File name: Pandora120s1_Davos_20180223_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T003820.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20180223_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20180223 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180223T061810.0Z 6628.262616 457 1 31.99 2 89.74 104.73 116.66 15.98 0.00 1 0.00 1 0 29 1.063e-01 1.004e-01 8.693e-02 8.336e-02 5.853430e+03 5.375635e+03 8.517190e+02 -6.000000e+00 5.301398e+03 261.67 -2.00 20.00 -2.00 505.22 0.00e+00 8.214630e-04 2.178839e-03 5.488460e-05 -6.000000e+00 2.812988e-03 261.67 -2.00 20.00 -2.00 499.59 0.00e+00 1.324320e+00 1.738065e+00 1.107884e-01 -6.000000e+00 2.104126e+00 224.07 -2.00 3.62 -2.00 501.30 0.00e+00 20.720 0.177 489.00 513.00 1 4.2301e+00 1.3235e-01 3.2708e-02 -6.0000e+00 1.5994e-01 1.5479e-01 3.4096e-02 2.0335e-03 -6.0000e+00 4.2100e-02 2.2433e-03 1.4270e-02 7.1551e-03 8.3125e-05 -6.0000e+00 9.7887e-03 -5.7243e-03 12 8 8 10 0 0 1.20 14.12 7.11 -0.00572 0.09326 8 1 1 2 0 4000.000 15.05 14.12 19.33 19.44 4333 -14361 11288 -14119 -5769 -3148 -1341 4630 -3068 1533 -9628 6014 -6788 8204 -9205 904 -6847 15633 2802 13729 3773 16346 -5799 2799 5642 -4730 5970 -3348 5195 -1086 6384 -14469 19536 -9752 -1924 -5254 7429 -11192 22087 -45 5968 6873 3679 6486 -3762 11670 -8015 5736 -14162 1570 -15098 9019 -3397 6348 -5705 13796 2917 8665 7506 -1082 11127 -4964 8747 -3462 5148 -12626 2194 1171 9142 -1063 17091 -8667 12137 1766 8702 13183 -4621 -7498 4141 17727 3321 14875 -9483 2800 -10354 22392 -11411 7528 -3229 14892 -5090 23450 -6522 30476 17971 4838 10971 -11936 -388 -13153 17776 -11953 13780 -18512 14648 -1110 12109 1176 9905 10551 -9145 8635 527 6044 2092 7230 -14661 9567 -23625 4764 -15946 25249 -6339 11057 -6931 3121 -6005 11955 -7272 -5709 -3138 -6173 10409 -11259 16950 -8853 3891 -10109 9810 -12775 17135 -15077 13351 2044 -7436 -2734 10543 11984 3792 4406 -17764 11477 -18533 -7113 -3850 -1624 5266 -3715 1744 -12062 6337 -8018 8285 -11111 1003 -8428 15756 3243 14247 4321 16507 -7160 3261 6231 -5757 6431 -3841 5284 -1157 6355 -18231 18196 -12477 -2278 -6355 7800 -13972 19627 -49 6289 7257 4056 7000 -4387 11823 -9499 5796 -16946 1554 -17233 8034 -3484 6101 -6371 12892 3047 8508 7427 -1170 10693 -5609 8572 -3781 5064 -14580 2154 1145 8144 -1043 14087 -9153 10788 1702 7688 11142 -4486 -7432 3651 13720 2989 12010 -9874 2604 -11011 17123 -12179 6637 -3183 12383 -5243 18237 -6754 21268 13809 4113 8532 -11156 -319 -12460 13066 -12104 11178 -20964 11803 -1029 9713 1055 8251 8866 -9460 7522 499 5440 1974 6522 -16033 8265 -27263 4060 -16561 17825 -6044 8873 -6657 2704 -5682 9445 -6907 -5240 -2758 -5535 7910 -10794 12549 -8644 3392 -10248 8203 -13163 13446 -16033 10903 1811 -7093 -2423 8198 9170 3124 SO 20180223T062424.0Z 6628.266945 