File name: Pandora120s1_Davos_20170509_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T000658.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20170509_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20170509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170509T040035.0Z 6338.167072 247 1 32.00 2 89.79 64.36 94.95 263.71 0.00 1 0.00 1 0 29 2.171e-01 1.852e-01 1.999e-01 1.814e-01 4.079547e+03 1.158755e+04 9.215940e+02 -6.000000e+00 1.123783e+04 270.55 -2.00 20.00 -2.00 505.13 0.00e+00 -2.947093e-03 4.899425e-03 7.744184e-05 -6.000000e+00 5.867392e-03 270.55 -2.00 20.00 -2.00 499.79 0.00e+00 -1.202490e+00 3.819390e+00 1.806671e-01 -6.000000e+00 4.285144e+00 229.44 -2.00 3.62 -2.00 501.46 0.00e+00 20.558 0.173 489.00 513.00 1 5.2093e+00 2.9131e-01 3.4162e-02 -6.0000e+00 3.2656e-01 2.0317e-01 7.6721e-02 2.7613e-03 -6.0000e+00 8.5654e-02 1.0370e-03 -4.1737e-02 1.5964e-02 1.7469e-04 -6.0000e+00 2.0014e-02 1.7062e-01 12 8 8 10 0 0 -3.93 15.07 6.13 0.17062 -0.11888 8 1 1 2 0 4000.000 15.01 15.07 19.96 20.25 -5839 -5295 10088 -13296 11388 -4543 20182 -2638 1245 -10693 12249 -17786 14925 22055 18904 -8719 -6073 20929 1886 -286 -17402 20455 -7006 -6773 -6581 25885 -4303 34289 -17344 26058 39146 34738 -1163 -10543 20836 -3669 -2280 -8533 25018 -7674 37354 -23818 31980 12882 -5072 7768 30391 -15096 -3609 7151 -11477 -8263 41124 35852 -16184 37744 -22065 7568 -13482 10056 -27522 51326 29320 18827 6076 27259 5021 19328 -10265 20956 3867 6189 35738 -19957 38066 -1372 -9533 10697 64410 -34107 12280 -8450 -1298 43149 17338 10854 -4018 504 -20695 -22433 -29381 51035 -8711 18777 -5156 36686 -25596 55415 3804 2428 3663 28098 13674 -946 9277 5401 44454 99 41211 -6243 34642 -16769 13317 -2143 29100 -32954 25764 11089 13785 11020 -13858 20739 21598 37455 300 11852 -8475 29363 -26451 29790 -17419 25430 569 -7535 5440 15876 3948 13321 4271 5184 12132 -1197 146 -23330 14437 -14143 29327 -15856 900000 -6510 -5856 9768 -16831 11634 -5570 19722 -3292 1505 -14487 13004 -25122 14982 20279 17717 -10728 -7337 19708 2158 -342 -24886 20533 -9016 -8688 -8442 24004 -5371 28826 -23976 22584 29559 26494 -1285 -13204 19774 -4532 -2766 -10613 22442 -9187 28974 -33250 26330 12951 -6007 8116 25813 -19477 -4076 7079 -13255 -8948 27265 25013 -18964 26664 -29122 7523 -16540 9699 -37640 32785 23442 16725 6092 21794 4928 16189 -11155 16843 3563 5575 24794 -23996 26569 -1383 -10241 9193 32696 -45096 10250 -8763 -1266 27278 14399 9732 -4200 504 -24986 -27628 -39033 31420 -9637 16137 -5413 25314 -31317 29995 3287 2089 3106 19504 11153 -936 8541 5191 28541 97 26459 -6453 24060 -19266 11669 -2149 21856 -45148 20183 9851 12079 9529 -15046 15995 16396 24350 277 9733 -8499 20056 -31434 20112 -18637 17370 490 -6962 4425 11847 3398 10624 3777 4585 10059 -1114 135 -27303 11799 -14858 19916 -16107 900000 SO 20170509T040718.0Z 6338.171736 253 1 32.00 2 88.75 65.57 96.07 264.87 0.00 1 0.00 1 0 8 1.059e-01 9.699e-02 1.085e-01 1.045e-01 -5.002081e+02 5.866439e+03 4.105266e+01 -6.000000e+00 5.481442e+03 270.55 -2.00 20.00 -2.00 505.23 0.00e+00 4.829798e-04 2.783573e-03 1.772826e-05 -6.000000e+00 2.861467e-03 270.55 -2.00 20.00 -2.00 499.79 0.00e+00 4.886766e+00 2.153873e+00 1.460712e-02 -6.000000e+00 2.097134e+00 229.44 -2.00 3.62 -2.00 501.48 0.00e+00 18.344 0.123 489.00 513.00 1 4.4298e+00 1.6506e-01 2.6040e-02 -6.0000e+00 1.5980e-01 4.9178e-02 4.2414e-02 1.4721e-03 -6.0000e+00 4.1950e-02 1.8554e-03 -4.9459e-04 9.2953e-03 1.3293e-05 -6.0000e+00 9.7541e-03 8.7650e-03 12 8 8 10 0 0 94.03 15.06 6.59 0.00876 0.00533 8 1 1 2 0 4000.000 15.16 15.06 19.96 20.25 6412 -17890 20202 -1021 -3907 -5123 15105 -10427 -2559 7696 1356 11029 -8115 -3942 -19552 1083 -3995 7094 3622 3267 -7320 6529 -755 7472 11101 2338 4470 -1495 6787 -308 -2974 4368 14593 -4616 -3170 -6359 2768 -6478 12059 -3801 -3262 11552 10482 6603 -9535 648 9829 10683 -6317 -7382 -12907 -6119 4707 10063 -7268 6568 2358 15496 1948 22494 -7741 2458 525 -309 7055 4410 6184 2748 -10539 -10523 6660 -18125 5119 1338 23587 507 -704 -8657 -6560 12854 -4182 16217 -4925 6746 -5603 8994 -7891 4210 6006 -3662 -3289 7631 2383 7957 -6038 15535 -4412 -3385 -10082 8522 17978 -18873 35926 -14140 -3576 346 23712 -9916 6928 4125 25605 -781 7843 9056 -2391 2261 -6438 -7506 -2952 22331 -2126 23798 -10707 -10321 -14675 -5591 2200 5591 -43 10469 26935 61 13829 11836 -337 -2809 7934 -22032 13802 -8291 -4036 -9438 22193 -6806 15896 -7046 9820 2403 -10745 6004 -21877 17521 -1133 -4577 -6061 15225 -13325 -3008 8048 1489 10846 -9520 -4389 -25376 1154 -4577 7490 4051 3693 -9208 7154 -891 8168 11748 2696 5010 -1746 7064 -333 -3202 4535 14132 -5488 -3784 -7809 3062 -7750 11841 -4352 -3727 11483 10650 7047 -12011 734 10034 10620 -7265 -8310 -14529 -6455 4450 9218 -7991 6456 2447 14088 2017 18897 -8824 2538 552 -325 6783 4271 5784 2623 -11311 -11144 5928 -20834 4727 1296 18187 482 -663 -8516 -6285 10401 -3948 12852 -4743 5837 -5525 7677 -7965 3760 5280 -3569 -3236 6833 2261 7087 -6095 12393 -4186 -3094 -9637 6719 13087 -20042 23395 -15145 -3432 314 17096 -9696 5766 3593 18342 -740 6902 7929 -2360 2139 -6632 -7732 -2860 16555 -1992 17209 -10790 -10424 -15507 -5398 1963 4826 -40 8547 18743 53 10460 9163 -301 -2637 6830 -25977 11483 -8651 -4058 -10099 17428 -7147 13155 -7163 8214 2133 -10691 SO 20170509T041323.0Z 6338.175961 259 1 32.01 2 87.79 66.67 97.09 265.93 0.00 1 0.00 1 0 29 7.801e-02 7.698e-02 8.591e-02 8.358e-02 4.682256e+03 5.320056e+03 3.467803e+02 -6.000000e+00 4.037864e+03 270.55 -2.00 20.00 -2.00 505.23 0.00e+00 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