File name: Pandora120s1_Davos_20180218_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T003811.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20180218_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20180218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180218T062650.0Z 6623.268634 480 1 32.01 2 89.74 107.41 103.69 82.80 0.00 1 0.00 1 0 29 2.911e-01 2.233e-01 2.602e-01 2.207e-01 7.631995e+03 1.526256e+04 2.225465e+03 -6.000000e+00 1.449551e+04 261.26 -2.00 20.00 -2.00 505.24 0.00e+00 -9.000679e-03 5.869083e-03 4.417573e-04 -6.000000e+00 7.697045e-03 261.26 -2.00 20.00 -2.00 499.54 0.00e+00 4.261980e+00 4.631166e+00 3.436452e-01 -6.000000e+00 5.762341e+00 223.87 -2.00 3.62 -2.00 501.23 0.00e+00 20.733 0.177 489.00 513.00 1 5.1180e+00 3.4969e-01 4.0995e-02 -6.0000e+00 4.3797e-01 6.9172e-02 9.1011e-02 3.8625e-03 -6.0000e+00 1.1527e-01 7.9828e-04 5.7282e-03 1.7519e-02 9.9854e-05 -6.0000e+00 2.6808e-02 -3.8483e-03 12 8 8 10 0 0 6.73 14.67 1.48 -0.00385 0.03588 8 1 1 2 0 4000.000 14.85 14.67 19.75 19.85 14803 7557 44240 7310 -597 19555 -8990 11281 -9937 -7183 -8063 50942 -23379 28957 -17364 22495 -13171 12023 -5778 33868 26262 26749 8353 18373 11304 -18730 64185 -5616 51063 -28926 27060 -18649 -1437 -10140 18956 -7371 17204 13486 8920 6446 1434 22640 191 39750 -34945 8564 -20648 37323 -34868 16971 -28451 10482 -17074 48330 -314 -14907 14518 13450 -5517 11087 38766 21772 87821 -15727 63954 -9096 1249 -9084 5129 -3313 28638 -619 34495 12505 -7549 7006 8273 65651 50483 21808 -17596 24123 -17127 36809 -11791 45639 -25523 16639 249 64097 -15827 15234 10199 6074 63849 12892 27384 -191 16187 -14348 7865 -18053 9194 -28807 53288 -11239 -10075 11607 27858 33351 23627 -25620 -20305 23713 21137 27457 -5684 55239 -14109 55730 -39464 6523 -23540 -2927 7245 11116 25367 -5198 12255 21877 50607 8580 41091 -29177 114783 -13717 57276 -27370 29435 -19284 50325 -473 2883 28520 14594 5225 10638 39642 5519 13459 7583 31885 7863 -694 19515 -11858 12257 -13321 -9279 -10417 36998 -34374 25044 -23934 21158 -18226 13388 -7871 31306 26263 26605 9979 19863 13077 -28349 43022 -7227 36987 -44391 24281 -26259 -1765 -14064 19894 -9989 17965 14366 9784 7172 1672 21372 226 31864 -57569 9259 -28701 29131 -53133 15215 -37935 9508 -19952 30840 -329 -18418 13453 12533 -6164 10445 28417 18494 39367 -19188 35414 -10021 1222 -9727 4700 -3275 20641 -606 24152 11009 -7858 6312 7197 32545 28328 16391 -19377 18132 -19291 25203 -12984 29134 -32469 13889 245 34318 -18543 13099 9077 5467 31884 10113 18038 -163 11558 -14069 6407 -19695 8275 -38363 32154 -12481 -10843 9925 20732 23646 18113 -32105 -24047 18062 16619 20508 -5950 31943 -15321 30825 -53093 5641 -27033 -2742 6266 9232 18200 -4945 9997 16018 27356 6843 24231 -34487 35455 -14698 31524 -34221 21639 -22842 31407 -485 2868 21926 12762 4920 9303 25714 5065 SO 20180218T063342.0Z 6623.273403 486 1 32.01 2 88.63 108.67 102.55 84.02 0.00 1 0.00 1 0 87 1.113e-01 1.030e-01 1.484e-01 1.418e-01 4.707555e+03 8.849708e+03 9.643141e+02 -6.000000e+00 5.543626e+03 261.26 -2.00 20.00 -2.00 505.27 0.00e+00 -3.935051e-03 3.658783e-03 1.953219e-04 -6.000000e+00 2.942639e-03 261.26 -2.00 20.00 -2.00 499.73 0.00e+00 3.344660e+00 2.896602e+00 1.716209e-01 -6.000000e+00 2.198973e+00 223.87 -2.00 3.62 -2.00 501.43 0.00e+00 18.184 0.120 489.00 513.00 1 4.9921e+00 2.1900e-01 2.8410e-02 -6.0000e+00 1.6718e-01 7.0182e-02 5.7596e-02 2.3385e-03 -6.0000e+00 4.3894e-02 1.2970e-03 9.0991e-03 1.1958e-02 9.0859e-05 -6.0000e+00 1.0243e-02 2.0508e-02 12 8 8 10 0 0 5.52 14.67 4.54 0.02051 0.08362 8 1 1 2 0 4000.000 14.93 14.67 19.75 19.96 25183 12529 -2387 5838 -4932 -5118 -3024 931 -8838 3877 852 -7417 11324 2062 22119 2349 -4557 2437 1811 10004 3369 11926 17066 -6556 -5987 5574 -7709 9989 -5460 8291 -12185 2713 -8729 -9974 -4122 -6876 5351 -4968 4300 -7483 -4038 -2188 4618 17515 9839 966 -1349 -17207 5015 -10398 3689 10314 17920 -13146 7640 -5867 -14619 3057 15564 -1290 -3976 -11141 10195 -754 -5988 -11946 -15080 17967 2611 -3041 15610 8930 8166 21923 14687 5213 24488 9411 7470 13308 7642 -1133 6589 -5717 -2475 -17188 10444 -411 7590 201 5042 6992 19832 8843 -5192 488 -6097 34478 885 5917 -7185 -853 -9532 -6833 8931 -1030 -7446 -8987 14055 7838 -6858 18914 -9885 -12468 8948 -22401 -4099 -17379 -318 9042 24985 -804 23348 -3330 14090 7096 13611 -9511 -10357 -1234 1007 5992 -21925 13396 9574 -19557 -13055 13939 -7761 14230 -5851 3106 12030 2710 5891 10432 10739 22635 13918 19761 11528 -2644 6121 -5891 -6255 -3665 1086 -11261 4294 962 -8744 11206 2226 19661 2530 -5418 2782 2110 10776 3880 12604 17169 -8373 -7585 6249 -9740 10286 -6344 8257 -14983 2950 -11059 -12830 -5016 -8504 5769 -5849 4565 -8908 -4660 -2497 4963 16622 10053 1067 -1498 -21906 4959 -11587 3476 9003 14696 -15171 7377 -6596 -17565 3133 13998 -1342 -4263 -12846 9450 -769 -6325 -13157 -16901 14615 2386 -2927 12554 7787 7279 17064 12096 4613 17558 7781 6297 10660 6540 -1069 5831 -5667 -2391 -19260 9074 -389 6660 191 4631 6312 15525 7536 -4949 426 -5543 20935 729 4707 -6759 -791 -10048 -7118 7893 -988 -7497 -8959 11490 6902 -6900 15104 -10312 -13391 7815 -26962 -4099 -19577 -296 7535 17581 -735 16861 -3145 11176 6023 10796 -9510 -10389 -1112 873 4901 -23234 10377 7919 -21670 -13795 11405 -7967 11815 -5988 2926 10387 2552 5282 8724 8787 16401 11136 SO 20180218T063955.0Z 6623.277720 492 1 32.01 2 87.62 109.81 101.51 85.13 0.00 1 0.00 1 0 36 1.052e-01 9.781e-02 9.292e-02 8.961e-02 5.123275e+03 5.601586e+03 7.967189e+01 -6.000000e+00 5.238862e+03 261.26 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