File name: Pandora120s1_Davos_20201124_L2Fit_fout2c1d20200806p1-8.txt File generation date: 20251120T223506.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v1d20200806.txt Level 1 file used: Pandora120s1_Davos_20201124_L1_smca1c1d20200806p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20201124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1371 305.2785 305.4199 305.5613 305.7027 305.8441 305.9855 306.1268 306.2682 306.4095 306.5508 306.6922 306.8335 306.9748 307.1160 307.2573 307.3986 307.5398 307.6811 307.8223 307.9635 308.1047 308.2459 308.3871 308.5282 308.6694 308.8105 308.9517 309.0928 309.2339 309.3750 309.5161 309.6572 309.7982 309.9393 310.0803 310.2214 310.3624 310.5034 310.6444 310.7854 310.9264 311.0673 311.2083 311.3492 311.4902 311.6311 311.7720 311.9129 312.0538 312.1946 312.3355 312.4763 312.6172 312.7580 312.8988 313.0396 313.1804 313.3212 313.4620 313.6027 313.7435 313.8842 314.0249 314.1657 314.3064 314.4470 314.5877 314.7284 314.8690 315.0097 315.1503 315.2909 315.4316 315.5722 315.7127 315.8533 315.9939 316.1344 316.2750 316.4155 316.5560 316.6965 316.8370 316.9775 317.1180 317.2585 317.3989 317.5393 317.6798 317.8202 317.9606 318.1010 318.2414 318.3817 318.5221 318.6624 318.8028 318.9431 319.0834 319.2237 319.3640 319.5043 319.6446 319.7848 319.9251 320.0653 320.2055 320.3457 320.4859 320.6261 320.7663 320.9064 321.0466 321.1867 321.3269 321.4670 321.6071 321.7472 321.8873 322.0273 322.1674 322.3075 322.4475 322.5875 322.7275 322.8675 323.0075 323.1475 323.2875 323.4274 323.5674 323.7073 323.8472 323.9871 324.1270 324.2669 324.4068 324.5467 324.6865 324.8264 324.9662 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201124T081515.4Z 7633.343928 98 1 52.76 2 77.83 139.20 136.99 27.13 0.00 1 0.00 1 0 25 1.315e-01 5.645e-03 1.058e-02 4.565e-04 5.747671e-01 2.207412e-04 6.864062e-03 -6.000000e+00 7.033334e-02 221.20 -2.00 3.62 -2.00 319.70 0.00e+00 1.057513e-03 6.271567e-05 3.978108e-04 -6.000000e+00 2.978025e-03 265.39 -2.00 20.00 -2.00 319.31 0.00e+00 4.613 0.002 302.00 328.00 3 4.2957e-01 6.0891e-04 4.7932e-02 -6.0000e+00 1.7342e-01 3.6628e-02 7.3063e-04 2.9785e-02 -6.0000e+00 1.9023e-01 -3.5695e-02 6.9661e-04 1.5385e-02 -6.0000e+00 1.1267e-01 8.1236e-03 3.7488e-04 4.9138e-03 -6.0000e+00 4.8445e-02 4.1025e-03 -7.4633e-05 1.1281e-05 4.2942e-05 -6.0000e+00 3.1666e-03 -4.7805e-03 0.0000e+00 10 0 0 10 0 0 90.94 14.12 0.26 -0.00478 -0.00534 814 166 2 8 0 61.050 14.99 14.12 4.75 19.54 19.75 18.1 760.06 -52132 -39890 -43400 -50246 -47624 -48414 -41934 -44541 -27734 -41176 -32685 -32915 -20071 -17670 -7683 -11194 -6570 -8590 -4518 -5667 -5800 -8959 -4914 -3340 -5957 -4600 -7258 -6645 -8804 -3398 -2696 15 -8998 -2347 -5936 -4122 -3025 -1190 -30 266 -394 486 543 197 732 282 509 -340 -114 814 2114 1319 1861 1079 1084 1140 786 413 521 367 1180 1403 2119 1860 201 650 -995 -86 701 577 596 148 301 273 -179 -318 -1174 -743 -627 -912 -728 -1558 -1891 -1397 -794 -218 105 631 899 778 979 252 167 328 242 185 776 456 49 -34 -783 -1157 -520 -396 -974 -523 -835 -496 -35 383 271 287 147 -93 -137 127 -211 80 -45 -212 -97 312 154 737 700 21 495 484 361 442 -52 -271 -172 -1 -19 -54 199 131 -204 105 -445 -451 -612 -462 -536 -602 -511 -601 -560 -716 -423 -751 -570 -693 -477 -518 -251 -432 -266 -388 -208 -277 -283 -455 -263 -195 -385 -306 -483 -417 -568 -237 -225 1 -1063 -252 -615 -446 -379 -182 -6 52 -84 108 124 45 171 67 123 -86 -30 232 673 464 710 406 424 464 323 165 201 143 497 670 1142 1001 106 352 -550 -47 446 383 416 104 200 180 -105 -184 -671 -425 -427 -678 -618 -1374 -1753 -1374 -780 -225 112 668 917 785 912 222 148 322 257 212 960 624 67 -43 -952 -1268 -572 -479 -1249 -659 -1122 -681 -54 614 437 460 236 -139 -204 190 -314 127 -72 -352 -154 474 239 1087 993 30 688 728 582 774 -92 -497 -320 -1 -39 -110 412 270 -404 203 -846 -832 SS 20201124T082140.4Z 7633.348384 101 1 52.77 2 77.13 140.55 136.47 29.24 0.00 1 0.00 1 0 25 9.290e-02 5.337e-03 8.171e-03 3.995e-04 5.487560e-01 1.924721e-04 6.576034e-03 -6.000000e+00 4.967388e-02 221.20 -2.00 3.62 -2.00 319.50 0.00e+00 8.149263e-04 5.145890e-05 3.196485e-04 -6.000000e+00 2.103112e-03 265.39 -2.00 20.00 -2.00 319.11 0.00e+00 4.377 0.002 302.00 328.00 3 3.8474e-01 5.2905e-04 4.5545e-02 -6.0000e+00 1.2248e-01 3.1175e-02 6.2666e-04 2.8318e-02 -6.0000e+00 1.3435e-01 -2.8048e-02 5.7108e-04 1.4591e-02 -6.0000e+00 7.9573e-02 5.2608e-03 3.0940e-04 4.5867e-03 -6.0000e+00 3.4217e-02 5.3085e-03 2.1533e-05 9.9320e-06 4.0364e-05 -6.0000e+00 2.2362e-03 -5.4904e-03 0.0000e+00 10 0 0 10 0 0 22.94 14.13 0.29 -0.00549 -0.00533 992 202 2 8 0 50.060 15.00 14.13 6.01 19.54 19.85 19.2 768.33 -31868 -30692 3639 -41244 -31445 -43908 -24451 -31049 -22252 -28153 -26073 -24849 -15592 -12736 -6247 -7128 -6683 -4391 -4571 -2184 -6618 -5694 -3881 -2223 -3833 -2420 -5116 -4644 -6755 -2381 -1834 572 -3022 -2214 -4666 -4440 -2801 -1041 277 -193 -402 86 326 249 319 139 219 -363 -255 1035 1503 1081 1448 938 851 1286 585 283 92 353 904 1328 1993 1833 230 302 -987 -172 677 555 636 127 376 228 -52 -400 -1019 -751 -565 -855 -707 -1615 -1910 -1223 -738 -183 105 680 767 717 857 187 66 285 300 195 831 428 23 -25 -733 -1132 -421 -369 -936 -604 -803 -464 -57 401 251 331 164 -92 -154 94 -183 126 -20 -240 -120 415 119 695 591 -20 527 462 318 436 -57 -226 -243 36 -2 -92 212 122 -166 26 -374 -459 -397 -419 40 -639 -405 -669 -351 -559 -412 -576 -540 -607 -442 -440 -247 -323 -329 -230 -254 -125 -393 -337 -247 -154 -291 -188 -398 -340 -505 -193 -177 63 -388 -273 -549 -553 -402 -182 54 -43 -97 22 85 65 85 37 60 -103 -75 327 533 386 559 388 366 573 264 124 39 151 418 692 1080 1068 131 163 -539 -100 459 392 473 95 266 160 -32 -228 -571 -454 -376 -667 -587 -1491 -1851 -1176 -758 -197 110 753 820 711 835 172 60 270 328 229 1051 568 30 -33 -910 -1272 -476 -459 -1165 -784 -1049 -652 -85 623 410 534 253 -138 -230 140 -273 201 -33 -382 -192 638 177 1036 847 -28 735 696 512 727 -100 -410 -445 72 -4 -185 432 249 -326 50 -678 -843 SS 20201124T082646.5Z 7633.351927 103 1 52.99 2 76.58 141.64 136.04 30.88 0.00 1 0.00 1 0 25 7.802e-02 5.286e-03 6.077e-03 3.625e-04 5.287262e-01 1.744069e-04 6.366792e-03 -6.000000e+00 4.172064e-02 221.20 -2.00 3.62 -2.00 319.31 0.00e+00 9.590005e-04 4.382653e-05 3.072563e-04 -6.000000e+00 1.766370e-03 265.39 -2.00 20.00 -2.00 318.92 0.00e+00 4.210 0.001 302.00 328.00 3 3.6016e-01 4.7642e-04 4.3841e-02 -6.0000e+00 1.0287e-01 2.8410e-02 5.5863e-04 2.7281e-02 -6.0000e+00 1.1284e-01 -2.6552e-02 4.8934e-04 1.4029e-02 -6.0000e+00 6.6833e-02 5.4591e-03 2.6641e-04 4.4254e-03 -6.0000e+00 2.8739e-02 6.3396e-03 -1.3602e-06 9.0517e-06 3.9645e-05 -6.0000e+00 1.8781e-03 -5.5528e-03 0.0000e+00 10 0 0 10 0 0 22.00 14.15 0.26 -0.00555 -0.00556 1090 222 2 8 0 45.560 14.99 14.15 7.25 19.54 19.85 19.6 775.13 -20554 -26081 -21733 -33993 -24681 -33090 -23449 -26242 -17761 -25144 -23546 -21359 -12620 -8499 -7021 -5226 -4257 -2981 -3669 -1300 -4667 -3892 -3882 -848 -3665 -1495 -4393 -4630 -5887 -2520 -928 521 -1062 -2538 -3652 -4038 -1841 -871 664 -355 -232 -34 335 195 579 135 213 -192 -359 604 1088 1092 1501 1063 613 1324 622 477 70 376 918 1333 1996 1559 180 266 -999 -351 798 342 556 -43 431 163 -53 -367 -1064 -761 -542 -839 -663 -1596 -1903 -1260 -771 -182 62 681 708 594 849 259 23 392 274 274 761 458 64 -33 -752 -1094 -392 -323 -917 -592 -805 -448 -11 367 244 270 185 -84 -166 102 -146 86 -79 -255 -94 428 122 716 619 63 490 443 304 451 20 -238 -200 23 -9 -131 156 129 -156 49 -386 -481 -314 -466 -380 -607 -367 -557 -409 -551 -384 -607 -576 -606 -415 -335 -332 -274 -240 -181 -237 -86 -318 -264 -288 -67 -321 -133 -391 -391 -501 -234 -101 65 -151 -353 -478 -563 -293 -170 143 -89 -62 -10 97 57 170 40 64 -60 -116 210 387 424 629 476 286 637 303 225 32 174 459 692 1163 977 110 153 -580 -217 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