File name: Pandora120s1_Davos_20180519_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T004906.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20180519_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20180519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180519T034850.2Z 6713.158914 336 1 32.41 2 89.77 60.71 112.44 14.35 0.00 1 0.00 1 0 15 1.548e-01 1.141e-01 1.353e-01 1.265e-01 4.591265e+03 8.124502e+03 4.200858e+02 -6.000000e+00 8.052495e+03 271.87 -2.00 20.00 -2.00 505.24 0.00e+00 1.695726e-03 3.355359e-03 1.119156e-04 -6.000000e+00 4.194486e-03 271.87 -2.00 20.00 -2.00 499.89 0.00e+00 3.144584e+00 2.613565e+00 2.840345e-02 -6.000000e+00 3.066098e+00 230.31 -2.00 3.62 -2.00 501.55 0.00e+00 20.492 0.171 489.00 513.00 1 4.4634e+00 1.9948e-01 3.1704e-02 -6.0000e+00 2.3371e-01 7.5967e-02 5.1649e-02 1.8766e-03 -6.0000e+00 6.1360e-02 1.5292e-03 -2.0293e-03 1.1137e-02 6.1864e-05 -6.0000e+00 1.4255e-02 5.7892e-03 12 8 8 10 0 0 -7.95 14.91 6.22 0.00579 -0.00829 8 1 1 2 0 4000.000 15.01 14.91 19.96 20.14 18572 -9695 18204 -20284 13590 1800 2759 20564 12290 2430 -9415 -1361 4218 713 7801 6383 -5590 5804 -12641 14647 -8395 9975 -2441 -4401 722 -4696 2444 6319 -4213 -16067 525 -7503 13143 2913 3715 -396 14052 -8755 2573 -9119 6495 -5716 -81 4073 -7290 15128 -17957 1017 2057 14016 18975 12428 -10028 8064 3820 160 1909 -2262 -3211 1336 7052 2167 8460 477 31085 6564 -9817 -15960 6649 -18227 21309 12939 -6257 -4016 5538 -11829 6782 -5056 11647 2474 -5344 -1778 -7445 3278 -9921 11947 -1395 11575 -3875 -15166 -6487 19334 10732 9157 -5331 -4809 1126 14579 13904 9774 1498 -18319 13318 -11539 877 -7069 9594 -5495 3810 10610 33520 15682 2769 18405 5066 8305 -10214 14097 -690 27866 -25979 8733 -2633 5203 -12132 53284 -27761 -1074 -7657 -6293 117493 -11234 -13408 9173 5865 -15149 5993 20362 5925 -8118 15460 4663 5444 383 13025 504 5545 -3897 7919 15187 -10751 15845 -26890 13176 2007 3102 19491 12600 2643 -11352 -1492 4309 746 7567 6326 -6368 6068 -16273 14473 -10451 10339 -2869 -5306 832 -5704 2748 6721 -4826 -19575 549 -8388 12630 3145 4066 -451 13679 -10563 2740 -10868 6648 -6677 -91 4422 -8924 14772 -24155 1113 2178 12776 15953 10926 -11005 7541 3854 168 2002 -2477 -3534 1401 7010 2273 8337 506 23914 6336 -10975 -18717 6131 -21270 16700 11110 -6599 -4189 5234 -13054 6077 -5026 9733 2267 -5207 -1682 -7505 3000 -10448 10126 -1347 9778 -3819 -16826 -6686 15625 9489 8122 -5344 -4672 1002 11043 10375 7541 1274 -19217 10876 -12168 821 -7084 8185 -5280 3357 8880 23220 12867 2608 14898 4714 7546 -11221 12071 -675 20102 -30928 7478 -2545 4684 -12744 29781 -34096 -1009 -7693 -6187 34408 -11226 -13579 7437 5008 -16362 5343 15960 5426 -8615 13034 4409 5132 379 11262 483 4928 -3747 6783 SO 20180519T035508.0Z 6713.163287 342 1 32.01 2 88.82 61.85 