e+00 1.582778e-03 1.703862e-03 7.286749e-05 -6.000000e+00 1.596694e-03 262.24 -2.00 20.00 -2.00 499.88 0.00e+00 1.431659e+00 1.341668e+00 2.173685e-02 -6.000000e+00 1.188012e+00 221.47 -2.00 3.62 -2.00 501.54 0.00e+00 19.118 0.139 489.00 513.00 1 4.1812e+00 1.0252e-01 2.7720e-02 -6.0000e+00 9.0346e-02 1.1862e-01 2.6738e-02 1.5923e-03 -6.0000e+00 2.3765e-02 2.8311e-03 -1.9341e-03 5.8074e-03 3.7417e-05 -6.0000e+00 5.5470e-03 -5.8471e-03 12 8 8 10 0 0 -2.14 14.83 0.56 -0.00585 -0.01926 8 1 1 2 0 4000.000 14.96 14.83 19.75 19.96 -1537 -5871 4213 -4376 600 1440 4494 -603 2429 5955 1248 -6042 5202 -10066 7687 2788 -5102 4408 -434 7538 -8429 -528 -7401 2197 -4424 9615 -505 4470 -15081 1486 546 -92 886 -662 4744 1379 -246 -4859 6594 2789 16117 -2850 15323 -9253 6144 -3586 3449 9330 3252 1008 3157 2048 9629 7518 -10112 9935 -5534 5079 -1190 -2597 -5124 6420 -2723 -658 9353 7720 -1372 -1983 -10046 5813 -4463 4425 -8786 -8359 -896 -3939 80 -1381 -6569 -8982 -6995 -1482 4388 814 4388 -9712 3389 8933 7002 5941 2057 -2104 6592 10097 -2236 6031 -9637 1778 -7862 5055 -10953 -7468 1466 3178 4180 -5168 5262 923 -1285 -300 7305 -2644 6456 513 6730 6393 -5389 1186 -5310 -1967 3969 770 14024 4052 -115 1998 -5232 194 -2662 7294 13517 279 6017 11028 -10096 -2590 3489 2389 1228 3091 -1714 -5674 -5897 -4009 -5466 663 799 -7000 5756 -1541 -6264 4210 -4938 661 1607 4951 -704 2740 6391 1381 -7084 5362 -11928 7583 2904 -5713 4724 -488 7897 -10361 -600 -9006 2440 -5274 9954 -575 4765 -18954 1529 560 -96 940 -741 5144 1546 -278 -5650 6756 2883 14975 -3156 14321 -11192 6416 -4122 3659 9183 3327 1024 3041 1951 8464 6880 -11410 9450 -6245 5167 -1283 -2833 -5751 6453 -2935 -691 8966 7221 -1382 -1983 -10739 5233 -4437 4054 -9314 -8936 -889 -3956 76 -1304 -6492 -9100 -6995 -1412 3969 771 4046 -10109 3160 7858 6143 5297 1932 -2093 6057 8887 -2186 5308 -9658 1547 -7360 4116 -10584 -7184 1342 2943 3847 -5157 4646 842 -1203 -282 6492 -2577 5804 492 6097 5845 -5556 1136 -5340 -1878 3518 701 11247 3614 -107 1821 -5115 180 -2531 6229 10651 247 4961 8643 -9715 -2367 3060 2148 1128 2800 -1635 -5663 -5926 -3951 -5410 603 707 -6563 4747 SO 20161226T072411.0Z 6204.308461 476 1 32.01 2 88.17 127.83 67.14 153.75 0.00 1 0.00 1 0 22 5.340e-02 5.155e-02 5.927e-02 5.829e-02 5.443801e+03 3.560815e+03 3.243932e+02 -6.000000e+00 2.668067e+03 262.24 -2.00 20.00 -2.00 505.21 0.00e+00 -4.544378e-04 1.512018e-03 6.072862e-05 -6.000000e+00 1.415443e-03 262.24 -2.00 20.00 -2.00 499.96 0.00e+00 -1.838652e-01 1.179869e+00 5.574848e-02 -6.000000e+00 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