File name: Pandora120s1_Davos_20180312_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T004147.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20180312_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20180312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180312T054617.0Z 6645.240475 364 1 32.01 2 89.74 95.15 71.61 153.24 0.00 1 0.00 1 0 8 1.007e-01 9.452e-02 9.043e-02 8.724e-02 1.233890e+02 4.652148e+03 1.692468e+02 -6.000000e+00 5.051262e+03 263.08 -2.00 20.00 -2.00 505.19 0.00e+00 1.818620e-03 2.253270e-03 7.403270e-05 -6.000000e+00 2.673162e-03 263.08 -2.00 20.00 -2.00 499.69 0.00e+00 2.008641e+00 1.792332e+00 3.560344e-02 -6.000000e+00 1.992757e+00 224.72 -2.00 3.62 -2.00 501.38 0.00e+00 20.679 0.176 489.00 513.00 1 4.2152e+00 1.3656e-01 3.1914e-02 -6.0000e+00 1.5153e-01 1.4223e-01 3.5946e-02 1.7920e-03 -6.0000e+00 3.9871e-02 2.1629e-03 -3.0293e-04 7.7684e-03 3.3843e-05 -6.0000e+00 9.2719e-03 -4.2899e-03 12 8 8 10 0 0 -5.42 14.89 4.64 -0.00429 -0.00639 8 1 1 2 0 4000.000 14.99 14.89 19.96 20.14 -599 -10803 1288 -1733 -564 5424 -3533 6342 -12798 6835 -2788 600 242 4606 751 -3885 -3853 12947 -9526 6188 -4228 10106 652 2391 125 -5501 -47 -12866 5557 -7349 7986 2679 -2088 -9764 23247 -5328 12133 -7378 10728 6424 3872 10543 75 -4729 -150 5413 3924 12640 -11732 10831 -10379 21383 -14533 11338 1468 9284 4890 20516 -4592 -1642 11181 -4656 6363 -10511 1809 1318 7539 -15943 12829 -10828 4987 -17084 13318 -2996 25236 7517 2755 12175 -14015 -2383 1865 3323 -5746 12449 -11227 18616 -5228 21970 -952 4641 -6553 29916 1058 5700 7813 3304 1783 -8543 2330 -5165 13930 -11299 9028 -4830 9081 -12500 3788 -10990 8505 4016 -1697 1768 10699 11346 -15251 5195 -14731 17683 -8627 9475 12045 7248 -8941 13029 -18140 16085 10458 -5181 -4035 11458 1142 -5685 -8549 576 13500 -16087 25902 -13447 3625 -7043 10490 -2387 -744 -4869 15446 -7415 5318 -2121 -743 -624 -12430 1361 -1955 -644 5959 -4316 7060 -17155 7409 -3272 671 267 4801 809 -4413 -4458 13009 -12252 6849 -5191 10744 744 2696 145 -6728 -54 -16521 5744 -8359 7703 2753 -2320 -12160 21240 -6462 12196 -8889 10653 6628 4113 10577 84 -5527 -168 5734 4173 12110 -14015 10011 -11491 17275 -16378 10073 1488 8950 4996 17942 -5138 -1779 10689 -5238 6412 -12451 1866 1342 7087 -18272 11118 -11462 4599 -19347 11542 -3020 19562 6673 2510 9956 -14809 -2245 1696 2995 -5703 10398 -11972 14753 -5250 16771 -915 4246 -6797 21907 1018 5325 6885 2987 1595 -8243 1969 -4659 10503 -11288 7630 -4788 7813 -13128 3317 -11042 7075 3554 -1621 1659 9286 9848 -16973 4835 -16340 14341 -8752 7887 9645 6073 -8871 10433 -19852 12492 8569 -4957 -3816 9197 997 -5218 -7974 490 10259 -16827 18143 -13841 3239 -6878 8810 -2244 -692 -4710 12311 -7092 4352 -1836 -635 SO 20180312T055232.0Z 6645.244815 370 1 32.01 2 88.67 96.29 