File name: Pandora120s1_Davos_20180505_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T004918.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20180505_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20180505 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180505T040644.0Z 6699.171343 165 1 32.01 2 89.76 66.18 68.88 190.77 0.00 1 0.00 1 0 22 1.416e-01 1.288e-01 1.340e-01 1.278e-01 1.236124e+04 8.925443e+03 1.158997e+03 -6.000000e+00 7.313846e+03 270.01 -2.00 20.00 -2.00 505.23 0.00e+00 3.538501e-03 3.359380e-03 2.368682e-04 -6.000000e+00 3.823964e-03 270.01 -2.00 20.00 -2.00 499.94 0.00e+00 7.334915e-01 2.620284e+00 3.699351e-02 -6.000000e+00 2.813476e+00 229.05 -2.00 3.62 -2.00 501.57 0.00e+00 20.541 0.172 489.00 513.00 1 4.6125e+00 1.9898e-01 3.2241e-02 -6.0000e+00 2.1424e-01 1.1521e-01 5.1453e-02 2.1094e-03 -6.0000e+00 5.6474e-02 1.5012e-03 9.4234e-03 1.0614e-02 1.4725e-04 -6.0000e+00 1.3072e-02 -3.2746e-02 12 8 8 10 0 0 -5.21 15.12 6.25 -0.03275 0.03262 8 1 1 2 0 4000.000 15.00 15.12 20.04 20.35 2705 -18761 -5351 1011 5933 14717 -1849 3232 -6018 17378 4587 27162 4708 3049 -10917 25769 -6136 46932 5793 15159 -5112 -4843 5832 4539 8679 -20430 6449 -11218 16959 -12424 -6038 -8624 4160 3938 6680 6309 5293 -5756 12524 -17840 6137 3159 -14924 26281 -140 35425 -17208 4214 -16530 6052 -8478 14180 -4827 13280 8190 -2334 -450 9662 -1879 -6483 -15279 -5125 25111 -11001 6486 -8161 5863 -14239 25633 -6449 20772 6444 -3533 9895 -2562 -1258 5437 4521 16781 22062 8216 28694 15453 23426 -23585 7043 -11769 625 -19493 17528 -3815 -3819 3443 -6212 -46 5778 -7573 -5895 12759 16368 4545 -21696 17754 -1808 27073 -15720 -919 -1846 8328 -1262 16995 98 19978 28649 -6219 124 -17634 22717 -12980 6307 -5863 6211 -14272 379 -6943 -2644 5427 495 13036 5108 20951 -14704 34457 7228 -2050 -21484 38992 -16994 22878 87 18271 -1552 18568 1995 14836 9633 -6537 3071 -12306 2616 -23130 -5995 1097 6275 14552 -2187 3641 -7363 16531 4880 22693 4847 3081 -12664 21449 -7006 33190 6136 14671 -6056 -5722 6214 4933 9088 -28565 6831 -13870 15273 -14602 -6636 -9899 4356 4280 6987 6581 5505 -6605 11869 -22914 6255 3361 -19302 22792 -159 28082 -22820 4433 -20887 5916 -9323 12255 -5078 11991 8055 -2555 -489 9703 -2062 -7454 -19303 -5878 21270 -13257 6456 -9241 5683 -16662 19847 -6815 16748 6058 -3722 9189 -2670 -1267 5017 4159 13579 16954 7294 20881 12954 18343 -29051 6371 -12755 594 -22624 14161 -3875 -3922 3261 -6308 -42 4849 -7044 -5266 9292 11501 3685 -23947 13889 -1775 20024 -17271 -859 -1735 7158 -1214 13803 95 15892 20957 -6504 124 -21140 18072 -14478 5666 -5838 5459 -15521 358 -7088 -2588 4891 469 10841 4532 15559 -15084 22044 5999 -1907 -24787 25487 -19282 17617 84 14915 -1550 15157 1910 12312 8230 -6421 2715 -12792 SO 20180505T041301.0Z 6699.175706 