File name: Pandora289s1_DeBilt_20250705_L2Fit_fout2c1d20250508p1-8.txt File generation date: 20260519T140737.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora289_OF_v1d20240910.txt Instrument calibration file used: Pandora289s1_CF_v1d20250508.txt Level 1 file used: Pandora289s1_DeBilt_20250705_L1_smca1c1d20250508p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20250705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.1323 305.2727 305.4130 305.5534 305.6937 305.8340 305.9743 306.1146 306.2549 306.3952 306.5354 306.6757 306.8159 306.9561 307.0964 307.2366 307.3768 307.5169 307.6571 307.7973 307.9374 308.0776 308.2177 308.3578 308.4979 308.6380 308.7781 308.9182 309.0582 309.1983 309.3383 309.4783 309.6183 309.7583 309.8983 310.0383 310.1783 310.3182 310.4582 310.5981 310.7380 310.8780 311.0179 311.1577 311.2976 311.4375 311.5773 311.7172 311.8570 311.9968 312.1366 312.2764 312.4162 312.5560 312.6958 312.8355 312.9753 313.1150 313.2547 313.3944 313.5341 313.6738 313.8135 313.9531 314.0928 314.2324 314.3720 314.5116 314.6512 314.7908 314.9304 315.0700 315.2095 315.3491 315.4886 315.6281 315.7677 315.9072 316.0466 316.1861 316.3256 316.4650 316.6045 316.7439 316.8833 317.0227 317.1621 317.3015 317.4409 317.5803 317.7196 317.8589 317.9983 318.1376 318.2769 318.4162 318.5555 318.6947 318.8340 318.9732 319.1125 319.2517 319.3909 319.5301 319.6693 319.8085 319.9476 320.0868 320.2259 320.3650 320.5042 320.6433 320.7824 320.9214 321.0605 321.1996 321.3386 321.4777 321.6167 321.7557 321.8947 322.0337 322.1727 322.3116 322.4506 322.5895 322.7285 322.8674 323.0063 323.1452 323.2841 323.4229 323.5618 323.7006 323.8395 323.9783 324.1171 324.2559 324.3947 324.5335 324.6723 324.8110 324.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250705T051427.5Z 9317.218374 1586 1 17.19 2 76.56 70.11 139.97 315.44 0.00 1 0.00 1 0 17 2.442e-01 1.135e-02 1.256e-01 5.601e-03 5.616817e-01 2.921634e-03 6.865155e-03 -6.000000e+00 1.439991e-01 233.83 -2.00 3.84 -2.00 320.02 0.00e+00 3.522770e-03 8.258960e-04 3.507184e-04 -6.000000e+00 5.645626e-03 282.27 -2.00 20.00 -2.00 319.70 0.00e+00 4.195 0.002 302.00 328.00 3 3.7195e+00 8.2454e-03 5.3327e-02 -6.0000e+00 3.6616e-01 1.0219e-01 9.7411e-03 3.2483e-02 -6.0000e+00 3.9790e-01 -1.0815e-01 9.1127e-03 1.6366e-02 -6.0000e+00 2.3173e-01 4.1634e-02 4.8147e-03 4.8158e-03 -6.0000e+00 9.4614e-02 1.0215e-04 -1.3198e-04 1.5829e-04 5.0542e-05 -6.0000e+00 6.8328e-03 1.3162e-02 0.0000e+00 12 9 9 12 1 1 90.23 24.62 0.27 0.01316 0.01217 7 14 1 5 0 2147.130 33.75 20.01 24.62 23.29 0.0 982.38 -104402 -152479 -75509 -6409 -35470 -119546 900000 -27039 -96517 