File name: Pandora289s1_DeBilt_20250517_L2Fit_fout2c1d20250508p1-8.txt File generation date: 20260519T135100.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora289_OF_v1d20240910.txt Instrument calibration file used: Pandora289s1_CF_v1d20250508.txt Level 1 file used: Pandora289s1_DeBilt_20250517_L1_smca1c1d20250508p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20250517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.1323 305.2727 305.4130 305.5534 305.6937 305.8340 305.9743 306.1146 306.2549 306.3952 306.5354 306.6757 306.8159 306.9561 307.0964 307.2366 307.3768 307.5169 307.6571 307.7973 307.9374 308.0776 308.2177 308.3578 308.4979 308.6380 308.7781 308.9182 309.0582 309.1983 309.3383 309.4783 309.6183 309.7583 309.8983 310.0383 310.1783 310.3182 310.4582 310.5981 310.7380 310.8780 311.0179 311.1577 311.2976 311.4375 311.5773 311.7172 311.8570 311.9968 312.1366 312.2764 312.4162 312.5560 312.6958 312.8355 312.9753 313.1150 313.2547 313.3944 313.5341 313.6738 313.8135 313.9531 314.0928 314.2324 314.3720 314.5116 314.6512 314.7908 314.9304 315.0700 315.2095 315.3491 315.4886 315.6281 315.7677 315.9072 316.0466 316.1861 316.3256 316.4650 316.6045 316.7439 316.8833 317.0227 317.1621 317.3015 317.4409 317.5803 317.7196 317.8589 317.9983 318.1376 318.2769 318.4162 318.5555 318.6947 318.8340 318.9732 319.1125 319.2517 319.3909 319.5301 319.6693 319.8085 319.9476 320.0868 320.2259 320.3650 320.5042 320.6433 320.7824 320.9214 321.0605 321.1996 321.3386 321.4777 321.6167 321.7557 321.8947 322.0337 322.1727 322.3116 322.4506 322.5895 322.7285 322.8674 323.0063 323.1452 323.2841 323.4229 323.5618 323.7006 323.8395 323.9783 324.1171 324.2559 324.3947 324.5335 324.6723 324.8110 324.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250517T042108.8Z 9268.181352 208 1 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0.00 1 0 17 1.122e-02 7.548e-03 2.697e-04 1.430e-04 2.647083e-01 7.368103e-05 3.437312e-03 -6.000000e+00 6.504010e-03 231.23 -2.00 3.84 -2.00 316.02 0.00e+00 5.359429e-04 7.030660e-06 4.012090e-05 -6.000000e+00 2.592696e-04 277.00 -2.00 20.00 -2.00 315.70 0.00e+00 1.680 0.000 302.00 328.00 3 2.5090e-01 1.9258e-04 2.2645e-02 -6.0000e+00 1.6416e-02 -7.7387e-04 2.1453e-04 1.4844e-02 -6.0000e+00 1.7862e-02 -1.4581e-03 1.2326e-04 7.2643e-03 -6.0000e+00 1.0471e-02 -1.5509e-03 5.5861e-05 2.0137e-03 -6.0000e+00 4.3211e-03 5.5614e-02 1.9047e-04 4.0707e-06 2.4084e-05 -6.0000e+00 3.0668e-04 1.0412e-02 0.0000e+00 11 8 0 10 0 0 91.03 24.94 0.29 0.01041 0.01184 1954 1954 1 5 0 15.350 34.00 20.00 24.94 23.57 0.0 986.91 256 -326 -1363 -3412 -3764 -3596 -94 1091 -170 -2160 -3030 -1828 -646 580 752 217 232 983 998 2011 782 461 525 1277 1313 401 -593 -348 -630 -421 1510 1861 