File name: Pandora120s1_Davos_20180530_L2Fit_fwvt1c1d20160404p1-8.txt File generation date: 20251202T010018.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Natalia Kouremeti Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v3d20160330.txt Instrument calibration file used: Pandora120s1_CF_v1d20160404.txt Level 1 file used: Pandora120s1_Davos_20180530_L1_smca1c1d20160404p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20180530 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0882 492.2101 492.3319 492.4538 492.5756 492.6974 492.8193 492.9410 493.0628 493.1846 493.3063 493.4280 493.5497 493.6714 493.7931 493.9148 494.0364 494.1580 494.2796 494.4012 494.5228 494.6444 494.7659 494.8874 495.0089 495.1304 495.2519 495.3734 495.4948 495.6163 495.7377 495.8591 495.9804 496.1018 496.2231 496.3445 496.4658 496.5871 496.7084 496.8296 496.9509 497.0721 497.1933 497.3145 497.4357 497.5569 497.6780 497.7991 497.9203 498.0414 498.1624 498.2835 498.4046 498.5256 498.6466 498.7676 498.8886 499.0095 499.1305 499.2514 499.3723 499.4932 499.6141 499.7350 499.8558 499.9767 500.0975 500.2183 500.3391 500.4598 500.5806 500.7013 500.8220 500.9427 501.0634 501.1841 501.3047 501.4254 501.5460 501.6666 501.7872 501.9077 502.0283 502.1488 502.2693 502.3898 502.5103 502.6308 502.7512 502.8717 502.9921 503.1125 503.2329 503.3532 503.4736 503.5939 503.7142 503.8345 503.9548 504.0751 504.1953 504.3156 504.4358 504.5560 504.6761 504.7963 504.9165 505.0366 505.1567 505.2768 505.3969 505.5169 505.6370 505.7570 505.8770 505.9970 506.1170 506.2370 506.3569 506.4768 506.5967 506.7166 506.8365 506.9564 507.0762 507.1960 507.3159 507.4356 507.5554 507.6752 507.7949 507.9146 508.0344 508.1540 508.2737 508.3934 508.5130 508.6326 508.7522 508.8718 508.9914 509.1110 509.2305 509.3500 509.4695 509.5890 509.7085 509.8279 509.9474 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180530T033911.0Z 6724.152211 142 1 32.00 2 89.78 57.51 84.55 234.02 0.00 1 0.00 1 0 15 9.740e-02 9.161e-02 8.622e-02 8.339e-02 8.986549e+02 4.757197e+03 1.037554e+02 -6.000000e+00 5.097543e+03 273.23 -2.00 20.00 -2.00 505.21 0.00e+00 2.593612e-03 2.226316e-03 5.925427e-05 -6.000000e+00 2.652022e-03 273.23 -2.00 20.00 -2.00 499.81 0.00e+00 2.163172e+00 1.724340e+00 1.069974e-02 -6.000000e+00 1.941314e+00 231.08 -2.00 3.62 -2.00 501.48 0.00e+00 20.459 0.170 489.00 513.00 1 4.1099e+00 1.3177e-01 3.1457e-02 -6.0000e+00 1.4783e-01 1.2722e-01 3.4716e-02 1.7252e-03 -6.0000e+00 3.9169e-02 2.3599e-03 -2.6554e-03 7.4942e-03 3.0207e-05 -6.0000e+00 8.9962e-03 7.8878e-02 12 8 8 10 0 0 -8.32 15.27 2.20 0.07888 0.06046 8 1 1 2 0 4000.000 15.00 15.27 20.25 20.46 -1783 -3569 -10319 395 -4211 4710 -11372 22169 -7343 3847 7741 -3081 -4575 116 11184 -9027 -11199 2561 7374 -10959 10256 -526 -1173 -6156 5150 208 9639 -4917 7271 -5461 15273 10709 9687 4183 -9535 3371 -3718 11918 -4132 10805 -5744 5769 -9518 4776 -4067 8444 -9730 9595 6107 4814 11243 -9779 15585 -11325 11570 -6834 -2826 -6146 14431 218 26070 -6027 8800 -10778 4919 1596 9975 2553 3020 -1730 2935 4469 -8911 5638 -16015 21702 3994 442 -6570 11118 -9303 -2668 6771 4778 12140 3836 3315 6478 -5269 94 15137 -2321 6167 1769 8767 -8788 -2096 -6481 12463 2417 -7419 13973 16367 7244 -2540 21355 -12805 -483 -3921 20785 -17840 -969 -13820 22611 -13901 15560 -8292 1195 -13206 -8538 10464 -1565 9099 2647 9645 -362 3930 -2050 5817 -4359 6103 -13665 23718 -5032 5031 -7170 8931 1358 12219 -8520 1717 24309 -10161 -2433 -11058 7709 -14753 4813 900000 -1830 -3847 -12354 437 -4992 5208 -14929 20802 -9143 4208 8019 -3499 -5195 125 10762 -10771 -13988 2862 