171 1 32.00 2 88.77 67.32 69.09 192.29 0.00 1 0.00 1 0 29 6.674e-02 6.620e-02 7.697e-02 7.540e-02 7.792250e+03 5.024857e+03 1.827799e+02 -6.000000e+00 3.446867e+03 270.01 -2.00 20.00 -2.00 505.31 0.00e+00 6.975003e-04 1.991948e-03 8.735315e-05 -6.000000e+00 1.801250e-03 270.01 -2.00 20.00 -2.00 500.02 0.00e+00 3.304651e+00 1.523826e+00 1.652656e-01 -6.000000e+00 1.322883e+00 229.05 -2.00 3.62 -2.00 501.68 0.00e+00 18.434 0.125 489.00 513.00 1 4.1876e+00 1.1618e-01 2.9173e-02 -6.0000e+00 1.0077e-01 3.9734e-02 2.9512e-02 3.1720e-03 -6.0000e+00 2.6491e-02 2.5984e-03 1.3548e-02 6.4553e-03 1.1474e-05 -6.0000e+00 6.1498e-03 -4.6541e-03 12 8 8 10 0 0 3.18 15.11 2.81 -0.00465 0.08932 8 1 1 2 0 4000.000 14.99 15.11 20.04 20.35 10668 -8808 3231 -9279 -4517 -5933 13155 -4063 4781 -6475 -1063 1666 -421 12985 5600 2100 507 -2576 -5934 6105 -5814 3329 -1395 -2832 -7793 8948 -7433 5295 -1645 13737 380 -2501 3695 -2788 1792 3738 9088 -10895 -3470 -2964 13234 1109 2163 3089 7952 7227 4668 259 -2155 -5372 -123 9940 4216 1306 -17272 6824 993 5931 -2160 5127 -7832 4305 -2793 5062 -270 2048 3826 2991 6578 971 1973 -9619 11867 -1059 -833 -8131 12685 -8859 -2067 8431 6435 -10265 5657 -4769 884 -5658 -4496 -3196 2067 7205 -4796 7165 -12812 -2173 2535 -2589 -1502 7912 -4389 2842 435 9434 6674 5050 -1131 -6497 11472 -5104 1897 -4880 1447 7198 5572 -12932 5928 4146 8993 88 3645 -2705 9489 10558 10478 -461 5373 -2608 -7271 1646 725 -5478 -3306 10518 -5765 -185 -4512 -5149 -6322 8936 -2073 7002 -1702 -15628 2835 -3557 5936 -9704 17149 -1850 9112 9456 -9585 3237 -10833 -5143 -6991 12940 -4744 5047 -7535 -1156 1738 -443 11884 5549 2194 554 -2980 -7014 6566 -6881 3601 -1590 -3293 -9526 9206 -8889 5420 -1745 12297 392 -2727 3938 -3255 2004 4056 9223 -13336 -3918 -3336 12778 1194 2333 3328 8155 7399 4827 274 -2269 -5657 -120 8708 3976 1310 -21510 6799 1052 5960 -2345 5188 -9068 4422 -3065 5069 -281 2040 3694 2806 6011 913 1848 -10254 10340 -1051 -811 -8327 10371 -8909 -1940 7162 5617 -10667 5071 -4795 843 -5747 -4491 -3144 1936 6483 -4825 6421 -13817 -2051 2214 -2308 -1289 6052 -3761 2295 372 7758 5872 4584 -1086 -6484 9453 -4976 1750 -4894 1378 6510 5141 -14121 5416 3895 8043 85 3330 -2585 7953 8799 8816 -434 4788 -2517 -7344 1522 673 -5322 -3095 8513 -5508 -171 -4448 -5106 -6448 7935 -2075 6449 -1722 -18274 2758 -3661 5458 -10188 13530 -1765 7905 SO 20180505T041906.0Z 6699.179931 177 1 32.02 2 87.81 68.42 69.32 193.75 0.00 1 0.00 1 0 29 5.540e-02 5.422e-02 4.494e-02 4.435e-02 7.986543e+02 2.413929e+03 3.408714e+02 -6.000000e+00 2.860766e+03 270.01 -2.00 20.00 -2.00 505.25 0.00e+00 3.570017e-03 1.170591e-03 1.510119e-04 -6.000000e+00 1.494908e-03 270.01 -2.00 20.00 -2.00 500.16 0.00e+00 1.171411e+00 8.966224e-01 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