1296 -1704 -3246 -3524 -2142 -118 -58 -508 -578 -528 -352 -351 300 -40 -321 -316 -689 -22 891 1205 1072 764 571 1099 671 225 137 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142 -300 -1392 -3657 -3914 -3794 -386 996 -321 -2306 -3244 -1846 -721 468 712 85 232 1059 987 1940 936 498 489 1202 1328 462 -548 -478 -654 -506 1474 1860 1349 -1620 -3339 -3583 -2342 -147 19 -542 -582 -494 -282 -301 265 16 -272 -323 -663 -53 878 1183 1081 847 611 1079 695 222 126 208 794 1770 1894 1939 656 -806 -1454 -1139 1030 857 371 416 252 531 97 -740 -1418 -1853 -975 -878 -1252 -1524 -2140 -1787 -1036 -548 372 276 664 863 845 -10 -672 -18 174 317 242 694 758 197 -766 -1491 -516 -215 -434 -914 -549 -892 77 615 831 577 416 148 -111 -154 47 0 327 200 270 15 273 475 800 397 -338 455 514 543 123 -671 -420 -135 126 38 44 181 277 196 -212 -777 -739 30 -62 -282 -752 -738 -710 -78 209 -73 -541 -772 -465 -192 143 227 29 83 390 379 761 350 187 189 493 576 204 -235 -194 -254 -197 612 850 615 -748 -1494 -1620 -1183 -79 11 -351 -387 -341 -198 -212 186 11 -187 -216 -463 -36 628 869 841 656 488 880 574 182 102 168 669 1537 1710 1756 611 -701 -1228 -967 911 819 369 425 254 510 89 -666 -1221 -1569 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1.9753e-04 4.0754e-06 2.4618e-05 -6.0000e+00 3.1382e-04 7.9820e-03 0.0000e+00 11 8 0 10 0 0 24.08 25.46 0.28 0.00798 0.00947 1913 1913 1 5 0 15.680 34.25 19.99 25.46 25.58 0.0 993.23 76 -287 -1379 -3401 -4068 -3640 -561 819 -308 -2300 -3316 -2025 -708 410 674 96 172 983 1040 1919 913 436 421 1180 1429 458 -577 -504 -629 -503 1467 1807 1374 -1632 -3359 -3593 -2337 -140 18 -509 -574 -423 -319 -318 319 26 -287 -298 -656 -69 862 1246 1074 837 608 1086 684 206 124 192 795 1781 1910 1936 633 -774 -1447 -1090 1024 874 392 413 229 534 58 -740 -1431 -1878 -997 -868 -1250 -1491 -2159 -1772 -1018 -532 379 290 671 882 849 6 -675 -47 177 275 232 692 757 200 -787 -1498 -517 -217 -450 -915 -554 -899 94 617 838 568 423 125 -113 -140 56 1 334 196 266 42 281 467 804 388 -367 459 530 538 113 -672 -422 -114 103 32 54 183 286 194 -206 -784 -734 16 -58 -294 -678 -747 -662 -110 181 -68 -525 -770 -498 -198 123 225 32 60 355 391 738 358 171 160 475 608 199 -244 -201 -240 -193 600 814 617 -744 -1484 -1603 -1165 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-6.0000e+00 1.0851e-02 -1.7487e-03 5.7757e-05 2.1332e-03 -6.0000e+00 4.4791e-03 5.3437e-02 2.0076e-04 4.1267e-06 2.4825e-05 -6.0000e+00 3.1765e-04 8.0389e-03 0.0000e+00 11 8 0 10 0 0 18.32 25.44 0.28 0.00804 0.00955 1879 1879 1 5 0 15.960 34.25 20.00 25.44 25.51 0.0 993.30 87 -398 -1505 -3429 -4052 -3845 -600 970 -403 -2397 -3524 -1955 -686 450 647 187 174 1061 1009 1996 924 510 500 1239 1378 446 -590 -464 -667 -539 1385 1906 1304 -1714 -3326 -3572 -2319 -182 57 -491 -558 -456 -328 -331 283 43 -237 -310 -711 -17 910 1270 1079 819 622 1077 698 223 118 226 804 1777 1911 1954 658 -758 -1439 -1076 987 878 376 411 236 535 100 -710 -1436 -1864 -978 -842 -1236 -1525 -2149 -1756 -1026 -514 379 270 660 864 826 -10 -676 -57 151 277 215 706 747 221 -763 -1517 -528 -217 -427 -911 -570 -918 76 617 834 574 418 143 -115 -146 62 -15 348 178 263 31 276 482 821 366 -352 485 536 545 116 -673 -420 -102 130 22 42 191 281 201 -222 -775 -752 17 -84 -312 -664 -722 -681 -115 208 -87 -533 -798 -468 -187 131 211 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1.7044e-02 -2.7922e-03 2.1924e-04 1.5781e-02 -6.0000e+00 1.8543e-02 -1.1595e-03 1.2675e-04 7.7305e-03 -6.0000e+00 1.0870e-02 -1.7255e-03 5.8164e-05 2.1491e-03 -6.0000e+00 4.4870e-03 5.3478e-02 2.1227e-04 4.1408e-06 2.4749e-05 -6.0000e+00 3.1821e-04 8.0066e-03 0.0000e+00 11 8 0 10 0 0 27.81 25.43 0.29 0.00801 0.00960 1913 1913 1 5 0 15.680 34.25 20.00 25.43 25.48 0.0 993.35 141 -265 -1351 -3581 -4071 -3952 -634 848 -440 -2406 -3356 -2050 -734 446 671 161 226 980 1037 1961 921 475 542 1237 1436 488 -602 -516 -707 -526 1418 1813 1400 -1628 -3277 -3523 -2364 -166 18 -509 -539 -429 -337 -319 327 7 -227 -366 -663 -87 893 1290 1078 870 608 1059 717 211 56 209 804 1792 1923 1997 650 -815 -1406 -1077 1039 863 385 433 250 505 108 -746 -1418 -1905 -1033 -817 -1271 -1516 -2144 -1770 -1022 -517 368 283 654 870 848 -5 -691 -32 137 269 195 717 731 191 -759 -1483 -535 -209 -422 -926 -556 -907 88 614 843 569 418 130 -120 -132 41 -16 362 184 251 -10 291 472 823 373 -351 473 537 531 107 -705 -429 -126 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20.00 -2.00 315.94 0.00e+00 1.696 0.000 302.00 328.00 3 2.4615e-01 1.9720e-04 2.3511e-02 -6.0000e+00 1.7110e-02 -2.9531e-03 2.1976e-04 1.5865e-02 -6.0000e+00 1.8615e-02 -1.0128e-03 1.2701e-04 7.7724e-03 -6.0000e+00 1.0913e-02 -1.7651e-03 5.8300e-05 2.1596e-03 -6.0000e+00 4.5044e-03 5.3187e-02 2.0774e-04 4.1450e-06 2.4891e-05 -6.0000e+00 3.1946e-04 8.1965e-03 0.0000e+00 11 8 0 10 0 0 33.06 25.42 0.29 0.00820 0.00976 1892 1892 1 5 0 15.850 34.25 19.99 25.42 25.44 0.0 993.19 87 -445 -1544 -3706 -4050 -3841 -769 950 -466 -2447 -3443 -2078 -753 541 675 120 227 951 948 1942 876 506 514 1315 1415 454 -636 -478 -703 -473 1420 1894 1395 -1602 -3264 -3535 -2330 -117 29 -477 -579 -459 -331 -272 310 30 -243 -275 -661 -84 902 1290 1103 829 614 1078 681 241 101 215 833 1803 1921 1949 659 -755 -1419 -1084 1004 845 392 422 250 525 88 -764 -1454 -1919 -990 -852 -1237 -1498 -2149 -1768 -1039 -528 356 282 654 872 845 -24 -650 -52 140 293 221 687 748 190 -766 -1509 -535 -223 -422 -913 -573 -902 88 597 832 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