7962 -13895 10767 -600 -1352 -7506 5618 238 9898 -5689 7183 -5989 13633 10226 9701 4564 -12016 3697 -4317 11682 -4717 10632 -6725 6092 -11589 5089 -4743 8629 -11755 9368 6009 4645 9909 -10513 13144 -12886 10813 -7840 -3135 -7028 13377 233 21640 -6915 8675 -12775 4897 1613 9133 2483 2879 -1677 2724 4131 -9545 5243 -18254 16598 3581 407 -6477 9225 -9532 -2570 5983 4346 10299 3532 3059 5784 -5311 91 12785 -2313 5641 1670 7575 -8836 -1917 -6035 9433 2027 -7016 11058 13042 6377 -2439 15854 -13178 -439 -3743 15808 -19893 -946 -15140 17689 -15402 13161 -8657 1118 -14023 -8520 8565 -1451 7642 2378 8083 -335 3476 -1925 5030 -4110 5082 -13660 16214 -4629 4279 -7040 7580 1256 10197 -8588 1569 18215 -10542 -2321 -11281 6337 -14819 3948 900000 SO 20180530T034337.0Z 6724.155289 146 1 32.00 2 89.13 58.31 85.15 234.84 0.00 1 0.00 1 0 15 7.822e-02 5.859e-02 6.429e-02 6.258e-02 9.081349e+02 3.543519e+03 3.959599e+01 -6.000000e+00 4.093333e+03 273.24 -2.00 20.00 -2.00 505.21 0.00e+00 8.987374e-04 1.676107e-03 4.057211e-05 -6.000000e+00 2.127673e-03 273.24 -2.00 20.00 -2.00 499.88 0.00e+00 3.489059e+00 1.272555e+00 3.340436e-02 -6.000000e+00 1.552142e+00 231.08 -2.00 3.62 -2.00 501.54 0.00e+00 19.251 0.142 489.00 513.00 1 3.8873e+00 9.7681e-02 2.8340e-02 -6.0000e+00 1.1833e-01 7.3810e-02 2.5162e-02 1.6410e-03 -6.0000e+00 3.1110e-02 3.1727e-03 2.3495e-03 5.6421e-03 1.6381e-05 -6.0000e+00 7.2127e-03 -9.9549e-03 12 8 8 10 0 0 3.21 15.27 2.08 -0.00995 0.00634 8 1 1 2 0 4000.000 15.00 15.27 20.25 20.46 908 -11443 -2247 -2243 4810 655 -2852 5533 -1244 -2483 -2021 6519 1975 -1217 -8822 -3191 -1209 1398 -1731 -1407 -5691 968 888 -2990 4043 -8423 7045 -3726 15120 2465 5712 4670 -1584 4403 1508 1648 8691 2109 -4505 9739 -8000 5264 3449 -423 -7296 1369 2011 -2869 4405 2953 3048 -3970 -5700 2725 5907 3563 1792 4651 8727 -8053 12089 -4276 3635 -1205 -636 6886 2432 -931 9632 -4092 -6594 -1367 606 2371 -6822 611 -8778 -2853 89 -740 3513 -1034 -8585 2337 3863 451 -8113 6003 -4393 117 -3181 4184 482 2558 5904 -428 -408 -9486 1932 -8501 3059 549 6374 2028 -95 2291 -263 8980 2632 10651 -3646 3279 3873 7741 -3713 1565 -1107 85 -9940 93 2848 404 -2209 -7901 1672 3015 8758 -1321 -2818 -11735 68505 -4152 3578 12566 12179 8740 7018 177 987 -5332 -1248 -1056 -5061 -6632 3923 412 -2932 -8629 -8484 880 -12850 -2389 -2469 5056 733 -3365 6039 -1445 -2878 -2296 6707 2094 -1317 -10031 -3545 -1313 1523 -1989 -1623 -6854 1091 1003 -3531 4467 -10525 7486 -4329 14081 2526 5620 4703 -1755 4769 1713 1862 9033 2309 -5087 9497 -9353 5441 3673 -474 -8790 1507 2173 -3199 4459 2938 2938 -4024 -5875 2642 5735 3637 1886 4755 8523 -9066 11428 -4671 3667 -1266 -654 6447 2342 -915 8388 -4037 -6661 -1322 583 2263 -7101 579 -8941 -2703 81 -685 3138 -973 -8769 2162 3547 420 -8212 5267 -4285 110 -3129 3882 466 2401 5268 -398 -370 -9163 1629 -7910 2575 489 5575 1893 -90 2094 -242 7476 2352 8939 -3518 2998 3556 6881 -3721 1495 -1086 82 -10373 86 2543 369 -2091 -7961 1533 2729 7470 -1247 -2700 -11925 31317 -3862 3052 9831 9755 7274 6060 166 927 -5362 -1211 -1030 -5169 -6878 3618 385 -2754 -8453 -8334 SO 20180530T034756.0Z 6724.158287 150 1 32.02 2 88.50 59.09 85.75 235.64 0.00 1 0.00 1 0 15 4.453e-02 4.318e-02 4.522e-02 4.449e-02 3.888502e+03 2.790277e+03 3.974666e+02 -6.000000e+00 2.330328e+03 273.24 -2.00 20.00 -2.00 505.24 0.00e+00 1.589280e-03 1.189479e-03 7.929996e-05 -6.000000e+00 1.210845e-03 273.24 -2.00 20.00 -2.00 499.94 0.00e+00 1.842575e+00 9.114065e-01 1.183053e-02 -6.000000e+00 8.819885e-01 231.08 -2.00 3.62 -2.00 501.60 0.00e+00 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