File name: Pandora120s1_Davos_20171218_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T003101.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20171218_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20171218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171218T071144.0Z 6561.299815 4 1 32.00 2 89.35 126.31 87.42 123.66 0.00 1 0.00 1 0 15 5.782e-02 5.812e-02 7.309e-02 7.172e-02 -4.133277e+03 3.801760e+03 1.415192e+02 -6.000000e+00 2.894934e+03 262.79 -2.00 20.00 -2.00 505.19 0.00e+00 1.863394e-03 1.865289e-03 1.113217e-04 -6.000000e+00 1.534322e-03 262.79 -2.00 20.00 -2.00 499.88 0.00e+00 2.601492e+00 1.468973e+00 7.993828e-02 -6.000000e+00 1.137614e+00 221.06 -2.00 3.62 -2.00 501.56 0.00e+00 19.993 0.159 489.00 513.00 1 4.0844e+00 1.1216e-01 3.0609e-02 -6.0000e+00 8.6552e-02 1.1541e-01 2.9359e-02 2.1538e-03 -6.0000e+00 2.2721e-02 2.6040e-03 -2.3800e-03 6.4898e-03 4.0845e-05 -6.0000e+00 5.3205e-03 1.2026e-02 12 8 8 10 0 0 85.80 13.74 -2.33 0.01203 -0.00448 8 1 1 2 0 4000.000 15.38 13.74 19.04 19.04 -1939 756 -115 4193 3432 -4737 7856 5297 -7928 2239 6783 -14273 6471 -1277 2118 2811 4873 -7877 -7049 -1650 -1963 -3862 -1155 5073 -11120 -5045 4201 13140 -5329 2734 -803 -1162 1926 4886 5659 9357 -5797 2087 7598 -1843 -7308 -2413 7293 7813 4636 -8893 4176 158 15418 9121 2706 -3516 4215 5296 2856 657 655 3711 -4252 5555 1581 -4058 -6956 7271 -2676 1794 -9785 -2708 -7183 8568 852 -11357 2996 -2030 1236 -3886 2429 4374 -8025 -5958 5345 2718 8124 -1375 3263 1083 9568 2645 -188 1048 15 1208 -2807 90 -215 37 6053 10726 -2801 -1121 -14080 2488 5951 -1929 5227 1956 434 2780 6754 4323 288 -811 -484 -7442 1514 -3745 4370 -4524 -6552 -8508 -3936 -1432 11744 14294 7557 -4488 6034 2605 10015 -2613 -9317 1826 -27 -3196 -1318 -728 -6428 245 -6172 8902 -4368 5809 -3685 10821 3107 -2754 2781 -3040 -5878 -1958 759 -121 4369 3693 -5650 8401 5846 -9931 2494 7102 -18174 6587 -1387 2214 2938 5086 -9370 -8502 -1899 -2266 -4542 -1324 5491 -14212 -6060 4568 12838 -6062 2776 -836 -1227 2033 5198 6097 9689 -6896 2262 7703 -2044 -8394 -2665 7400 7979 4916 -10768 4387 170 13906 8495 2605 -3528 3906 4959 2832 685 693 3808 -4703 5555 1650 -4503 -7765 7153 -2799 1762 -10610 -2698 -7375 7415 795 -12060 2794 -2013 1182 -3841 2207 3848 -7958 -5804 4686 2461 7006 -1316 3001 1020 8281 2454 -180 977 14 1161 -2844 88 -211 36 5397 8876 -2589 -1008 -14554 2234 5315 -1888 4718 1787 395 2444 5747 3841 272 -793 -469 -7798 1457 -3799 4058 -4526 -6575 -8590 -3764 -1336 9687 11550 6534 -4373 5281 2360 8429 -2475 -9264 1593 -23 -2880 -1183 -666 -6217 224 -6071 7546 -4238 5123 -3597 9140 2801 -2565 2378 -2704 -5387 SO 20171218T071239.0Z 6561.300451 5 1 32.01 2 89.22 126.48 87.29 123.83 0.00 1 0.00 1 0 22 7.269e-02 6.986e-02 7.223e-02 7.049e-02 5.920255e+02 3.816416e+03 1.661825e+02 -6.000000e+00 3.639834e+03 262.79 -2.00 20.00 -2.00 505.23 0.00e+00 -4.387982e-04 1.827572e-03 3.383465e-05 -6.000000e+00 1.928858e-03 262.79 -2.00 20.00 -2.00 499.86 0.00e+00 2.887274e+00 1.423664e+00 5.489834e-02 -6.000000e+00 1.429554e+00 221.06 -2.00 3.62 -2.00 501.54 0.00e+00 19.713 0.152 489.00 513.00 1 4.0993e+00 1.0841e-01 2.9413e-02 -6.0000e+00 1.0877e-01 9.2869e-02 2.8179e-02 1.7604e-03 -6.0000e+00 2.8538e-02 2.6465e-03 5.3250e-03 6.2518e-03 2.5554e-05 -6.0000e+00 6.6876e-03 1.7103e-02 12 8 8 10 0 0 1.84 13.74 -1.30 0.01710 0.05404 8 1 1 2 0 4000.000 15.34 13.74 19.04 19.04 -416 -8166 3190 -9032 4096 -11507 12197 -9438 6324 -3636 6121 -7494 -1822 4649 -790 5419 426 18318 -4309 9784 -2137 3351 -3276 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1272 -6733 5935 -204 399 2916 11058 6684 1412 1377 -1256 6210 -3718 7529 -14271 -7464 -7937 9945 -11461 -890 -4122 4460 9848 16712 -5142 7792 -656 7449 3280 6075 4106 -5624 1154 -16380 8308 -5545 1677 -9325 4835 -3468 7559 -5596 -2134 801 2648 5399 155 -298 527 1176 -7057 10159 -5952 5668 -2066 2402 -371 11767 -1608 -238 -3897 9573 1011 -5714 6159 -2405 3402 -3390 13278 -9843 3767 -7931 -1248 -4615 13026 -5168 -3025 -303 2206 320 1729 -848 -5882 8006 -15145 5115 -4143 2159 -9387 7042 9953 9333 -18628 6031 SO 20171218T071333.0Z 6561.301076 6 1 32.01 2 89.10 126.65 87.17 124.00 0.00 1 0.00 1 0 22 7.757e-02 7.370e-02 6.938e-02 6.777e-02 1.464069e+03 3.752008e+03 1.203747e+02 -6.000000e+00 3.884041e+03 262.79 -2.00 20.00 -2.00 505.18 0.00e+00 2.243327e-03 1.773161e-03 1.779987e-04 -6.000000e+00 2.058924e-03 262.79 -2.00 20.00 -2.00 499.91 0.00e+00 1.686481e+00 1.383952e+00 3.187985e-02 -6.000000e+00 1.528415e+00 221.06 -2.00 3.62 -2.00 501.56 0.00e+00 19.419 0.146 489.00 513.00 1 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