File name: Pandora289s1_DeBilt_20250723_L2Fit_fout2c1d20250508p1-8.txt File generation date: 20260519T141618.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora289_OF_v1d20240910.txt Instrument calibration file used: Pandora289s1_CF_v1d20250508.txt Level 1 file used: Pandora289s1_DeBilt_20250723_L1_smca1c1d20250508p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20250723 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.1323 305.2727 305.4130 305.5534 305.6937 305.8340 305.9743 306.1146 306.2549 306.3952 306.5354 306.6757 306.8159 306.9561 307.0964 307.2366 307.3768 307.5169 307.6571 307.7973 307.9374 308.0776 308.2177 308.3578 308.4979 308.6380 308.7781 308.9182 309.0582 309.1983 309.3383 309.4783 309.6183 309.7583 309.8983 310.0383 310.1783 310.3182 310.4582 310.5981 310.7380 310.8780 311.0179 311.1577 311.2976 311.4375 311.5773 311.7172 311.8570 311.9968 312.1366 312.2764 312.4162 312.5560 312.6958 312.8355 312.9753 313.1150 313.2547 313.3944 313.5341 313.6738 313.8135 313.9531 314.0928 314.2324 314.3720 314.5116 314.6512 314.7908 314.9304 315.0700 315.2095 315.3491 315.4886 315.6281 315.7677 315.9072 316.0466 316.1861 316.3256 316.4650 316.6045 316.7439 316.8833 317.0227 317.1621 317.3015 317.4409 317.5803 317.7196 317.8589 317.9983 318.1376 318.2769 318.4162 318.5555 318.6947 318.8340 318.9732 319.1125 319.2517 319.3909 319.5301 319.6693 319.8085 319.9476 320.0868 320.2259 320.3650 320.5042 320.6433 320.7824 320.9214 321.0605 321.1996 321.3386 321.4777 321.6167 321.7557 321.8947 322.0337 322.1727 322.3116 322.4506 322.5895 322.7285 322.8674 323.0063 323.1452 323.2841 323.4229 323.5618 323.7006 323.8395 323.9783 324.1171 324.2559 324.3947 324.5335 324.6723 324.8110 324.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250723T082727.6Z 9335.352402 4390 1 30.73 2 49.92 110.72 33.69 125.88 0.00 1 0.00 1 0 17 1.624e-02 9.983e-03 7.062e-03 3.139e-03 2.377503e-01 1.620950e-03 3.052593e-03 -6.000000e+00 9.501221e-03 233.64 -2.00 3.84 -2.00 316.52 0.00e+00 5.068150e-04 1.740236e-04 4.531524e-05 -6.000000e+00 3.754263e-04 283.27 -2.00 20.00 -2.00 316.18 0.00e+00 1.550 0.000 302.00 328.00 3 6.2235e+00 4.2842e-03 2.0792e-02 -6.0000e+00 2.4124e-02 5.7307e-02 4.7637e-03 1.3490e-02 -6.0000e+00 2.6199e-02 -4.6189e-03 2.7825e-03 6.5602e-03 -6.0000e+00 1.5328e-02 -9.1532e-04 1.2931e-03 1.8072e-03 -6.0000e+00 6.2943e-03 1.6413e-04 5.7908e-04 9.0157e-05 2.0237e-05 -6.0000e+00 4.4429e-04 9.5362e-03 0.0000e+00 12 8 8 10 0 0 99.99 24.87 0.44 0.00954 0.01389 9 9 1 5 0 3412.590 34.00 19.99 24.87 23.05 0.0 982.65 -174 69 -4395 -2246 -4128 -4672 -1965 1079 -3008 -4250 -5755 -4025 -406 219 3534 298 21 2423 289 1851 2849 846 1243 882 1153 2294 -2345 -2218 1074 -569 2105 1210 2654 -962 -5710 -1759 -2312 -795 95 439 88 -777 -349 408 -29 -447 -316 -902 -786 237 449 612 645 589 716 552 945 131 -335 -194 1435 2225 2732 944 885 -584 -1946 -1903 1103 1192 754 968 -38 1300 -157 -970 -2371 -2845 -1722 -2094 -1003 -2160 -2002 -1992 -747 211 859 612 1398 1416 615 -758 -1271 224 -10 -298 574 1496 982 335 -1124 -1899 -971 -828 -958 -1172 -399 -706 209 1161 1313 1246 659 154 -710 -559 34 -758 19 106 1062 333 248 129 904 401 -1041 159 226 788 -203 -832 -697 76 399 -216 199 443 462 109 -220 -591 -918 -31 13 -805 -366 -624 -705 -321 194 -600 -860 -1179 -861 -95 59 1015 85 6 722 91 591 906 273 409 310 426 841 -863 -767 375 -202 780 450 1015 -373 -2204 -658 -985 -402 56 265 57 -525 -238 277 -20 -302 -208 -578 -495 151 302 439 487 459 572 451 774 107 -270 -157 1194 1832 2408 876 796 -488 -1645 -1618 928 1119 762 1000 -39 1260 -142 -860 -1934 -2273 -1457 -1850 -978 -2310 -2100 -2201 -869 260 1036 753 1802 1747 706 -794 -1327 229 -11 -335 707 1852 1277 429 -1439 -2249 -1115 -996 -1241 -1503 -528 -974 301 1650 1937 1838 995 216 -920 -735 45 -984 27 155 1571 488 350 176 1163 525 -1319 200 303 1055 -286 -1195 -1021 116 597 -342 322 726 758 177 -343 -886 -1365 SU 20250723T082921.0Z 9335.353715 4392 1 31.36 2 49.65 111.18 33.47 126.50 0.00 1 0.00 1 0 17 2.387e-02 1.269e-02 1.172e-02 4.668e-03 2.421999e-01 2.410279e-03 3.119631e-03 -6.000000e+00 1.396172e-02 233.64 -2.00 3.84 -2.00 316.81 0.00e+00 4.355193e-04 2.737775e-04 4.768879e-05 -6.000000e+00 5.516715e-04 283.27 -2.00 20.00 -2.00 316.47 0.00e+00 1.541 0.000 302.00 328.00 3 6.8020e+00 6.3890e-03 2.0933e-02 -6.0000e+00 3.5449e-02 7.6563e-02 7.1189e-03 1.3770e-02 -6.0000e+00 3.8498e-02 -4.2103e-03 4.1803e-03 6.7023e-03 -6.0000e+00 2.2524e-02 2.7525e-05 1.9669e-03 1.8506e-03 -6.0000e+00 9.2494e-03 9.1081e-05 2.2889e-04 1.3463e-04 2.0565e-05 -6.0000e+00 6.5287e-04 9.4626e-03 0.0000e+00 12 8 8 10 0 0 99.37 24.87 0.26 0.00946 0.01118 9 9 1 5 0 3482.920 34.00 20.00 24.87 23.08 0.0 982.80 1752 5156 902 -9476 296 -7661 569 -6418 4161 -6833 -8144 -3381 -3293 -1202 2713 -557 306 2436 477 4586 -3854 2429 857 1984 3077 -129 -3708 -1047 4750 -1934 6 7022 398 -3002 -3798 -4455 -3499 -310 1363 -42 -294 -336 1933 -1868 412 -403 -943 642 -2151 536 -1341 1430 969 1375 2328 1450 1170 -177 187 -938 1112 1080 3077 2774 1054 -1054 -2900 -328 602 1160 603 1359 1352 526 -226 -1171 -2815 -4562 -2740 -2297 -1737 -1736 -2582 -1903 -745 -207 818 912 1492 367 1668 -1115 -1910 -1568 -1094 173 636 1484 1593 414 -945 -1622 -682 -1281 -989 -919 -697 -164 1648 1534 1777 1462 550 -216 -769 -1000 -1706 -621 135 89 725 399 609 621 1017 -312 -1518 -828 292 709 417 -1010 -461 32 296 -382 346 -194 918 709 27 -840 -1174 260 770 135 -1436 37 -1029 78 -1075 669 -1229 -1479 -622 -688 -283 680 -153 86 693 143 1361 -1251 736 270 658 1066 -46 -1323 -342 1390 -603 2 2353 149 -1138 -1378 -1637 -1438 -149 689 -24 -181 -214 1222 -1230 265 -258 -591 384 -1303 322 -869 965 692 1009 1735 1114 908 -137 142 -724 879 922 2770 2378 973 -910 -2348 -260 521 1023 574 1316 1290 484 -210 -985 -2184 -3506 -2212 -2079 -1600 -1735 -2753 -2122 -875 -259 985 1116 1940 462 1915 -1184 -1880 -1525 -1129 195 787 1983 2053 528 -1219 -1931 -785 -1554 -1285 -1167 -919 -224 2323 2298 2764 2280 826 -302 -992 -1327 -2283 -864 184 129 1063 577 848 831 1400 -411 -1928 -1051 391 1014 576 -1433 -663 47 466 -634 587 -311 1573 1197 44 -1323 -1828 SU 20250723T083108.8Z 9335.354963 4394 1 30.95 2 49.39 111.62 33.26 127.08 0.00 1 0.00 1 0 17 1.445e-02 8.858e-03 4.926e-03 2.379e-03 2.344702e-01 1.231072e-03 3.026881e-03 -6.000000e+00 8.451241e-03 233.64 -2.00 3.84 -2.00 316.27 0.00e+00 7.486527e-04 1.239285e-04 3.920487e-05 -6.000000e+00 3.339076e-04 283.27 -2.00 20.00 -2.00 315.93 0.00e+00 1.533 0.000 302.00 328.00 3 5.8018e+00 3.2414e-03 2.0545e-02 -6.0000e+00 2.1458e-02 5.4359e-02 3.6070e-03 1.3312e-02 -6.0000e+00 2.3303e-02 -3.0828e-03 2.0836e-03 6.4655e-03 -6.0000e+00 1.3634e-02 -3.0698e-03 9.5225e-04 1.7749e-03 -6.0000e+00 5.5992e-03 2.5589e-04 2.7828e-04 6.8080e-05 2.0143e-05 -6.0000e+00 3.9514e-04 8.7838e-03 0.0000e+00 11 9 0 11 8 0 99.95 24.88 0.40 0.00878 0.01087 13 13 1 5 0 2380.470 34.00 20.01 24.88 23.15 0.0 983.19 1631 2369 36 -4115 -6078 -2959 1317 1726 1717 -3157 -2720 -4774 -1811 -195 1575 1174 1568 60 1357 943 1867 -1691 252 817 1347 1224 34 -760 -700 -679 2746 2173 547 -2141 -3637 -4471 -2766 -485 586 -428 -247 -960 -111 -392 55 -342 -659 -283 -1361 -25 320 1349 1746 677 980 759 -374 -115 229 34 1687 1730 2221 1690 1023 -511 -1162 -1242 708 987 310 621 375 814 759 -336 -2082 -2618 -1567 -1134 -1321 -1403 -2298 -1217 -589 -259 432 611 955 630 776 -580 -813 -587 -410 123 298 1132 742 88 -942 -1875 111 -628 -1055 -980 -405 -906 346 567 1374 1151 399 95 -313 -95 -520 -342 194 244 460 244 329 559 659 38 -710 410 392 574 35 -972 -572 -83 465 233 87 540 41 461 -321 -1020 -665 315 473 7 -769 -1055 -492 233 345 365 -706 -603 -1147 -481 -53 468 371 510 20 473 340 670 -625 93 320 553 505 14 -289 -253 -244 1024 891 238 -937 -1534 -1912 -1313 -248 350 -267 -164 -667 -77 -275 38 -237 -447 -185 -885 -16 220 984 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