File name: Pandora289s1_DeBilt_20250911_L2Fit_fout2c2d20250401p1-8.txt File generation date: 20250911T233758.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora289_OF_v3d20240910.txt Instrument calibration file used: Pandora289s1_CF_v2d20250401.txt Level 1 file used: Pandora289s1_DeBilt_20250911_L1_smca1c2d20250401p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20250911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 341 Nominal wavelengths inside fitting window [nm]: 305.0110 305.1514 305.2918 305.4321 305.5725 305.7128 305.8531 305.9934 306.1337 306.2740 306.4143 306.5545 306.6948 306.8350 306.9752 307.1155 307.2557 307.3959 307.5360 307.6762 307.8164 307.9565 308.0967 308.2368 308.3769 308.5170 308.6571 308.7972 308.9372 309.0773 309.2173 309.3574 309.4974 309.6374 309.7774 309.9174 310.0574 310.1973 310.3373 310.4772 310.6171 310.7571 310.8970 311.0369 311.1767 311.3166 311.4565 311.5963 311.7362 311.8760 312.0158 312.1556 312.2954 312.4352 312.5749 312.7147 312.8544 312.9942 313.1339 313.2736 313.4133 313.5530 313.6927 313.8323 313.9720 314.1116 314.2513 314.3909 314.5305 314.6701 314.8097 314.9492 315.0888 315.2284 315.3679 315.5074 315.6469 315.7864 315.9259 316.0654 316.2049 316.3443 316.4838 316.6232 316.7626 316.9020 317.0414 317.1808 317.3202 317.4596 317.5989 317.7383 317.8776 318.0169 318.1562 318.2955 318.4348 318.5741 318.7133 318.8526 318.9918 319.1310 319.2702 319.4094 319.5486 319.6878 319.8270 319.9661 320.1053 320.2444 320.3835 320.5226 320.6617 320.8008 320.9399 321.0789 321.2180 321.3570 321.4960 321.6351 321.7741 321.9131 322.0520 322.1910 322.3300 322.4689 322.6078 322.7467 322.8857 323.0246 323.1634 323.3023 323.4412 323.5800 323.7189 323.8577 323.9965 324.1353 324.2741 324.4129 324.5516 324.6904 324.8291 324.9679 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250911T065222.2Z 9385.286368 848 1 14.21 2 74.85 102.58 62.50 261.94 0.00 1 0.00 1 0 17 4.753e-02 7.071e-03 1.735e-02 2.027e-03 4.451099e-01 1.041469e-03 5.679567e-03 -6.000000e+00 2.781200e-02 229.27 -2.00 3.84 -2.00 318.59 0.00e+00 6.390983e-04 2.190582e-04 3.965522e-04 -6.000000e+00 1.219628e-03 280.71 -2.00 20.00 -2.00 317.89 0.00e+00 3.752 0.001 302.00 328.00 3 2.4337e+00 2.8427e-03 4.5102e-02 -6.0000e+00 6.9359e-02 3.8991e-02 3.2447e-03 2.5290e-02 -6.0000e+00 7.5239e-02 -2.5982e-02 2.2471e-03 1.2379e-02 -6.0000e+00 4.4752e-02 6.1864e-03 1.1739e-03 3.4727e-03 -6.0000e+00 1.8658e-02 6.7059e-04 -4.5903e-04 5.8528e-05 3.7994e-05 -6.0000e+00 1.3561e-03 -5.0719e-03 0.0000e+00 12 9 1 12 1 1 99.39 24.76 0.27 -0.00507 -0.00852 25 10 1 5 0 546.470 34.00 20.00 24.76 20.04 0.0 968.50 -23629 -19761 -14109 -1334 290 -4947 -21122 3008 -24404 -14481 3631 -15439 -6361 -3696 3871 -1108 -6537 -4721 -932 -888 4713 -5209 -1816 -843 1425 -2100 -5640 -1378 -282 -3948 4375 1436 4584 1589 -2586 -3862 -3107 -536 -1475 -87 1185 -1901 -536 -60 -1740 14 -313 571 326 -192 995 1214 2484 1308 517 992 1632 1127 1027 -199 419 1833 2914 2565 1756 1029 -561 -204 -344 1230 333 -329 -412 291 -152 -119 -1121 -909 -1755 -883 -726 -1494 -1610 -2396 -1200 -877 -305 384 -83 727 850 889 364 444 47 311 -2 6 459 40 -603 -1012 -1149 -516 5 -378 -1332 -536 -804 289 536 373 387 383 655 302 324 547 113 306 -43 -120 -64 339 691 410 -70 -431 775 519 192 189 -661 -200 -67 290 -330 -87 241 343 -233 -219 -414 -307 -794 -750 -547 -45 9 -155 -794 100 -1221 -716 157 -852 -364 -248 291 -102 -708 -494 -100 -101 528 -656 -225 -109 195 -320 -910 -209 -41 -588 635 244 860 332 -567 -835 -685 -132 -407 -28 403 -729 -214 -25 -732 6 -132 239 138 -84 421 559 1236 662 278 556 940 662 598 -115 242 1101 1784 1738 1203 712 -375 -139 -243 900 261 -280 -341 248 -123 -93 -806 -648 -1203 -664 -593 -1327 -1506 -2427 -1214 -943 -333 438 -96 829 928 948 359 438 48 330 -3 7 598 54 -795 -1290 -1394 -599 6 -466 -1760 -707 -1125 415 806 578 613 592 989 445 458 776 164 469 -66 -186 -97 512 1004 597 -98 -607 1069 756 297 302 -1104 -334 -119 522 -608 -164 459 652 -435 -401 -722 -545 SU 20250911T065325.1Z 9385.287096 850 1 54.51 2 74.69 102.79 62.65 262.16 0.00 1 0.00 1 0 17 4.172e-02 6.467e-03 3.231e-03 4.621e-04 4.387752e-01 2.372326e-04 5.609977e-03 -6.000000e+00 2.441304e-02 229.27 -2.00 3.84 -2.00 318.40 0.00e+00 8.463383e-04 4.651018e-05 3.106562e-04 -6.000000e+00 1.070547e-03 280.71 -2.00 20.00 -2.00 317.69 0.00e+00 3.716 0.001 302.00 328.00 3 9.5432e-01 6.4365e-04 4.4579e-02 -6.0000e+00 6.0883e-02 1.5298e-02 7.3145e-04 2.4877e-02 -6.0000e+00 6.6043e-02 -2.0025e-02 4.9015e-04 1.2170e-02 -6.0000e+00 3.9282e-02 4.8946e-03 2.5370e-04 3.4529e-03 -6.0000e+00 1.6378e-02 3.1094e-03 -3.1874e-04 1.3357e-05 3.8146e-05 -6.0000e+00 1.1903e-03 -5.3124e-03 0.0000e+00 11 8 0 10 0 0 93.18 24.76 0.28 -0.00531 -0.00771 517 52 1 5 0 105.420 34.00 20.00 24.76 20.03 0.0 968.58 -15794 -15461 -12990 -11724 -13085 -17481 -15653 -9320 -13735 -9033 -9938 -13402 -8547 -5599 -2139 -1652 -2080 -1548 1339 254 1289 -1019 -50 -241 -61 205 -1804 -2213 -2021 -2027 587 1939 1592 1167 -2533 -2760 -2936 -1698 -248 -54 -212 -462 -353 347 -228 731 389 403 240 -116 607 1336 1462 1032 1092 836 1179 833 312 160 773 1479 2120 1979 1753 586 -193 -367 85 1330 626 94 142 32 19 -485 -823 -959 -1370 -875 -1001 -1611 -1700 -2200 -1771 -854 -634 197 52 625 704 775 187 -113 359 341 337 146 406 108 -368 -848 -1034 -374 