File name: Pandora289s1_DeBilt_20250915_L2Fit_fout2c2d20250401p1-8.txt File generation date: 20250915T234026.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora289_OF_v3d20240910.txt Instrument calibration file used: Pandora289s1_CF_v2d20250401.txt Level 1 file used: Pandora289s1_DeBilt_20250915_L1_smca1c2d20250401p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20250915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 341 Nominal wavelengths inside fitting window [nm]: 305.0110 305.1514 305.2918 305.4321 305.5725 305.7128 305.8531 305.9934 306.1337 306.2740 306.4143 306.5545 306.6948 306.8350 306.9752 307.1155 307.2557 307.3959 307.5360 307.6762 307.8164 307.9565 308.0967 308.2368 308.3769 308.5170 308.6571 308.7972 308.9372 309.0773 309.2173 309.3574 309.4974 309.6374 309.7774 309.9174 310.0574 310.1973 310.3373 310.4772 310.6171 310.7571 310.8970 311.0369 311.1767 311.3166 311.4565 311.5963 311.7362 311.8760 312.0158 312.1556 312.2954 312.4352 312.5749 312.7147 312.8544 312.9942 313.1339 313.2736 313.4133 313.5530 313.6927 313.8323 313.9720 314.1116 314.2513 314.3909 314.5305 314.6701 314.8097 314.9492 315.0888 315.2284 315.3679 315.5074 315.6469 315.7864 315.9259 316.0654 316.2049 316.3443 316.4838 316.6232 316.7626 316.9020 317.0414 317.1808 317.3202 317.4596 317.5989 317.7383 317.8776 318.0169 318.1562 318.2955 318.4348 318.5741 318.7133 318.8526 318.9918 319.1310 319.2702 319.4094 319.5486 319.6878 319.8270 319.9661 320.1053 320.2444 320.3835 320.5226 320.6617 320.8008 320.9399 321.0789 321.2180 321.3570 321.4960 321.6351 321.7741 321.9131 322.0520 322.1910 322.3300 322.4689 322.6078 322.7467 322.8857 323.0246 323.1634 323.3023 323.4412 323.5800 323.7189 323.8577 323.9965 324.1353 324.2741 324.4129 324.5516 324.6904 324.8291 324.9679 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250915T062249.4Z 9389.265849 548 1 1.96 2 80.31 97.80 24.03 183.31 0.00 1 0.00 1 0 17 4.994e-01 2.181e-02 3.453e-01 1.717e-02 6.248433e-01 9.350787e-03 8.012772e-03 -6.000000e+00 2.959449e-01 228.78 -2.00 3.84 -2.00 320.48 0.00e+00 -1.620149e-03 3.667722e-03 3.721095e-03 -6.000000e+00 1.522999e-02 280.31 -2.00 20.00 -2.00 319.89 0.00e+00 5.668 0.004 302.00 328.00 3 1.9613e+00 2.8507e-02 6.9066e-02 -6.0000e+00 7.3975e-01 5.4315e-02 3.6479e-02 4.3486e-02 -6.0000e+00 8.0501e-01 -7.2643e-02 3.4662e-02 1.9355e-02 -6.0000e+00 4.7722e-01 3.0189e-02 1.7183e-02 5.3893e-03 -6.0000e+00 2.0278e-01 1.4871e-04 3.3368e-04 4.9766e-04 7.1105e-05 -6.0000e+00 1.5012e-02 -4.9794e-03 0.0000e+00 12 9 9 12 1 1 999.00 24.74 0.52 -0.00498 -0.00247 1 6 1 5 0 979.280 34.00 20.00 24.74 19.39 0.0 965.37 -94064 900000 900000 900000 900000 -223059 -66936 900000 -161113 4150 900000 900000 149270 900000 900000 -75805 -56186 900000 177366 -86486 258447 -27941 103839 -95591 -32944 -86737 40843 25353 86391 117181 50151 144792 -3040 24500 -30471 -9979 66574 48992 -28103 15287 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1535 -267 -1913 -484 294 1765 -2616 1779 -2138 1338 2735 -440 -2569 343 338 -3078 -23 -1719 1759 -3293 -2432 -2974 860 1728 -1419 -842 957 1254 -1346 -777 1458 2269 3456 -208 -25 2276 1705 2631 1176 -269 -729 -1716 -119 1174 2003 1534 -1447 -789 -3911 -29 55 1156 -150 -1171 -30 2118 -2125 SU 20250915T062339.6Z 9389.266430 550 1 54.37 2 80.18 97.97 24.04 183.75 0.00 1 0.00 1 0 17 2.666e-01 7.484e-03 1.103e-01 1.435e-03 6.224997e-01 7.525915e-04 7.760548e-03 -6.000000e+00 1.557088e-01 228.78 -2.00 3.84 -2.00 320.24 0.00e+00 1.787184e-03 2.728980e-04 