File name: Pandora289s1_DeBilt_20250630_L2Fit_fout2c1d20250508p1-8.txt File generation date: 20260519T141238.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora289_OF_v1d20240910.txt Instrument calibration file used: Pandora289s1_CF_v1d20250508.txt Level 1 file used: Pandora289s1_DeBilt_20250630_L1_smca1c1d20250508p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20250630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.1323 305.2727 305.4130 305.5534 305.6937 305.8340 305.9743 306.1146 306.2549 306.3952 306.5354 306.6757 306.8159 306.9561 307.0964 307.2366 307.3768 307.5169 307.6571 307.7973 307.9374 308.0776 308.2177 308.3578 308.4979 308.6380 308.7781 308.9182 309.0582 309.1983 309.3383 309.4783 309.6183 309.7583 309.8983 310.0383 310.1783 310.3182 310.4582 310.5981 310.7380 310.8780 311.0179 311.1577 311.2976 311.4375 311.5773 311.7172 311.8570 311.9968 312.1366 312.2764 312.4162 312.5560 312.6958 312.8355 312.9753 313.1150 313.2547 313.3944 313.5341 313.6738 313.8135 313.9531 314.0928 314.2324 314.3720 314.5116 314.6512 314.7908 314.9304 315.0700 315.2095 315.3491 315.4886 315.6281 315.7677 315.9072 316.0466 316.1861 316.3256 316.4650 316.6045 316.7439 316.8833 317.0227 317.1621 317.3015 317.4409 317.5803 317.7196 317.8589 317.9983 318.1376 318.2769 318.4162 318.5555 318.6947 318.8340 318.9732 319.1125 319.2517 319.3909 319.5301 319.6693 319.8085 319.9476 320.0868 320.2259 320.3650 320.5042 320.6433 320.7824 320.9214 321.0605 321.1996 321.3386 321.4777 321.6167 321.7557 321.8947 322.0337 322.1727 322.3116 322.4506 322.5895 322.7285 322.8674 323.0063 323.1452 323.2841 323.4229 323.5618 323.7006 323.8395 323.9783 324.1171 324.2559 324.3947 324.5335 324.6723 324.8110 324.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250630T040350.7Z 9312.169337 82 1 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167 48 61 309 469 328 -300 -1164 -1136 SU 20250630T074147.5Z 9312.320689 324 1 30.01 2 53.85 98.40 103.46 58.01 0.00 1 0.00 1 0 17 1.070e-02 7.746e-03 2.231e-04 1.359e-04 2.279130e-01 7.070287e-05 2.954966e-03 -6.000000e+00 6.262896e-03 233.76 -2.00 3.84 -2.00 315.55 0.00e+00 4.781917e-04 6.082537e-06 2.928214e-05 -6.000000e+00 2.472630e-04 281.83 -2.00 20.00 -2.00 315.24 0.00e+00 1.691 0.000 302.00 328.00 3 2.0088e-01 1.8502e-04 2.1449e-02 -6.0000e+00 1.5906e-02 2.8261e-03 2.0530e-04 1.2954e-02 -6.0000e+00 1.7270e-02 -1.3941e-03 1.1702e-04 6.2714e-03 -6.0000e+00 1.0104e-02 -2.0239e-03 5.1479e-05 1.7153e-03 -6.0000e+00 4.1499e-03 6.1993e-02 1.0500e-04 3.8581e-06 2.1191e-05 -6.0000e+00 2.9257e-04 6.2479e-03 0.0000e+00 11 8 0 10 0 0 5.51 25.96 0.29 0.00625 0.00704 1954 1954 1 5 0 15.350 34.75 20.00 25.96 29.83 0.0 1010.07 507 -38 -828 -2824 -3109 -2915 289 1648 384 -1700 -2878 -1507 -474 722 857 154 200 939 885 1873 759 419 448 1235 1333 447 -467 -350 -524 -436 1447 1827 1379 -1569 -3302 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11 8 0 10 0 0 2.71 26.01 0.29 0.00598 0.00665 2015 2015 1 5 0 14.890 34.75 20.01 26.01 30.03 0.0 1010.93 482 -87 -867 -2964 -3018 -2941 253 1644 300 -1605 -2711 -1423 -334 838 877 104 136 943 943 1870 697 380 418 1174 1302 538 -483 -330 -486 -411 1431 1793 1456 -1611 -3196 -3474 -2325 -131 2 -623 -695 -588 -466 -445 193 -69 -357 -432 -834 -129 817 1148 1009 854 625 1096 698 248 143 199 785 1683 1844 1931 594 -735 -1410 -1133 1038 931 328 415 294 623 201 -653 -1402 -1887 -953 -819 -1261 -1526 -2160 -1764 -1031 -527 344 256 644 900 853 -7 -688 -22 175 249 211 718 823 253 -753 -1496 -556 -227 -474 -941 -551 -958 32 599 843 639 449 162 -76 -143 -1 -28 320 195 261 41 290 446 849 452 -345 459 530 531 161 -696 -434 -112 94 17 22 206 301 214 -194 -778 -787 135 -25 -248 -787 -785 -754 70 471 93 -510 -865 -473 -116 309 358 45 58 408 423 856 325 177 199 556 651 273 -238 -161 -225 -189 690 888 758 -847 -1622 -1774 -1253 -79 2 -435 -521 -437 -351 -336 145 -52 -271 -318 -605 -95 626 899 800 701 527 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6.5676e-02 7.7691e-05 3.7549e-06 2.0678e-05 -6.0000e+00 2.9184e-04 6.0086e-03 0.0000e+00 11 8 0 10 0 0 5.80 26.02 0.29 0.00601 0.00659 2012 2012 1 5 0 14.910 34.75 20.00 26.02 30.05 0.0 1011.11 537 1 -830 -3014 -3097 -2898 169 1689 373 -1626 -2663 -1531 -280 803 901 144 97 946 890 1767 787 426 508 1196 1355 486 -487 -366 -499 -493 1425 1814 1437 -1589 -3190 -3496 -2327 -116 22 -595 -684 -545 -478 -470 159 -95 -400 -455 -769 -126 831 1206 1049 865 615 1079 713 250 153 233 763 1718 1834 1932 621 -764 -1444 -1093 1060 920 351 432 304 601 226 -623 -1378 -1887 -938 -843 -1274 -1509 -2137 -1754 -1025 -518 343 244 676 902 855 -17 -681 -10 199 233 196 728 827 247 -734 -1459 -500 -217 -478 -944 -538 -940 36 562 835 637 438 153 -76 -138 13 -50 302 214 276 26 286 455 846 437 -342 462 523 544 130 -696 -443 -111 107 31 48 191 288 224 -206 -781 -778 152 0 -240 -812 -817 -753 47 491 117 -523 -860 -516 -99 300 372 60 42 414 403 818 371 200 244 572 684 249 -242 -181 -234 -229 694 906 754 -843 -1632 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6.0592e-03 -6.0000e+00 9.9852e-03 -2.3370e-03 4.9094e-05 1.6577e-03 -6.0000e+00 4.1014e-03 6.6925e-02 9.0151e-05 3.7140e-06 2.0544e-05 -6.0000e+00 2.8913e-04 5.9241e-03 0.0000e+00 11 8 0 10 0 0 1.51 26.04 0.30 0.00592 0.00660 2030 2030 1 5 0 14.780 34.75 20.00 26.04 30.07 0.0 1011.00 569 -77 -822 -2948 -3060 -2804 197 1605 403 -1644 -2636 -1384 -366 806 850 96 180 941 858 1786 760 434 449 1076 1356 540 -448 -329 -486 -451 1312 1785 1482 -1586 -3219 -3414 -2320 -134 41 -617 -698 -545 -478 -469 203 -84 -404 -407 -786 -130 834 1218 1077 833 598 1117 710 239 129 221 719 1702 1848 1924 648 -743 -1424 -1125 1061 896 368 438 310 622 230 -608 -1372 -1896 -967 -859 -1262 -1518 -2135 -1765 -989 -519 338 251 642 916 846 -13 -684 -27 169 248 193 749 819 260 -756 -1487 -497 -208 -456 -926 -549 -938 28 578 853 638 439 167 -95 -138 25 -53 309 198 262 44 280 446 825 464 -357 468 520 538 122 -708 -463 -106 105 32 54 193 295 213 -205 -751 -768 164 -23 -242 -806 -819 -739 52 474 129 -537 -863 -441 -130 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