463 1 32.01 2 88.71 105.86 116.36 17.54 0.00 1 0.00 1 0 22 5.486e-02 5.335e-02 5.574e-02 5.440e-02 1.832621e+03 3.148090e+03 6.155232e+01 -6.000000e+00 2.735688e+03 261.68 -2.00 20.00 -2.00 505.23 0.00e+00 1.557134e-03 1.405554e-03 7.396427e-05 -6.000000e+00 1.451581e-03 261.68 -2.00 20.00 -2.00 499.72 0.00e+00 3.240963e+00 1.120497e+00 4.389963e-02 -6.000000e+00 1.084964e+00 224.07 -2.00 3.62 -2.00 501.41 0.00e+00 18.415 0.124 489.00 513.00 1 3.9226e+00 8.5257e-02 2.6204e-02 -6.0000e+00 8.2479e-02 9.1549e-02 2.2092e-02 1.6105e-03 -6.0000e+00 2.1688e-02 3.4871e-03 7.0803e-03 4.8050e-03 2.3309e-05 -6.0000e+00 5.0495e-03 5.1224e-03 12 8 8 10 0 0 -12.31 14.12 6.99 0.00512 0.05423 8 1 1 2 0 4000.000 14.69 14.12 19.33 19.44 -3031 -219 -2119 1365 -7058 7652 -5796 -1446 -441 2998 -4149 4250 -1051 -5288 4324 -4217 6587 627 5246 -5297 4762 -3539 -4058 -3603 10079 -1483 4224 -4538 3106 490 1013 -4515 902 237 -2611 6164 56 11062 -4307 2548 -5511 9871 -1474 4947 -6642 7685 993 141 -2235 -947 -2862 -1974 14310 -3949 551 -6921 4905 -3846 4454 -2340 8588 -3994 8234 548 3066 -1330 -4766 8287 -426 2892 -4292 2565 -6860 588 -6480 11094 -4707 3272 -1268 8296 212 5947 -1847 9229 3416 -48 7846 -5886 4300 -4554 2990 -7089 2316 -3249 6103 -7711 3403 2506 6138 5602 1813 2696 -438 3236 -7541 901 -7972 6300 -3059 3572 -2614 9362 1639 -543 -5780 7139 10340 7809 -4679 -5444 766 -6878 5777 -5190 5563 -15448 -3422 -5754 -4726 -7 -2139 5635 -1306 -841 5925 5758 3199 -2447 6283 7232 -7919 14347 -1364 3215 -7232 3372 -172 4118 -11315 -3156 -229 -2342 1501 -8633 8245 -7233 -1729 -517 3335 -4887 4530 -1164 -6056 4502 -4730 6796 705 5725 -6440 5233 -4226 -4886 -4343 10616 -1747 4647 -5315 3251 514 1058 -5087 999 273 -3118 6680 62 11103 -4879 2693 -6359 9873 -1671 5310 -8019 7982 1087 152 -2410 -976 -2923 -1972 12255 -4180 576 -7961 5046 -4305 4566 -2508 8483 -4383 7969 566 3034 -1350 -4931 7418 -410 2666 -4263 2404 -7163 573 -6688 9393 -4579 2909 -1177 7024 196 5215 -1765 7970 3070 -45 6718 -5772 3820 -4461 2758 -7321 2173 -3174 5320 -7525 2890 2092 4856 4465 1535 2350 -408 2939 -7565 816 -7602 5313 -2807 3124 -2474 7962 1517 -516 -5826 6352 8877 6786 -4527 -5222 684 -6654 4966 -4997 4815 -16133 -3231 -5566 -4512 -7 -1885 4629 -1119 -725 4885 4864 2818 -2308 5472 6265 -8028 11713 -1307 2928 -7184 2933 -151 3446 -11162 SO 20180223T063030.0Z 6628.271181 469 1 32.01 2 87.71 106.98 116.03 19.06 0.00 1 0.00 1 0 15 3.138e-02 3.069e-02 3.273e-02 3.221e-02 3.554655e+03 1.919224e+03 2.196210e+02 -6.000000e+00 1.565111e+03 261.68 -2.00 20.00 -2.00 505.20 0.00e+00 3.368859e-04 8.301031e-04 5.736451e-05 -6.000000e+00 8.304058e-04 261.68 -2.00 20.00 -2.00 499.86 0.00e+00 1.612749e+00 6.583285e-01 3.955826e-02 -6.000000e+00 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