3 -572 -1203 -585 -737 326 561 582 312 359 200 241 312 607 192 291 -100 -167 -162 446 490 627 255 -117 700 511 281 -114 -598 -197 58 13 -114 -64 202 158 -69 -199 -478 -378 -592 -677 -600 -533 -566 -745 -670 -421 -742 -508 -589 -869 -599 -459 -205 -167 -235 -188 169 34 179 -147 -7 -37 -10 36 -334 -404 -356 -355 106 392 337 268 -607 -646 -708 -462 -75 -18 -81 -193 -145 146 -98 314 169 175 105 -52 288 642 768 552 616 494 718 516 192 98 470 889 1393 1360 1286 436 -138 -252 60 987 501 77 120 27 16 -389 -600 -690 -1003 -669 -841 -1481 -1655 -2216 -1812 -923 -702 220 59 697 781 833 195 -111 362 363 390 177 524 144 -482 -1068 -1234 -443 3 -728 -1578 -774 -997 457 829 889 489 548 298 345 443 867 280 438 -153 -258 -251 663 725 919 357 -165 975 756 431 -182 -995 -329 100 24 -206 -119 380 297 -127 -358 -842 -656 SU 20250911T065509.1Z 9385.288299 852 1 54.52 2 74.43 103.15 62.90 262.51 0.00 1 0.00 1 0 17 3.942e-02 6.437e-03 2.901e-03 4.367e-04 4.326839e-01 2.243582e-04 5.535108e-03 -6.000000e+00 2.306985e-02 229.27 -2.00 3.84 -2.00 318.34 0.00e+00 9.251418e-04 4.344184e-05 2.761038e-04 -6.000000e+00 1.011641e-03 280.71 -2.00 20.00 -2.00 317.63 0.00e+00 3.658 0.001 302.00 328.00 3 9.0341e-01 6.0701e-04 4.3901e-02 -6.0000e+00 5.7533e-02 1.5499e-02 6.8893e-04 2.4515e-02 -6.0000e+00 6.2409e-02 -1.9950e-02 4.5757e-04 1.1997e-02 -6.0000e+00 3.7121e-02 4.7845e-03 2.3642e-04 3.4248e-03 -6.0000e+00 1.5477e-02 3.4806e-03 -3.0491e-04 1.2619e-05 3.7339e-05 -6.0000e+00 1.1248e-03 -5.3549e-03 0.0000e+00 11 8 0 10 0 0 48.79 24.76 0.27 -0.00535 -0.00765 590 60 1 5 0 92.390 34.00 20.00 24.76 20.04 0.0 968.96 -16136 -14737 -12075 -9720 -12193 -15402 -14121 -11814 -11986 -10404 -8504 -12193 -8183 -5648 -1514 -1115 -1776 -1594 255 735 1439 -842 680 382 955 46 -1195 -1727 -2015 -1777 599 1641 1759 1261 -2257 -3165 -2350 -1386 -123 -300 -518 -417 -374 72 -161 694 202 380 88 128 630 1300 1610 1109 833 809 1085 840 387 300 702 1394 2221 2002 1736 454 -430 -328 -45 1341 610 67 214 -25 31 -427 -842 -922 -1207 -947 -1014 -1676 -1792 -2143 -1697 -810 -524 186 42 593 702 687 314 -62 380 424 240 108 493 231 -317 -849 -1022 -261 -59 -618 -1173 -700 -681 348 566 531 363 333 164 188 259 516 241 266 -100 -168 -160 475 535 612 248 -156 694 548 225 -137 -556 -230 45 93 -144 -61 193 211 -62 -216 -490 -396 -648 -684 -589 -461 -557 -684 -633 -581 -675 -628 -525 -825 -602 -488 -151 -118 -210 -203 34 103 209 -127 103 61 164 8 -229 -326 -369 -322 112 316 385 299 -557 -768 -581 -388 -38 -104 -204 -168 -158 31 -71 306 90 170 40 59 306 639 863 604 481 487 674 501 230 186 435 855 1483 1399 1230 326 -311 -228 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