71.15 154.67 0.00 1 0.00 1 0 29 7.689e-02 7.589e-02 7.192e-02 7.015e-02 -3.653567e+03 3.722509e+03 3.308210e+02 -6.000000e+00 3.857775e+03 263.08 -2.00 20.00 -2.00 505.19 0.00e+00 2.109411e-03 1.831072e-03 1.038987e-04 -6.000000e+00 2.041559e-03 263.08 -2.00 20.00 -2.00 499.83 0.00e+00 3.154143e+00 1.436261e+00 1.955654e-02 -6.000000e+00 1.521915e+00 224.72 -2.00 3.62 -2.00 501.50 0.00e+00 18.279 0.121 489.00 513.00 1 4.1927e+00 1.0949e-01 2.5839e-02 -6.0000e+00 1.1573e-01 9.5521e-02 2.8748e-02 1.4818e-03 -6.0000e+00 3.0451e-02 2.7120e-03 -9.4356e-03 6.3212e-03 5.9126e-05 -6.0000e+00 7.0812e-03 -4.2805e-03 12 8 8 10 0 0 -5.97 14.89 4.63 -0.00428 -0.06973 8 1 1 2 0 4000.000 14.86 14.89 19.96 20.14 -7483 6684 5531 -1719 -2612 8565 -4669 9709 -3255 621 -16257 3708 -2002 -463 -931 -4521 -2364 -3672 1675 3198 2241 -4890 10472 -6996 508 1436 8392 -7263 6074 -5085 5883 -1529 8216 -6515 2688 938 7967 1547 15033 7001 6179 3923 -4066 2241 -16471 6873 -6183 2790 -661 9753 111 20589 -10855 8982 4978 -3419 3777 -4747 5777 4196 -2489 -5483 13582 -1058 17770 -10944 -1066 -9367 5601 -626 5513 481 2218 6291 -4214 19848 5416 -3514 -7465 7922 -9910 7884 -20089 -745 -222 4268 -12003 7338 9055 -392 5105 -12508 14643 -3548 12715 -1516 8128 -12030 11486 -6801 8412 -8387 -1602 -1385 -1753 1670 -1616 9306 -5903 8290 1040 11235 -4256 11236 -4395 12228 235 11375 -13768 2733 -2157 9506 -8462 6650 4525 -234 11217 636 1777 -6181 -2847 87 8315 -10065 8674 608 7967 -10422 445 7824 2685 3938 4364 -3299 -8574 2025 86 943 -15629 -8001 6262 5404 -1875 -2964 8886 -5642 10284 -3928 713 -21716 3996 -2249 -505 -1009 -5084 -2635 -4247 1887 3516 2494 -5841 10726 -8562 580 1628 8842 -8853 6320 -5707 5776 -1616 8039 -7664 2978 1067 8369 1708 14315 7159 6369 4166 -4620 2421 -21663 7173 -7302 2970 -715 9243 112 16485 -11745 8038 4773 -3683 3869 -5333 5826 4278 -2712 -6186 12698 -1142 15704 -12374 -1072 -10080 5117 -600 4916 453 2072 5718 -4278 15654 4830 -3364 -7368 6693 -10060 6747 -22841 -703 -211 3879 -12556 6464 7849 -367 4568 -13581 12321 -3603 10931 -1488 7125 -12566 9226 -6429 6821 -8184 -1504 -1330 -1695 1535 -1503 7632 -5625 6950 958 9556 -4216 9866 -4445 10504 227 9737 -14911 2470 -2023 7896 -8457 5762 4015 -218 9300 586 1619 -6085 -2675 78 6732 -9698 6972 541 6748 -10560 409 6704 2426 3530 3924 -3217 -8776 1830 77 815 -15790 SO 20180312T055837.0Z 6645.249039 376 1 32.01 2 87.64 97.40 70.72 156.08 0.00 1 0.00 1 0 8 5.000e-02 4.928e-02 5.278e-02 5.181e-02 1.848232e+03 2.908180e+03 6.786624e+01 -6.000000e+00 2.508795e+03 263.08 -2.00 20.00 -2.00 505.17 0.00e+00 1.111104e-03 1.339820e-03 9.454913e-05 -6.000000e+00 1.327724e-03 263.08 -2.00 20.00 -2.00 499.84 0.00e+00 1.287862e+00 1.059575e+00 3.773976e-02 -6.000000e+00 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