File name: Pandora120s1_Davos_20170425_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T000340.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20170425_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20170425 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170425T042201.0Z 6324.181956 357 1 32.00 2 89.78 70.70 87.38 89.17 0.00 1 0.00 1 0 43 5.509e-01 3.033e-01 4.402e-01 3.078e-01 2.651238e+04 2.539843e+04 3.271102e+02 -6.000000e+00 2.828611e+04 268.65 -2.00 20.00 -2.00 505.07 0.00e+00 -5.268950e-03 7.800000e-03 2.292696e-04 -6.000000e+00 1.481795e-02 268.65 -2.00 20.00 -2.00 499.54 0.00e+00 -9.952358e+00 6.614573e+00 3.640602e-02 -6.000000e+00 1.090542e+01 228.09 -2.00 3.62 -2.00 501.22 0.00e+00 20.603 0.174 489.00 513.00 1 6.3482e+00 4.9535e-01 3.2287e-02 -6.0000e+00 8.3053e-01 3.7165e-01 1.3574e-01 1.8535e-03 -6.0000e+00 2.1816e-01 5.6922e-04 -9.1828e-02 2.1810e-02 9.8836e-05 -6.0000e+00 5.0733e-02 5.1363e-03 12 12 8 10 0 0 -2.19 15.23 17.52 0.00514 -0.63182 8 1 1 2 0 4000.000 15.11 15.23 20.04 20.35 96119 -4088 64811 230 -3576 -11370 30288 -19242 -29817 42159 134 7863 22747 91721 -13061 67829 29331 147621 28379 -3086 1650 -17406 49535 15153 6938 -18866 15054 -37669 32305 -17007 36466 -22075 36326 -18397 27983 6919 32424 44638 9127 34102 -12472 12913 -2876 52430 24473 68433 -24625 -8336 -23576 82841 11105 63260 35594 37177 -5398 22720 2731 -14103 123925 25962 -11180 -16246 21168 -26140 43947 -15421 36394 -36141 164703 -15523 81799 29919 69483 13769 -8126 79283 -22011 32273 3475 81599 -34494 144479 27459 84885 -23377 119989 -6453 40015 30144 12313 -17009 61075 -19979 -4179 77767 -3015 122027 -7221 53928 -26073 121376 31530 88315 -26626 36690 -1045 78019 30291 -162 -28537 -20527 47546 -9096 48251 -19176 31700 39650 4626 -10680 31595 21965 -1972 92680 77841 61551 35713 8425 -28497 17914 -9103 50441 -29222 71235 -14862 65761 -41795 18238 32913 101573 8159 57574 11153 17354 914 48305 2689 12028 298031 -32099 51111 -5690 44751 281 -4369 -14859 26467 -27710 -49234 35536 171 9426 24275 50228 -19104 44585 27898 44521 26335 -3793 1941 -25197 38689 16681 8369 -28726 16685 -68717 29959 -25145 32168 -33775 31223 -25846 24474 7356 26892 33656 9937 30340 -17247 13678 -3512 37159 22142 40761 -36409 -10546 -35031 43722 11681 40065 28538 28714 -6194 19052 2732 -16204 39291 21580 -13567 -21114 19463 -37541 32003 -19932 28912 -58132 49673 -20064 40314 23847 37822 12656 -9219 38491 -29082 25260 3693 40815 -51774 43573 21886 38713 -30004 38835 -7151 29021 24675 12004 -22428 37716 -26905 -4778 40206 -3447 42187 -8559 34077 -33831 36605 21282 32976 -30253 22657 -946 34734 22945 -174 -42445 -28421 33681 -10910 33165 -25368 25791 29477 4692 -12444 24597 18669 -2176 40952 39309 35399 24968 7507 -35523 14366 -9547 29717 -36232 33475 -15638 31825 -55181 13251 20529 