38808 -53895 -66842 -37022 36843 -2977 -13535 -13833 -9674 -13157 -7631 -22921 -22012 -19280 -1458 -995 9556 4700 -3250 -5548 -20556 -3320 -8314 -7821 -6363 15 -9185 -1937 -4298 7262 3641 1231 5086 3241 8340 1584 -103 2875 4932 4706 3327 5547 5674 1915 3493 1924 -1004 2648 1372 661 1137 -1386 4547 3818 2120 680 806 -1825 -1686 1767 -161 813 1290 638 -656 -398 -1447 -2495 -4829 -944 -2181 654 -2331 -1764 -1584 -1179 -867 287 1261 1118 1623 307 -408 -681 -1281 -1211 -285 1080 1278 822 599 -1185 -1248 -638 -1031 -1448 -1056 187 -1089 520 411 831 454 -208 -506 -473 -372 84 -189 216 -246 897 85 1094 495 331 668 147 461 484 849 -191 -478 -98 -307 -107 137 -15 554 317 289 -84 -726 -1187 -2125 -5526 -1402 -56 -387 -3068 900000 -354 -2741 297 -1118 -1862 -970 583 -85 -488 -551 -402 -604 -346 -1227 -1178 -1053 -72 -53 464 236 -174 -309 -1459 -236 -731 -752 -608 1 -893 -201 -561 1015 605 230 969 651 1626 336 -23 626 1080 1077 828 1493 1538 585 1113 652 -363 936 485 230 396 -524 1808 1717 1051 348 395 -893 -866 911 -96 516 836 406 -397 -219 -793 -1305 -2673 -522 -1432 482 -1817 -1476 -1405 -1109 -867 277 1229 1074 1600 287 -355 -571 -1128 -1194 -297 1268 1561 1075 776 -1435 -1458 -706 -1183 -1789 -1287 236 -1480 714 625 1280 726 -330 -813 -713 -540 123 -292 353 -394 1416 139 1699 749 484 989 212 650 760 1398 -342 -847 -181 -604 -212 283 -32 1181 675 598 -163 -1419 -2290 SU 20250705T051558.6Z 9317.219428 1588 1 29.98 2 76.34 70.39 140.13 315.92 0.00 1 0.00 1 0 17 1.529e-01 7.336e-03 2.781e-02 1.376e-03 5.573339e-01 7.150642e-04 6.844099e-03 -6.000000e+00 8.944509e-02 233.83 -2.00 3.84 -2.00 319.76 0.00e+00 2.220285e-03 1.898571e-04 3.255899e-04 -6.000000e+00 3.533296e-03 282.27 -2.00 20.00 -2.00 319.44 0.00e+00 4.132 0.001 302.00 328.00 3 1.8628e+00 2.0017e-03 5.2660e-02 -6.0000e+00 2.2721e-01 3.1443e-02 2.3435e-03 3.2198e-02 -6.0000e+00 2.4675e-01 -4.2926e-02 2.1509e-03 1.6215e-02 -6.0000e+00 1.4435e-01 1.3763e-02 1.1462e-03 4.7558e-03 -6.0000e+00 5.9221e-02 7.1685e-04 -2.1528e-05 3.8369e-05 4.7983e-05 -6.0000e+00 4.1825e-03 1.2805e-02 0.0000e+00 11 9 0 11 8 0 88.09 24.63 0.26 0.01280 0.01264 98 98 1 5 0 305.770 34.00 20.00 24.63 23.24 0.0 982.27 -56744 -42908 -58479 -49618 -68394 -62322 -42585 -39571 -50519 -46909 -35845 -27647 -28995 -10209 -10673 -2375 -12443 -7047 -6331 -4910 -7334 -6966 -2246 -1417 -8196 -10701 -7912 -5506 -8563 -8216 -5071 416 -1429 -495 -6486 -6629 -4296 796 -1633 -772 18 -374 487 -69 903 1276 166 519 61 1165 1070 2694 2649 1416 1158 1805 800 54 -308 467 699 1870 2780 3303 712 -642 -1129 -714 1526 1386 960 1141 911 495 -576 -1632 -2187 -2188 -1161 -1446 -1473 -1408 -1866 -1490 -1136 -479 584 957 914 1331 878 -104 -806 -308 -401 79 89 562 864 221 -851 -1518 -561 -272 -560 -1011 -724 -972 323 669 871 499 300 -118 -272 -295 -74 -267 332 160 147 93 382 425 666 157 -588 397 463 568 53 -716 -452 -210 204 -118 64 245 343 472 -163 -665 -532 -792 -576 -926 -679 -1065 -937 -600 -627 -976 -919 -678 -568 -763 -281 -355 -83 -533 -311 -297 -238 -372 -358 -117 -80 -537 -737 -522 -349 -568 -594 -422 39 -149 -52 -699 -734 -536 117 -270 -145 4 -82 110 -16 211 302 41 130 16 325 331 911 893 514 443 714 325 22 -122 185 293 863 1429 1690 380 -334 -573 -381 903 930 649 790 618 317 -366 -949 -1208 -1248 -742 -1010 -1187 -1179 -1695 -1344 -1088 -487 619 968 967 1345 833 -98 -738 -293 -401 84 103 723 1120 285 -1075 -1738 -643 -321 -673 -1296 -920 -1314 448 1024 1369 815 483 -182 -413 -432 -109 -415 521 261 238 146 604 651 980 221 -854 567 735 958 93 -1257 -829 -391 402 -234 130 504 703 938 -320 -1238 -1014 SU 20250705T051743.8Z 9317.220646 1590 1 29.95 2 76.08 70.71 140.32 316.47 0.00 1 0.00 1 0 17 1.334e-01 7.094e-03 4.617e-02 1.920e-03 5.505231e-01 9.992782e-04 6.756134e-03 -6.000000e+00 7.805158e-02 233.83 -2.00 3.84 -2.00 319.89 0.00e+00 2.246497e-03 2.742897e-04 3.299668e-04 -6.000000e+00 3.083377e-03 282.27 -2.00 20.00 -2.00 319.57 0.00e+00 4.062 0.001 302.00 328.00 3 2.5109e+00 2.8035e-03 5.1884e-02 -6.0000e+00 1.9827e-01 3.4133e-02 3.3195e-03 3.1870e-02 -6.0000e+00 2.1532e-01 -3.6791e-02 3.1486e-03 1.6122e-02 -6.0000e+00 1.2596e-01 1.0468e-02 1.6716e-03 4.7560e-03 -6.0000e+00 5.1676e-02 4.0181e-04 2.0151e-05 5.3846e-05 4.9131e-05 -6.0000e+00 3.6499e-03 1.3098e-02 0.0000e+00 11 8 0 10 0 0 80.94 24.63 0.29 0.01310 0.01325 74 74 1 5 0 404.600 34.00 20.00 24.63 23.20 0.0 982.28 -27808 -14075 -51018 -49683 -34400 -71785 -54795 -40162 -48653 -42684 -25039 -27219 -13375 -12743 93 -8539 -13357 -8656 -425 -8606 1722 -14344 231 39 -11545 -10305 -8704 -4142 -7837 -132 -4908 194 -209 -4565 -9120 -5233 -5977 -1740 -638 -1078 -1470 -407 -71 -735 975 -112 928 987 -1210 979 1281 1059 3014 2315 1145 2113 732 -190 -196 -974 1172 1965 2901 3905 1583 141 -939 -274 356 1428 685 982 -208 1180 -544 -1338 -1960 -2540 -1874 -981 -1125 -1392 -1770 -1597 -1010 -134 696 744 1061 825 686 336 -662 -480 -19 390 313 553 763 83 -1065 -1375 -163 -552 -427 -1244 -679 -1070 69 521 745 708 36 67 -168 -353 -109 59 424 199 73 -123 508 436 829 37 -754 682 330 625 42 -598 -509 -442 -12 -79 161 374 367 262 -127 -584 -401 -271 -132 -697 -633 -354 -1102 -810 -594 -856 -743 -394 -515 -278 -332 3 -293 -530 -357 -17 -398 73 -728 11 2 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