File name: Pandora120s1_Davos_20180412_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T004810.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20180412_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20180412 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180412T044541.0Z 6676.198391 341 1 32.01 2 89.76 77.56 77.63 123.22 0.00 1 0.00 1 0 80 1.487e+00 9.280e-01 8.073e-01 5.836e-01 -6.931102e+04 3.089157e+04 1.221266e+04 -6.000000e+00 8.842260e+04 266.91 -2.00 20.00 -2.00 504.99 0.00e+00 6.450669e-02 1.808423e-02 1.283186e-04 -6.000000e+00 4.689051e-02 266.91 -2.00 20.00 -2.00 499.58 0.00e+00 1.023926e+01 1.337582e+01 2.184132e-01 -6.000000e+00 3.724214e+01 226.91 -2.00 3.62 -2.00 501.15 0.00e+00 20.629 0.175 489.00 513.00 1 4.8250e+00 1.0274e+00 3.6617e-02 -6.0000e+00 2.8435e+00 1.3538e-01 2.7113e-01 1.0909e-02 -6.0000e+00 7.6748e-01 1.6169e-04 1.6531e-01 1.7681e-02 1.1209e-03 -6.0000e+00 1.5933e-01 -6.6904e-02 12 12 12 10 0 0 -9.32 14.82 11.95 -0.06690 1.07974 8 1 1 2 0 4000.000 14.99 14.82 19.85 20.14 154478 2522 415838 -51772 410210 39214 149938 295153 334688 402989 -1625 85241 -43506 900000 -76982 297579 -55081 900000 -8551 -23201 -84923 217874 36382 160445 54285 80223 128436 900000 88 -55532 48757 -9247 3049 -48233 272145 -69361 199450 110364 900000 -19013 900000 102582 83105 97024 743 900000 -14899 340004 256504 168694 59929 900000 -34928 900000 -6071 222210 -14271 78901 900000 -17060 329429 -25466 900000 15590 900000 19588 900000 -44766 24270 52506 45402 17434 90216 -59512 900000 -55660 900000 242183 69413 -10621 39499 900000 111004 124200 -279 900000 -15060 900000 14293 900000 5555 900000 -27860 900000 11640 121660 -25062 116466 50370 -27741 900000 -41983 900000 38175 28560 -7531 900000 -11446 900000 -61655 900000 -18064 900000 276891 17310 900000 -8201 900000 -9676 377717 103376 900000 -64525 900000 -21935 22795 -26653 174767 900000 900000 172592 144777 408427 201913 900000 176217 900000 184298 900000 -18068 900000 -4130 900000 -75379 98292 2963 900000 900000 900000 87633 2447 235897 -78318 232705 24049 85057 167435 189862 228608 -1359 48356 -53906 900000 -136611 168811 -84125 900000 -8298 -24938 -152956 123596 20639 91017 30795 45509 72859 900000 75 -79544 27659 -9415 2928 -80032 154383 -155423 113144 62608 900000 -26156 900000 58193 47144 55040 854 900000 -21552 192878 145510 95697 44457 900000 -65242 900000 -8400 126056 -20535 45907 900000 -23368 186879 -35940 900000 14593 900000 17224 900000 -70611 19619 32841 29619 14835 51178 -95654 900000 -80092 900000 137386 39377 -9258 22407 900000 62971 70456 -335 900000 -27461 900000 18919 900000 6678 900000 -37254 900000 7892 69016 -19072 66069 28574 -23414 900000 -49901 900000 27466 23916 -9155 900000 -12368 900000 -97607 900000 -20983 900000 157075 15899 900000 -9737 900000 -12127 