File name: Pandora120s1_Davos_20170504_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T000530.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20170504_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20170504 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170504T040744.0Z 6333.172037 310 1 32.00 2 89.78 66.50 114.04 322.38 0.00 1 0.00 1 0 34 7.719e-01 3.750e-01 5.195e-01 3.687e-01 2.162557e+04 2.748877e+04 2.347622e+03 -6.000000e+00 3.989925e+04 269.87 -2.00 20.00 -2.00 505.43 0.00e+00 -1.675035e-03 1.011999e-02 4.884798e-04 -6.000000e+00 2.082820e-02 269.87 -2.00 20.00 -2.00 500.05 0.00e+00 6.996134e+00 7.395208e+00 8.225708e-02 -6.000000e+00 1.531292e+01 228.96 -2.00 3.62 -2.00 501.73 0.00e+00 20.571 0.173 489.00 513.00 1 5.2119e+00 5.6739e-01 3.4350e-02 -6.0000e+00 1.1663e+00 -5.7318e-02 1.4167e-01 3.3092e-03 -6.0000e+00 3.0675e-01 4.6552e-04 -7.6686e-03 2.8776e-02 2.5304e-04 -6.0000e+00 7.1172e-02 -8.7809e-03 12 8 8 10 0 0 2.97 14.96 15.65 -0.00878 -0.06197 8 1 1 2 0 4000.000 15.07 14.96 19.85 20.14 8613 18291 -11411 40820 -5782 47824 -39866 43209 -15070 49120 -4415 74009 42009 31705 17836 14585 -5937 -24276 2408 -14325 44303 -2829 71712 -19444 67097 -22639 90375 -13774 110775 19924 -1380 20142 23445 32255 48286 -18988 4113 65755 -14031 109668 1105 95863 -23790 128560 -13033 126913 -29151 23497 -28325 49288 -10914 2995 24798 -8364 24579 -9407 185867 -11508 282527 -2104 96642 74353 71502 -12286 43490 -2716 176051 5663 -2232 46334 40441 30244 21838 55050 -54402 52624 -9843 110561 -27589 66954 -29571 38461 27394 16104 -7694 27467 -14168 3775 17750 -5023 52767 31962 28298 2780 470846 -17131 76180 -36590 207954 -28890 6976 -13244 14648 65109 10567 27927 4085 134755 -52943 21455 41849 223892 -19661 900000 25551 30399 -17019 6119 6716 35757 -11905 1723 4055 7778 36354 -28056 27483 29715 97095 -33388 109246 4865 174961 -19259 25265 19374 30647 -29724 34831 1588 25869 112056 22331 9563 -23957 3875 -21899 285990 -3753 8187 15994 -13527 30651 -6962 35455 -69115 34909 -21353 37350 -5519 42910 32291 26719 17179 14588 -7237 -36606 2870 -20566 36516 -3652 45161 -29847 44740 -36183 47707 -19900 47380 19430 -1633 19279 22228 29125 38368 -29105 5088 44454 -19777 46720 1324 47053 -37094 46433 -18600 47014 -48535 23338 -45164 36049 -13749 3193 21496 -9947 21652 -12016 67132 -15410 102043 -2540 44504 42968 42611 -16059 32948 -3130 63586 5937 -2438 31429 28857 23978 19045 34917 -98703 33841 -11258 39932 -36300 34799 -39416 26767 20966 13988 -8602 21730 -16936 3734 15111 -5357 32539 23913 21902 2701 170060 -17987 31541 -43335 75109 -30818 5399 -12793 11715 33594 9586 21581 3980 48671 -87788 17480 28791 80865 -23886 900000 20174 23236 -20956 6219 6615 26430 -13486 1669 3828 7151 25955 -37539 21700 22963 39244 -46360 39458 4592 63192 -23397 20117 16857 