File name: Pandora289s1_DeBilt_20250722_L2Fit_fout2c1d20250508p1-8.txt File generation date: 20260519T141701.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora289_OF_v1d20240910.txt Instrument calibration file used: Pandora289s1_CF_v1d20250508.txt Level 1 file used: Pandora289s1_DeBilt_20250722_L1_smca1c1d20250508p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20250722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.1323 305.2727 305.4130 305.5534 305.6937 305.8340 305.9743 306.1146 306.2549 306.3952 306.5354 306.6757 306.8159 306.9561 307.0964 307.2366 307.3768 307.5169 307.6571 307.7973 307.9374 308.0776 308.2177 308.3578 308.4979 308.6380 308.7781 308.9182 309.0582 309.1983 309.3383 309.4783 309.6183 309.7583 309.8983 310.0383 310.1783 310.3182 310.4582 310.5981 310.7380 310.8780 311.0179 311.1577 311.2976 311.4375 311.5773 311.7172 311.8570 311.9968 312.1366 312.2764 312.4162 312.5560 312.6958 312.8355 312.9753 313.1150 313.2547 313.3944 313.5341 313.6738 313.8135 313.9531 314.0928 314.2324 314.3720 314.5116 314.6512 314.7908 314.9304 315.0700 315.2095 315.3491 315.4886 315.6281 315.7677 315.9072 316.0466 316.1861 316.3256 316.4650 316.6045 316.7439 316.8833 317.0227 317.1621 317.3015 317.4409 317.5803 317.7196 317.8589 317.9983 318.1376 318.2769 318.4162 318.5555 318.6947 318.8340 318.9732 319.1125 319.2517 319.3909 319.5301 319.6693 319.8085 319.9476 320.0868 320.2259 320.3650 320.5042 320.6433 320.7824 320.9214 321.0605 321.1996 321.3386 321.4777 321.6167 321.7557 321.8947 322.0337 322.1727 322.3116 322.4506 322.5895 322.7285 322.8674 323.0063 323.1452 323.2841 323.4229 323.5618 323.7006 323.8395 323.9783 324.1171 324.2559 324.3947 324.5335 324.6723 324.8110 324.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250722T060133.6Z 9334.251083 2104 1 30.42 2 71.81 80.22 44.27 102.98 0.00 1 0.00 1 0 17 2.285e-01 1.903e-02 1.687e-01 1.095e-02 4.645254e-01 5.693174e-03 5.755865e-03 -6.000000e+00 1.336311e-01 233.70 -2.00 3.84 -2.00 319.68 0.00e+00 6.958884e-03 1.421794e-03 2.458304e-04 -6.000000e+00 5.364140e-03 283.27 -2.00 20.00 -2.00 319.35 0.00e+00 3.161 0.001 302.00 328.00 3 6.0283e+00 1.5804e-02 4.1765e-02 -6.0000e+00 3.3933e-01 2.0534e-01 1.8246e-02 2.6735e-02 -6.0000e+00 3.6856e-01 -1.1972e-01 1.5119e-02 1.3368e-02 -6.0000e+00 2.1576e-01 4.7784e-02 8.0217e-03 3.8826e-03 -6.0000e+00 8.8933e-02 2.7855e-05 -3.1597e-04 3.1937e-04 4.1927e-05 -6.0000e+00 6.2916e-03 1.3470e-02 0.0000e+00 12 8 8 10 0 0 99.82 24.72 0.50 0.01347 0.01110 8 8 1 5 0 3802.110 34.00 19.99 24.72 23.59 0.0 983.17 -93911 -70125 900000 889 78536 145948 -16260 -68249 -70393 -24063 -83394 33833 -25303 -41269 -27379 4585 7184 -2509 1396 17546 49384 -1887 -12233 4644 24091 5310 3312 -34470 -4169 -9759 3030 30234 11203 -1582 -11633 -12399 20361 2102 -2168 2327 -1377 12580 595 7774 10439 2222 6817 -6894 449 -665 2739 3755 2907 2419 1910 4337 3058 -5416 -143 3564 6375 -465 5731 4216 2256 4383 1782 -1010 498 -5054 3221 -2502 338 2997 -3354 176 -140 -864 -8476 -6446 -1688 -2831 512 -1656 439 -1536 1392 985 1363 532 778 -1920 -3444 -902 64 662 2778 2586 -156 710 -1653 -2918 -1315 -1846 -553 -2715 -213 -1814 1283 961 1765 1255 1525 -613 -2036 -1732 -1100 -727 -376 1165 2196 -6 2177 1052 1044 672 -1293 -315 142 -6 265 -1194 -904 -222 79 1257 161 838 453 868 -1057 -1263 -956 -4467 -2859 900000 16 839 1558 -347 -2716 -3007 -719 -4720 686 -1162 -2776 -1900 259 430 -177 100 1105 2268 -143 -1045 352 1569 420 262 -3902 -352 -938 298 2615 1268 -203 -1578 -1708 2283 341 -433 500 -332 2781 153 1901 2530 593 1754 -2054 127 -200 866 1283 1071 935 765 1732 1241 -2354 -58 1400 2580 -223 2864 2287 1250 2246 893 -537 292 -3519 2215 -1860 238 1936 -2106 96 -71 -451 -5322 -4598 -1308 -2446 457 -1450 400 -1521 1408 1017 1380 520 704 -1796 -3089 -809 63 667 3095 3201 -210 933 -2041 -3292 -1397 -2038 -644 -3424 -274 -2493 1849 1516 2946 2152 2539 -979 -3076 -2499 -1589 -1098 -602 1915 3581 -10 3302 1557 1483 909 -1721 -428 211 -9 462 -2184 -1708 -402 152 2486 331 1722 930 1728 -2029 -2501 -1851 SU 20250722T060429.2Z 9334.253116 2110 1 30.21 2 71.37 80.78 43.85 103.64 0.00 1 0.00 1 0 17 7.115e-02 7.302e-03 1.598e-02 1.483e-03 4.695717e-01 7.647002e-04 5.881943e-03 -6.000000e+00 4.161131e-02 233.70 -2.00 3.84 -2.00 319.00 0.00e+00 1.665019e-03 1.609550e-04 2.044113e-04 -6.000000e+00 1.644289e-03 283.27 -2.00 20.00 -2.00 318.68 0.00e+00 3.090 0.001 302.00 328.00 3 3.1185e+00 2.0973e-03 4.1399e-02 -6.0000e+00 1.0567e-01 5.8776e-03 2.3770e-03 2.6901e-02 -6.0000e+00 1.1476e-01 -1.8935e-02 1.8342e-03 1.3319e-02 -6.0000e+00 6.7141e-02 5.6568e-03 9.8364e-04 3.7986e-03 -6.0000e+00 2.7559e-02 6.0413e-04 3.0856e-05 4.1990e-05 3.8258e-05 -6.0000e+00 1.9462e-03 1.1634e-02 0.0000e+00 11 8 0 10 0 0 99.98 24.73 0.27 0.01163 0.01187 58 58 1 5 0 520.680 34.00 20.00 24.73 23.48 0.0 982.60 -20992 -23819 -19825 -11651 -36873 -36737 -21564 -24297 -17647 -17272 -17885 -15448 -5195 -8361 -4318 -5072 -3926 2309 -1187 754 -163 -1336 -2044 -1479 970 -3711 -2239 -5078 -5138 -3665 -1741 370 2533 -2194 -4644 -4817 -2612 -1364 -522 -109 -932 -867 531 142 510 930 764 -193 540 -307 1481 2132 1801 1497 837 1900 1013 53 -335 806 747 2271 2557 2466 856 -155 -1114 -335 1432 1240 623 521 388 119 -311 -828 -1966 -2299 -1487 -1073 -1302 -1388 -1911 -1783 -813 -635 534 454 934 831 879 10 -649 -351 -56 -42 226 665 379 230 -902 -1533 -511 -299 -483 -905 -608 -1100 134 570 1020 681 310 88 -334 -177 154 -82 157 52 272 -65 344 615 791 325 -468 549 543 435 149 -576 -348 -199 125 -96 -86 258 443 187 -151 -824 -526 -534 -679 -542 -275 -1045 -1057 -605 -808 -597 -605 -665 -641 -239 -489 -285 -379 -315 187 -106 69 -15 -128 -207 -162 112 -456 -266 -602 -606 -454 -245 59 428 -390 -818 -867 -480 -304 -139 -33 -310 -279 173 47 172 315 261 -67 192 -117 605 952 870 706 415 966 527 27 -171 408 400 1324 1532 1583 561 -97 -676 -210 992 907 495 424 311 90 -232 -559 -1255 -1495 -1068 -831 -1156 -1280 -1902 -1769 -852 -670 587 508 1025 926 912 10 -633 -351 -58 -47 268 873 502 301 -1156 -1888 -598 -362 -596 -1190 -794 -1520 188 875 1590 1092 487 137 -487 -260 227 -122 247 81 427 -100 529 910 1122 463 -648 777 805 681 250 -963 -603 -349 233 -181 -165 500 856 354 -283 -1468 -919 SU 20250722T060600.7Z 9334.254175 2112 1 30.02 2 71.14 81.06 43.63 103.98 0.00 1 0.00 1 0 25 7.757e-02 7.757e-03 3.388e-02 2.641e-03 4.631872e-01 1.360502e-03 5.778972e-03 -6.000000e+00 4.536906e-02 233.70 -2.00 3.84 -2.00 319.29 0.00e+00 2.040492e-03 3.122075e-04 2.213285e-04 -6.000000e+00 1.792732e-03 283.27 -2.00 20.00 -2.00 318.96 0.00e+00 3.055 0.001 302.00 328.00 3 4.1104e+00 3.7482e-03 4.0910e-02 -6.0000e+00 1.1521e-01 2.8806e-02 4.2855e-03 2.6607e-02 -6.0000e+00 1.2512e-01 -2.0665e-02 3.5061e-03 1.3271e-02 -6.0000e+00 7.3203e-02 4.3864e-03 1.8815e-03 3.8267e-03 -6.0000e+00 3.0048e-02 2.3030e-04 1.1219e-04 7.5580e-05 3.7991e-05 -6.0000e+00 2.1219e-03 1.1390e-02 0.0000e+00 11 8 0 10 0 0 99.91 24.73 0.21 0.01139 0.01223 39 39 1 5 0 769.460 34.00 20.00 24.73 23.43 0.0 982.55 -35348 3837 -35090 -19749 -31294 -14102 -38764 -21083 -20277 -6648 -19158 -20782 -12737 -2538 -15439 -8226 -2055 -5046 -2895 695 2851 1770 4069 2208 -3266 -4473 -4589 503 -5865 -8808 362 -1792 785 -1325 -492 -9797 546 -1606 -1396 146 -634 -569 782 843 64 876 983 -514 676 819 2072 1597 466 1136 1733 785 1338 -64 -962 283 726 2156 3090 2829 495 -620 -508 -1145 2114 1401 422 674 7 817 61 -570 -1264 -2713 -1758 -1626 -1322 -1522 -2282 -1909 -883 -515 678 378 905 1175 948 -187 -382 -475 -320 133 435 708 835 194 -860 -1659 -590 -536 -343 -874 -578 -874 6 879 838 813 133 319 -334 -369 -399 -233 439 -160 244 -209 344 533 564 287 -555 524 536 593 135 -696 -210 -113 77 -188 -20 243 678 374 -250 -903 -538 -892 71 -958 -432 -717 -276 -1098 -576 -595 -176 -607 -765 -531 -118 -958 -532 -135 -368 -219 53 216 137 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