32770 6655 29202 9097 13441 827 28143 2433 9915 89882 -40443 SO 20170425T042804.0Z 6324.186157 363 1 32.00 2 88.80 71.80 86.36 90.22 0.00 1 0.00 1 0 29 2.684e-01 2.199e-01 2.534e-01 2.236e-01 1.744914e+04 1.638211e+04 1.763593e+03 -6.000000e+00 1.378304e+04 268.65 -2.00 20.00 -2.00 505.24 0.00e+00 -7.943373e-03 5.827076e-03 2.757885e-04 -6.000000e+00 7.216158e-03 268.65 -2.00 20.00 -2.00 499.96 0.00e+00 -3.048646e+00 4.545476e+00 8.804223e-02 -6.000000e+00 5.296241e+00 228.09 -2.00 3.62 -2.00 501.62 0.00e+00 18.522 0.126 489.00 513.00 1 5.8326e+00 3.4516e-01 2.7707e-02 -6.0000e+00 4.0355e-01 1.5419e-01 8.7637e-02 1.5202e-03 -6.0000e+00 1.0563e-01 8.2810e-04 2.3038e-02 1.7013e-02 1.7340e-04 -6.0000e+00 2.4670e-02 3.9031e-02 12 8 8 10 0 0 80.08 15.23 15.31 0.03903 0.19883 8 1 1 2 0 4000.000 15.05 15.23 20.14 20.35 17160 -21171 13200 9353 50708 -13645 15312 24234 -6764 5 -11047 22886 2593 42674 -32026 67720 -20458 4047 -4469 40711 11559 25537 14030 12035 2043 14605 -2382 8096 14664 -28725 12715 -11789 11515 -17538 17739 -30077 13574 -2579 31134 -1229 17784 7269 23516 26232 -14529 18826 -2803 4301 -12920 13633 -19367 13989 21624 -7926 -4124 -2238 8547 -7776 -21706 18425 11924 -4559 71054 -20715 25779 23357 49199 -21952 5009 -17137 35182 21506 60459 7339 -6620 -19795 26630 -29684 1450 26244 31985 20925 8618 35202 -30999 30611 10805 42631 -31270 45696 -5802 8926 -4829 26244 5548 6679 -4152 -13354 57964 2932 11102 -7412 34310 -31393 60134 17013 19074 -4787 70873 9571 46594 -2628 4548 39493 -4723 61398 -7322 22142 -9367 16897 -39525 46489 -41836 32 -5321 54535 -24882 7211 21586 19973 79996 -3271 9710 12900 20243 9119 44000 -7939 26572 -284 -111 -8583 63497 -14292 29188 -4063 -15903 4318 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1.712e-01 2.137e-01 1.955e-01 9.356051e+03 1.335003e+04 6.272917e+02 -6.000000e+00 1.073602e+04 268.65 -2.00 20.00 -2.00 505.24 0.00e+00 -6.208446e-03 5.104874e-03 2.525419e-04 -6.000000e+00 5.618560e-03 268.65 -2.00 20.00 -2.00 499.73 0.00e+00 3.353875e+00 3.963127e+00 2.252435e-01 -6.000000e+00 4.146475e+00 228.09 -2.00 3.62 -2.00 501.44 0.00e+00 15.822 0.079 489.00 513.00 1 5.5474e+00 3.0220e-01 2.7093e-02 -6.0000e+00 3.1601e-01 3.2346e-02 7.5821e-02 3.2990e-03 -6.0000e+00 8.3183e-02 9.4899e-04 6.1163e-02 1.6343e-02 8.8794e-05 -6.0000e+00 1.9289e-02 -2.1467e-02 12 8 8 10 0 0 -2.61 15.23 10.89 -0.02147 0.40278 8 1 1 2 0 4000.000 14.86 15.23 20.14 20.35 -30249 28660 17139 14512 28450 1493 5072 9438 8223 -8430 5222 -11719 30555 -19322 7320 -13128 55922 -20064 19514 -16483 10747 31117 14918 41364 -9325 8063 -4220 8725 -13283 29277 -9103 5001 -1996 16733 -15794 9199 -9405 3213 -1673 -8296 23930 323 -9053 -5659 25714 11649 48958 -5105 47013 -25220 11794 -20836 21925 -6907 -8482 -2616 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