24403 -43182 27734 1759 23358 44237 21264 10131 -35380 4292 -30935 103294 -4368 SO 20170504T041354.0Z 6333.176319 316 1 32.00 2 88.81 67.61 114.66 323.81 0.00 1 0.00 1 0 36 3.951e-01 3.058e-01 3.450e-01 2.757e-01 -1.890838e+04 1.478395e+04 7.598907e+02 -6.000000e+00 2.039570e+04 269.87 -2.00 20.00 -2.00 505.20 0.00e+00 1.555671e-02 7.304631e-03 6.508023e-04 -6.000000e+00 1.067575e-02 269.87 -2.00 20.00 -2.00 499.89 0.00e+00 6.326573e+00 5.737067e+00 2.480966e-01 -6.000000e+00 7.871238e+00 228.96 -2.00 3.62 -2.00 501.56 0.00e+00 18.528 0.127 489.00 513.00 1 5.0465e+00 4.3369e-01 3.6450e-02 -6.0000e+00 5.9906e-01 2.9949e-02 1.2052e-01 4.4670e-03 -6.0000e+00 1.5847e-01 6.5398e-04 -2.7148e-02 2.0084e-02 1.8112e-04 -6.0000e+00 3.6473e-02 -7.0197e-02 12 8 8 10 0 0 -6.76 14.97 12.29 -0.07020 -0.25851 8 1 1 2 0 4000.000 15.16 14.97 19.96 20.14 68069 38798 -11319 15767 28485 15691 34302 -27492 46316 -30137 51854 -13814 37339 -2798 106413 -3658 -13054 2034 5215 -6219 -12179 32741 -17831 58731 4387 6255 -12693 23070 -23850 20472 -23616 38768 14218 54170 -29595 14115 6699 33371 7978 -30650 4447 -4568 30946 -3093 54610 22785 57148 -17766 41132 -21944 125872 -20650 -4488 10894 20650 -17754 30752 18147 17282 9121 -7769 51581 -19854 55467 18101 31750 -30282 26092 13971 39854 15926 50988 7325 -6871 21400 -8620 41158 22933 46716 -27622 94912 -9878 11768 -12543 64086 -5078 -20462 10896 8319 -38190 91380 30447 -23050 40284 13631 23288 -6784 55294 13725 23477 9685 120321 -16480 53632 -8897 89207 23813 9144 26176 -18132 -16742 -13801 16541 11128 2433 -2051 50989 -16997 48503 -9263 53551 -12946 41765 93224 72713 36759 38823 32853 43778 24921 -78224 26617 -18072 52521 -20491 89696 46667 66459 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20170504T041953.0Z 6333.180475 322 1 32.00 2 87.86 68.69 115.24 325.22 0.00 1 0.00 1 0 127 2.425e-01 1.953e-01 2.389e-01 2.139e-01 1.941830e+04 1.573682e+04 3.627201e+02 -6.000000e+00 1.251546e+04 269.87 -2.00 20.00 -2.00 505.18 0.00e+00 -3.474975e-03 5.549522e-03 1.780638e-04 -6.000000e+00 6.539633e-03 269.87 -2.00 20.00 -2.00 499.84 0.00e+00 1.179076e+00 4.165140e+00 9.181380e-02 -6.000000e+00 4.796252e+00 228.96 -2.00 3.62 -2.00 501.52 0.00e+00 15.909 0.080 489.00 513.00 1 5.7153e+00 3.1883e-01 2.2574e-02 -6.0000e+00 3.6545e-01 6.1836e-02 7.6944e-02 2.1814e-03 -6.0000e+00 9.5857e-02 8.7362e-04 9.1836e-02 1.6527e-02 8.7662e-05 -6.0000e+00 2.2321e-02 1.7293e-02 12 12 8 10 0 0 -4.55 14.98 16.83 0.01729 0.65431 8 1 1 2 0 4000.000 14.82 14.98 19.96 20.14 37669 225 66076 -5610 20698 9435 50154 -12940 -17821 -3540 -8299 20322 1434 -3554 -14826 24920 -23953 17613 -16070 974 -2519 17951 -2836 1426 -3671 16419 -10725 2117 45752 21132 24110 2505 -3307 -4469 16467 -26750 33539 16372 37134 -1214 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