File name: Pandora120s1_Davos_20210105_L2Fit_fwvt1c1d20200806p1-8.txt File generation date: 20251120T224222.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v1d20200806.txt Level 1 file used: Pandora120s1_Davos_20210105_L1_smca1c1d20200806p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8000 Location longitude [deg]: 9.8300 Location altitude [m]: 1590 Local noon date: 20210105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0967 492.2186 492.3405 492.4624 492.5842 492.7061 492.8279 492.9498 493.0716 493.1933 493.3151 493.4369 493.5586 493.6803 493.8020 493.9237 494.0454 494.1670 494.2887 494.4103 494.5319 494.6535 494.7751 494.8966 495.0182 495.1397 495.2612 495.3827 495.5041 495.6256 495.7470 495.8685 495.9899 496.1113 496.2326 496.3540 496.4753 496.5967 496.7180 496.8393 496.9605 497.0818 497.2030 497.3243 497.4455 497.5667 497.6878 497.8090 497.9301 498.0513 498.1724 498.2935 498.4145 498.5356 498.6566 498.7777 498.8987 499.0197 499.1406 499.2616 499.3826 499.5035 499.6244 499.7453 499.8662 499.9870 500.1079 500.2287 500.3495 500.4703 500.5911 500.7118 500.8326 500.9533 501.0740 501.1947 501.3154 501.4360 501.5567 501.6773 501.7979 501.9185 502.0391 502.1596 502.2802 502.4007 502.5212 502.6417 502.7622 502.8826 503.0031 503.1235 503.2439 503.3643 503.4847 503.6050 503.7254 503.8457 503.9660 504.0863 504.2066 504.3268 504.4471 504.5673 504.6875 504.8077 504.9279 505.0480 505.1682 505.2883 505.4084 505.5285 505.6486 505.7686 505.8886 506.0087 506.1287 506.2487 506.3686 506.4886 506.6085 506.7284 506.8483 506.9682 507.0881 507.2079 507.3278 507.4476 507.5674 507.6872 507.8069 507.9267 508.0464 508.1661 508.2858 508.4055 508.5252 508.6448 508.7645 508.8841 509.0037 509.1233 509.2428 509.3624 509.4819 509.6014 509.7209 509.8404 509.9598 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210105T085257.2Z 7675.370106 3 1 6.33 2 77.51 144.11 70.80 253.54 0.00 1 0.00 1 0 8 3.362e-03 3.334e-03 7.379e-05 7.370e-05 6.159229e+02 3.697853e+00 5.690376e+01 -6.000000e+00 1.676031e+02 261.68 -2.00 20.00 -2.00 505.27 0.00e+00 4.824304e-04 1.910323e-06 2.586650e-05 -6.000000e+00 8.901192e-05 261.68 -2.00 20.00 -2.00 500.50 0.00e+00 4.553711e-01 1.440100e-03 5.982021e-03 -6.000000e+00 6.639437e-02 221.88 -2.00 3.62 -2.00 502.09 0.00e+00 4.502 0.002 489.00 513.00 1 2.2633e-01 1.0950e-04 5.3191e-03 -6.0000e+00 5.0478e-03 -2.6754e-03 2.8798e-05 3.1525e-04 -6.0000e+00 1.3287e-03 8.9044e-01 1.2599e-04 6.6513e-06 1.2823e-05 -6.0000e+00 3.0981e-04 -4.5833e-03 -1.1606e-04 10 0 0 10 0 0 0.73 13.32 0.37 -0.00458 -0.00371 1644 334 2 2 0 3.330 15.00 13.32 -1.37 18.83 19.04 20.4 754.72 -886 -659 -107 145 109 436 528 463 477 195 148 -3 -248 -231 -329 -327 -226 160 369 174 229 195 69 304 330 267 316 272 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-114 31 277 359 332 431 528 539 355 213 96 -175 -90 235 100 138 309 95 113 385 148 -58 -76 -372 -508 -124 114 64 231 298 132 167 251 275 313 219 -121 -477 -684 -619 SQ 20210105T085304.4Z 7675.370189 3 2 6.71 2 77.50 144.14 70.82 253.56 0.00 1 0.00 1 0 8 3.359e-03 3.331e-03 7.401e-05 7.391e-05 6.178409e+02 3.712562e+00 5.623969e+01 -6.000000e+00 1.674561e+02 261.68 -2.00 20.00 -2.00 505.27 0.00e+00 4.847347e-04 1.915645e-06 2.594087e-05 -6.000000e+00 8.893401e-05 261.68 -2.00 20.00 -2.00 500.49 0.00e+00 4.546146e-01 1.444968e-03 6.110187e-03 -6.000000e+00 6.633646e-02 221.88 -2.00 3.62 -2.00 502.08 0.00e+00 4.498 0.002 489.00 