1.521192e-03 -6.000000e+00 6.829888e-03 280.31 -2.00 20.00 -2.00 319.64 0.00e+00 5.602 0.004 302.00 328.00 3 1.0941e+00 2.2454e-03 6.6345e-02 -6.0000e+00 3.8791e-01 6.5298e-02 2.8163e-03 3.6607e-02 -6.0000e+00 4.2099e-01 -6.0713e-02 2.6607e-03 1.8730e-02 -6.0000e+00 2.5044e-01 1.7533e-02 1.3433e-03 5.6818e-03 -6.0000e+00 1.0447e-01 3.7197e-04 -4.6896e-04 3.9700e-05 7.0268e-05 -6.0000e+00 7.6057e-03 -4.4501e-03 0.0000e+00 11 8 0 10 0 0 99.92 24.73 0.33 -0.00445 -0.00797 158 16 1 5 0 344.080 34.00 19.99 24.73 19.38 0.0 965.38 -136230 -133742 -64215 -25162 114578 -66779 -87670 47885 -116737 -58190 35966 -31015 -19818 -19853 3192 -37738 -36500 -25642 -7258 -20046 -2525 -30132 -15979 -18739 -14352 -17284 -25132 -55 -8106 -32810 11554 7153 8553 2035 -15686 -6217 586 -4668 -5899 -3370 1700 -2947 -1386 60 -6028 2275 -665 3065 312 -2183 303 2596 5559 3515 1104 2369 1426 2393 1041 -1683 413 3130 4846 4069 3442 1652 130 -544 517 2257 1364 -5 620 89 -480 -386 -1987 -1466 -2355 -1229 -569 -1182 -1091 -2124 -1670 -550 -21 283 -159 826 551 1175 20 185 22 -155 125 -16 397 426 -485 -1037 -909 -889 40 -509 -1208 -792 -854 252 674 568 295 401 356 31 48 391 101 509 76 26 15 453 568 593 -5 -492 274 170 236 -184 -789 -362 -95 -12 -152 13 335 338 -54 -20 -297 -173 -1439 -1853 -494 -134 160 -495 -834 134 -1961 -603 156 -291 -200 -256 42 -903 -1001 -707 -183 -617 -69 -1105 -523 -677 -548 -738 -1199 -2 -322 -1722 435 337 472 133 -1254 -445 41 -395 -623 -421 234 -429 -213 9 -1032 366 -113 515 56 -426 63 588 1366 966 334 748 475 805 352 -573 138 1083 1691 1616 1505 756 59 -247 247 1109 766 -3 389 55 -279 -204 -1056 -742 -1259 -684 -371 -835 -865 -1726 -1442 -501 -19 268 -154 781 502 1064 17 155 20 -145 128 -19 489 532 -639 -1266 -1059 -983 45 -616 -1480 -1019 -1116 359 1014 887 483 651 554 48 72 594 155 819 126 42 24 692 885 893 -7 -702 408 271 403 -328 -1494 -690 -192 -24 -317 28 722 726 -112 -40 -597 -342 SU 20250915T062524.8Z 9389.267648 552 1 54.45 2 79.92 98.32 24.06 184.67 0.00 1 0.00 1 0 17 3.029e-01 7.692e-03 1.146e-01 1.439e-03 6.084801e-01 7.530619e-04 7.572627e-03 -6.000000e+00 1.769284e-01 228.78 -2.00 3.84 -2.00 320.21 0.00e+00 1.738227e-03 2.703667e-04 1.498364e-03 -6.000000e+00 7.760584e-03 280.31 -2.00 20.00 -2.00 319.60 0.00e+00 5.468 0.004 302.00 328.00 3 1.2250e+00 2.2421e-03 6.4756e-02 -6.0000e+00 4.4077e-01 5.4784e-02 2.8013e-03 3.5731e-02 -6.0000e+00 4.7836e-01 -5.2572e-02 2.6224e-03 1.8290e-02 -6.0000e+00 2.8457e-01 1.5439e-02 1.3259e-03 5.5410e-03 -6.0000e+00 1.1870e-01 3.7635e-04 -4.0771e-04 4.0129e-05 6.5882e-05 -6.0000e+00 8.6421e-03 -4.5035e-03 0.0000e+00 11 9 0 11 8 0 99.88 24.72 0.34 -0.00450 -0.00757 180 18 1 5 0 302.460 34.00 20.00 24.72 19.33 0.0 965.55 -105016 -124212 -71593 4375 182426 -57791 -110061 -28695 -115939 -57284 117081 -66756 -34269 -23665 26642 -30917 -20884 -11410 -18413 -19305 -3958 -26033 -13406 -20729 -16713 -11310 -30383 -5325 -13118 -32649 15937 9487 11151 4042 -9772 -11272 2499 -7855 -6316 -2181 2501 -1630 -1830 1854 -6777 4395 144 3468 1700 -1757 -1087 2873 4512 2469 856 2152 2146 2980 491 -1622 1323 2089 4618 4597 3628 1294 -365 -372 449 2703 1365 -347 579 225 -1084 -313 -1739 -1841 -1778 -1142 -316 -1746 -1191 -2210 -1566 -806 0 295 75 648 851 942 -219 176 220 132 -54 130 259 165 -390 -983 -1114 -857 126 -585 -1140 -770 -721 192 533 615 276 554 355 -10 20 499 155 372 166 75 -101 520 665 552 -198 -391 203 175 170 -10 -754 -321 -174 120 -351 21 144 437 31 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