214272 58643 900000 -127282 900000 -25176 16625 -31294 99142 900000 900000 97908 82130 231694 114542 900000 99965 900000 104549 900000 -14063 900000 -3051 900000 -112733 55759 1994 900000 900000 900000 SO 20180412T045318.0Z 6676.203681 347 1 32.00 2 88.48 78.94 76.56 124.73 0.00 1 0.00 1 0 36 2.194e-01 1.851e-01 2.154e-01 1.968e-01 1.693615e+04 1.423799e+04 7.750434e+02 -6.000000e+00 1.118545e+04 266.91 -2.00 20.00 -2.00 505.31 0.00e+00 4.866304e-03 5.307612e-03 1.460209e-04 -6.000000e+00 5.875869e-03 266.91 -2.00 20.00 -2.00 500.09 0.00e+00 -2.044446e-01 3.985385e+00 2.348814e-01 -6.000000e+00 4.333545e+00 226.91 -2.00 3.62 -2.00 501.74 0.00e+00 17.703 0.110 489.00 513.00 1 5.4314e+00 3.0741e-01 3.0970e-02 -6.0000e+00 3.2997e-01 9.0808e-02 7.6959e-02 4.7113e-03 -6.0000e+00 8.6523e-02 9.4154e-04 9.5797e-03 1.6521e-02 2.8085e-05 -6.0000e+00 2.0187e-02 2.4445e-02 12 8 8 10 0 0 1.69 14.78 2.31 0.02444 0.09089 8 1 1 2 0 4000.000 14.99 14.78 19.85 20.04 19892 -3063 4416 15040 9292 -18271 26083 -7122 21410 -6898 11324 -8506 16026 25505 16216 -16268 2018 24822 -14983 10400 3053 25322 -13479 -10863 -5608 -23475 5246 11236 -310 -5936 21690 233 2374 -9708 -3582 -6241 25615 -12751 32358 -11672 -1565 -14403 48804 -22745 7992 2587 6380 -8413 -6346 32035 28707 27679 19222 24339 3031 2392 7695 44152 -8952 2702 -15709 51531 -6226 69413 14013 38107 -2050 25418 11912 -721 50741 -25028 10866 -6275 10725 -33159 -5538 -39867 -3727 -13557 6493 -15016 11825 -11303 28151 20099 20096 34240 11157 6062 -13355 26015 6983 34051 -23018 42616 -18751 45920 -25730 12251 17953 21167 20839 13020 10589 -9516 17966 26515 -12112 -10566 20443 -25948 59403 -11703 8820 -444 -10617 1324 33896 2095 14162 -5719 -10114 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-4272 2656 -12030 14670 -6843 11076 -947 14845 SO 20180412T050002.0Z 6676.208357 353 1 32.02 2 87.35 80.16 75.63 126.08 0.00 1 0.00 1 0 22 1.066e-01 9.799e-02 1.074e-01 1.042e-01 -4.578361e+03 5.501776e+03 3.449832e+02 -6.000000e+00 5.436149e+03 266.91 -2.00 20.00 -2.00 505.22 0.00e+00 3.577581e-03 2.742355e-03 1.767910e-04 -6.000000e+00 2.856608e-03 266.91 -2.00 20.00 -2.00 499.99 0.00e+00 3.724467e+00 2.121022e+00 4.791081e-02 -6.000000e+00 2.111288e+00 226.91 -2.00 3.62 -2.00 501.65 0.00e+00 14.587 0.062 489.00 513.00 1 4.9351e+00 1.6209e-01 1.9489e-02 -6.0000e+00 1.6070e-01 4.1156e-02 4.2105e-02 1.4277e-03 -6.0000e+00 4.2255e-02 1.8368e-03 3.9815e-03 9.3491e-03 7.4063e-05 -6.0000e+00 9.8219e-03 -3.0089e-03 12 8 8 10 0 0 88.24 14.76 3.88 -0.00301 0.02461 8 1 1 2 0 4000.000 15.01 14.76 19.85 20.04 4192 -12986 2780 5135 -3431 4334 -6074 -237 -4769 3711 -7670 18986 -6673 5466 -13092 11938 -3943 11855 -3497 6323 -80 7977 1384 -10062 8992 -450 16711 -19147 21219 -9948 7993 -4902 9499 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