513.00 1 2.3204e-01 1.0986e-04 5.3156e-03 -6.0000e+00 5.0434e-03 -2.6467e-03 2.8898e-05 3.1596e-04 -6.0000e+00 1.3275e-03 8.8580e-01 1.4050e-04 6.6742e-06 1.2748e-05 -6.0000e+00 3.0954e-04 -4.8074e-03 -1.1499e-04 10 0 0 10 0 0 -4.90 13.32 0.37 -0.00481 -0.00383 1644 334 2 2 0 3.330 15.00 13.32 -1.01 18.83 19.04 20.4 755.90 -888 -678 -130 126 103 430 541 468 494 205 146 0 -254 -226 -324 -337 -219 164 368 161 218 193 67 311 329 283 328 259 -244 -509 -507 -715 -235 427 327 160 138 -43 -243 -213 -128 -41 113 281 356 351 264 162 32 -335 -553 -772 -955 -565 -139 134 249 194 129 116 259 300 340 368 216 68 -42 -49 -267 -411 -299 -348 -150 230 162 -117 -285 -325 -412 -403 -196 -287 -272 19 -29 -54 -43 -100 -95 -171 50 377 407 320 345 192 -108 -225 -530 -718 -691 -476 187 257 31 -25 -356 -497 -267 -107 46 262 364 330 443 526 519 358 232 105 -192 -100 231 90 127 296 109 128 404 149 -57 -86 -393 -524 -120 122 67 230 300 152 142 251 266 305 218 -132 -489 -696 -656 -860 -669 -130 128 106 448 563 491 516 212 151 0 -256 -229 -327 -337 -223 168 379 168 227 202 70 325 345 297 343 266 -248 -512 -503 -719 -239 440 340 166 144 -45 -248 -216 -130 -42 117 290 369 364 271 166 32 -335 -546 -748 -924 -556 -138 135 254 196 132 118 261 304 345 372 219 68 -42 -48 -262 -399 -289 -340 -148 227 160 -116 -276 -311 -400 -385 -189 -279 -267 19 -29 -54 -43 -99 -95 -169 50 375 408 319 344 188 -106 -218 -504 -679 -662 -462 185 255 31 -24 -351 -486 -262 -105 46 260 366 334 449 536 529 361 231 105 -189 -98 227 89 126 293 107 126 398 145 -55 -82 -375 -501 -116 119 65 228 299 150 141 251 267 306 217 -131 -473 -673 -634 SQ 20210105T085311.1Z 7675.370267 3 3 6.13 2 77.48 144.16 70.84 253.59 0.00 1 0.00 1 0 8 3.371e-03 3.342e-03 7.409e-05 7.400e-05 6.237126e+02 3.719283e+00 5.709678e+01 -6.000000e+00 1.680314e+02 261.68 -2.00 20.00 -2.00 505.27 0.00e+00 4.796576e-04 1.917358e-06 2.566567e-05 -6.000000e+00 8.923945e-05 261.68 -2.00 20.00 -2.00 500.50 0.00e+00 4.510455e-01 1.446281e-03 6.047354e-03 -6.000000e+00 6.656413e-02 221.88 -2.00 3.62 -2.00 502.08 0.00e+00 4.494 0.002 489.00 513.00 1 2.3495e-01 1.0996e-04 5.3101e-03 -6.0000e+00 5.0607e-03 -2.6068e-03 2.8926e-05 3.1562e-04 -6.0000e+00 1.3321e-03 8.8390e-01 1.1539e-04 6.6837e-06 1.2791e-05 -6.0000e+00 3.1061e-04 -4.7962e-03 -1.1483e-04 10 0 0 10 0 0 -11.94 13.32 0.37 -0.00480 -0.00400 1644 334 2 2 0 3.330 15.00 13.32 -1.01 18.83 19.04 20.4 755.90 -870 -657 -134 136 98 432 529 451 502 193 156 -4 -263 -221 -343 -342 -228 145 380 170 217 191 63 309 333 274 317 290 -221 -527 -515 -724 -254 418 336 159 157 -39 -235 -208 -123 -35 106 274 375 341 258 156 36 -334 -579 -787 -986 -543 -139 128 256 189 136 114 269 309 350 398 210 69 -41 -54 -264 -420 -305 -359 -137 233 165 -142 -292 -334 -418 -360 -199 -289 -265 23 -16 -47 -52 -105 -105 -153 58 391 416 310 337 199 -118 -206 -539 -730 -680 -479 202 242 47 -12 -356 -492 -280 -128 21 264 368 344 414 506 532 355 215 104 -190 -100 236 80 130 291 104 132 410 161 -54 -76 -398 -537 -122 102 66 238 322 145 160 244 263 303 215 -124 -501 -678 -646 -841 -647 -134 138 100 449 550 473 524 199 162 -4 -265 -224 -346 -341 -232 148 398 177 225 199 66 323 350 288 330 297 -224 -529 -511 -727 -257 430 348 165 163 -40 -240 -211 -125 -36 109 282 389 353 265 161 36 -333 -571 -762 -953 -534 -138 129 262 194 139 117 271 313 355 402 213 69 -41 -53 -259 -407 -295 -351 -136 229 163 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