112.18 15.84 0.00 1 0.00 1 0 15 8.442e-02 8.152e-02 8.537e-02 8.350e-02 4.425245e+03 5.199292e+03 6.660471e+01 -6.000000e+00 4.393332e+03 271.87 -2.00 20.00 -2.00 505.26 0.00e+00 -3.023292e-05 2.226932e-03 7.907316e-05 -6.000000e+00 2.288347e-03 271.87 -2.00 20.00 -2.00 500.07 0.00e+00 1.980140e+00 1.691269e+00 1.189112e-01 -6.000000e+00 1.673281e+00 230.32 -2.00 3.62 -2.00 501.73 0.00e+00 18.521 0.126 489.00 513.00 1 4.3864e+00 1.2905e-01 2.7965e-02 -6.0000e+00 1.2754e-01 7.0785e-02 3.3290e-02 2.3567e-03 -6.0000e+00 3.3499e-02 2.3550e-03 -3.7399e-04 7.3051e-03 2.3699e-05 -6.0000e+00 7.7782e-03 1.5136e-03 12 8 8 10 0 0 -3.88 14.91 2.71 0.00151 -0.00108 8 1 1 2 0 4000.000 15.01 14.91 19.96 20.14 -15863 3208 3736 -3504 -10518 2151 -3274 11430 -133 85 648 6002 7295 -3165 6063 -11171 3841 -11631 10687 -7629 4023 1176 4748 934 -3330 9786 -2485 8342 -3903 1839 -1759 5276 -1926 10516 4814 6971 -6994 7582 -7559 16634 -3805 -265 -10391 9210 -426 -4783 15310 -8564 5358 -11100 -3500 4583 6547 -8736 -4088 3346 2879 945 11487 10239 6700 15039 -3535 3960 1763 10436 -7750 11171 -12455 -5757 -7683 11666 2154 4351 -5991 4397 7700 -5363 -2388 -11770 -5249 -3694 3307 7447 189 -2742 5321 -12203 10622 6255 5966 -2177 1555 13031 -11146 -6615 4905 2791 -10538 14131 11364 -343 -8676 3582 -13564 11210 -12438 22321 -5812 22753 6259 7421 -6492 14275 10097 9117 -12401 2517 5073 -6716 2626 -4962 6053 3311 7051 -9120 12044 -11136 13221 -1171 3238 -1048 16978 2363 -6035 4451 -10143 9274 -6366 6002 -7257 -9523 -10168 -2995 -11493 11272 -597 14213 10004 -18037 3084 3706 -3776 -12466 2296 -3756 11403 -148 93 696 6035 7132 -3397 5915 -13061 3947 -14365 10811 -9346 4391 1321 5153 1059 -3859 10173 -2831 8384 -4295 1852 -1819 5149 -2086 10446 5167 7305 -8323 7694 -8819 15163 -4269 -289 -12710 9364 -479 -5478 14523 -9906 5396 -12480 -3536 4186 5854 -9307 -4301 3361 2947 987 10751 9681 6590 13676 -3874 4001 1795 9569 -8390 9882 -13767 -5881 -7995 10098 2081 4069 -6193 4022 6671 -5225 -2247 -12189 -5133 -3585 3019 6604 182 -2727 4877 -13295 9223 5710 5535 -2222 1532 11290 -11752 -6493 4268 2418 -10000 10667 8979 -309 -8895 3347 -15115 9639 -13318 16718 -5801 17331 5712 6772 -6857 12300 9122 8386 -13894 2413 4767 -6820 2391 -4854 5340 3020 6207 -9439 10067 -11724 10910 -1105 2874 -956 12832 2076 -5882 4005 -10768 8230 -6679 5604 -7617 -10294 -11115 -3044 -12583 9613 -559 11306 8323 SO 20180519T040119.0Z 6713.167581 348 1 31.99 2 87.89 62.96 111.89 17.30 0.00 1 0.00 1 0 22 7.751e-02 7.632e-02 7.340e-02 7.175e-02 1.962436e+03 4.208953e+03 2.012861e+02 -6.000000e+00 4.033760e+03 271.87 -2.00 20.00 -2.00 505.19 0.00e+00 -3.167821e-05 1.908796e-03 1.191182e-05 -6.000000e+00 2.100711e-03 271.87 -2.00 20.00 -2.00 499.93 0.00e+00 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