File name: Pandora289s1_DeBilt_20251015_L2Fit_fout2c31d20250921p1-8.txt File generation date: 20260624T152441.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c31p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora289_OF_v3d20240910.txt Instrument calibration file used: Pandora289s1_CF_v31d20250921.txt Level 1 file used: Pandora289s1_DeBilt_20251015_L1_smca1c31d20250921p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20251015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 341 Nominal wavelengths inside fitting window [nm]: 305.0120 305.1523 305.2926 305.4330 305.5733 305.7136 305.8539 305.9942 306.1345 306.2747 306.4150 306.5552 306.6955 306.8357 306.9759 307.1161 307.2563 307.3964 307.5366 307.6768 307.8169 307.9570 308.0971 308.2372 308.3773 308.5174 308.6575 308.7976 308.9376 309.0777 309.2177 309.3577 309.4977 309.6377 309.7777 309.9176 310.0576 310.1976 310.3375 310.4774 310.6173 310.7572 310.8971 311.0370 311.1769 311.3167 311.4566 311.5964 311.7363 311.8761 312.0159 312.1557 312.2954 312.4352 312.5750 312.7147 312.8544 312.9942 313.1339 313.2736 313.4133 313.5529 313.6926 313.8323 313.9719 314.1115 314.2512 314.3908 314.5304 314.6700 314.8095 314.9491 315.0886 315.2282 315.3677 315.5072 315.6467 315.7862 315.9257 316.0652 316.2046 316.3441 316.4835 316.6230 316.7624 316.9018 317.0412 317.1805 317.3199 317.4593 317.5986 317.7380 317.8773 318.0166 318.1559 318.2952 318.4345 318.5737 318.7130 318.8522 318.9915 319.1307 319.2699 319.4091 319.5483 319.6874 319.8266 319.9657 320.1049 320.2440 320.3831 320.5222 320.6613 320.8004 320.9395 321.0785 321.2176 321.3566 321.4956 321.6347 321.7737 321.9126 322.0516 322.1906 322.3295 322.4685 322.6074 322.7463 322.8852 323.0241 323.1630 323.3019 323.4408 323.5796 323.7184 323.8573 323.9961 324.1349 324.2737 324.4125 324.5512 324.6900 324.8287 324.9675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20251015T110134.9Z 9419.459431 2190 1 1.53 2 61.01 173.37 55.94 256.84 0.00 1 0.00 1 0 17 1.583e-02 9.434e-03 1.067e-02 5.840e-03 2.530449e-01 2.932173e-03 3.296851e-03 -6.000000e+00 8.936537e-03 224.42 -2.00 3.84 -2.00 315.87 0.00e+00 3.792974e-04 2.785419e-04 3.836255e-05 -6.000000e+00 3.649059e-04 276.17 -2.00 20.00 -2.00 315.56 0.00e+00 2.054 0.000 302.00 328.00 3 3.6033e+00 7.5367e-03 2.4591e-02 -6.0000e+00 2.2200e-02 1.5790e-02 8.4390e-03 1.3728e-02 -6.0000e+00 2.4272e-02 -3.5333e-03 4.8659e-03 6.8306e-03 -6.0000e+00 1.4316e-02 2.7782e-04 2.2071e-03 1.9582e-03 -6.0000e+00 5.9458e-03 1.4014e-03 2.0785e-04 1.6502e-04 2.3192e-05 -6.0000e+00 4.2854e-04 7.2866e-04 0.0000e+00 12 9 9 12 1 1 999.00 25.17 0.26 0.00073 0.00229 1 7 1 5 0 758.440 34.25 20.00 25.17 20.39 0.0 971.45 -48 -2927 -450 -2341 4483 -3234 -6444 702 2639 -2669 -1988 -4392 595 -747 1821 4170 613 1307 658 -582 1506 1682 2096 2011 925 60 -1413 239 -1520 -544 -692 2694 4301 -2012 -3858 -2790 -4927 -2224 117 1396 655 -1367 -479 -289 -848 391 -1420 -747 -935 -1649 -219 1414 1986 209 2191 105 1970 815 251 594 283 1704 956 2897 2211 -56 -1074 -2036 -542 732 312 471 450 435 -52 308 -1525 -1602 -1571 -964 -740 -241 -2078 -1601 -2467 -637 -44 379 397 917 1617 395 -12 -1296 113 -39 315 225 820 707 278 -959 -322 -213 -912 -118 -1278 -734 -708 -374 261 862 1028 236 391 90 -647 229 -567 264 852 235 -27 688 1013 446 237 -700 160 120 355 9 -616 -805 48 4 234 -49 61 333 -184 196 -450 -550 -10 -685 -106 -585 951 -679 -1400 159 667 -703 -522 -1186 164 -224 615 1431 231 508 267 -233 608 681 843 835 415 27 -649 110 -669 -226 -290 1186 1931 -1006 -1919 -1308 -2395 -1137 67 886 447 -976 -336 -206 -609 277 -1015 -541 -661 -1162 -156 1011 1516 165 1747 84 1593 671 205 495 229 1428 843 2607 2075 -52 -960 -1773 -473 673 299 467 457 435 -51 289 -1356 -1353 -1306 -860 -692 -242 -2160 -1754 -2787 -732 -53 458 487 1104 1904 448 -13 -1375 119 -42 357 275 1023 923 355 -1172 -381 -248 -1087 -146 -1647 -954 -958 -520 375 1250 1488 338 528 118 -819 289 -740 356 1209 333 -38 944 1370 596 309 -881 203 159 490 12 -863 -1157 70 6 359 -77 96 533 -291 302 -672 -834 SU 20251015T110249.5Z 9419.460295 2192 1 35.26 2 60.99 173.72 56.12 257.10 0.00 1 0.00 1 0 17 1.542e-02 9.087e-03 2.876e-03 1.459e-03 2.522286e-01 7.298772e-04 3.333970e-03 -6.000000e+00 8.704399e-03 224.42 -2.00 3.84 -2.00 316.06 0.00e+00 3.781937e-04 7.290564e-05 4.022552e-05 -6.000000e+00 3.553931e-04 276.17 -2.00 20.00 -2.00 315.76 0.00e+00 2.053 0.000 302.00 328.00 3 4.5712e+00 1.8820e-03 2.4624e-02 -6.0000e+00 2.1623e-02 2.3478e-02 2.1087e-03 1.3824e-02 -6.0000e+00 2.3641e-02 -1.1280e-03 1.2214e-03 6.8903e-03 -6.0000e+00 1.3944e-02 -1.9847e-03 5.6243e-04 1.9769e-03 -6.0000e+00 5.7918e-03 5.3147e-04 -2.3796e-04 4.1374e-05 2.3667e-05 -6.0000e+00 4.1736e-04 4.9682e-05 0.0000e+00 12 9 1 12 41 1 99.71 25.17 -0.03 0.00005 -0.00174 20 3 1 5 0 1678.820 34.25 20.00 25.17 20.53 0.0 971.72 -4876 1565 -1193 164 -1862 -2564 -7632 3511 -666 -1173 -2876 -4433 -2035 -1673 3182 134 402 461 3582 416 1602 963 213 1206 665 932 1189 -192 -1299 -827 1514 1638 2751 1371 -2184 -4353 -3611 -1720 -1376 74 11 -690 -191 82 -927 -136 50 -448 -142 -1260 -790 420 1548 1766 664 266 1699 989 7 -7 540 757 2773 2499 2074 446 -1127 -2159 -1160 1240 991 -259 371 224 389 369 -1143 -2165 -2796 -943 -682 -1237 -1429 -2269 -1670 -1087 -120 339 217 916 976 718 -416 75 387 -23 240 317 920 756 139 -922 -1549 -623 -366 -691 -966 -720 -1063 127 789 1050 994 659 265 -240 -186 -332 -211 371 319 414 106 377 354 953 296 -532 213 130 575 410 -721 -578 -292 216 -245 53 176 245 379 -83 -887 -502 -943 320 -261 34 -359 -497 -1426 717 -148 -279 -698 -1098 -528 -457 957 46 136 162 1265 157 616 374 83 481 285 393 502 -84 -545 -329 592 692 1179 623 -1007 -1952 -1627 -864 -781 46 8 -464 -133 58 -660 -96 35 -307 -100 -885 -566 300 1171 1336 526 217 1400 826 6 -6 442 619 2408 2241 1938 411 -1015 -1820 -981 1133 927 -263 384 228 378 345 -1018 -1866 -2380 -809 -630 -1229 -1481 -2412 -1861 -1236 -145 413 269 1112 1177 835 -460 80 410 -25 278 390 1183 982 178 -1136 -1830 -714 -440 -861 -1235 -957 -1424 179 1132 1517 1438 944 365 -317 -242 -435 -280 506 446 589 149 527 475 1260 386 -670 269 170 779 581 -1015 -831 -437 330 -382 85 276 385 603 -128 -1358 -758 SU 20251015T110952.5Z 9419.465191 2231 1 3.75 2 60.89 175.71 57.17 258.58 0.00 1 0.00 1 0 17 1.144e-02 7.853e-03 1.996e-03 1.152e-03 2.522725e-01 5.780847e-04 3.338544e-03 -6.000000e+00 6.460143e-03 224.42 -2.00 3.84 -2.00 315.71 0.00e+00 4.736258e-04 5.313730e-05 3.440230e-05 -6.000000e+00 2.637707e-04 276.17 -2.00 20.00 -2.00 315.41 0.00e+00 2.046 0.000 302.00 328.00 3 1.9469e+00 1.4842e-03 2.4564e-02 -6.0000e+00 1.6048e-02 1.0919e-02 1.6619e-03 1.3805e-02 -6.0000e+00 1.7546e-02 -2.3692e-03 9.5570e-04 6.8716e-03 -6.0000e+00 1.0349e-02 -1.2846e-03 4.2975e-04 1.9646e-03 -6.0000e+00 4.2984e-03 7.4211e-03 -7.5377e-05 3.2503e-05 2.4108e-05 -6.0000e+00 3.0977e-04 2.6438e-04 0.0000e+00 12 9 1 12 1 1 -72.18 25.18 0.28 0.00026 -0.00030 27 41 1 5 0 133.460 34.25 20.00 25.18 21.04 0.0 973.52 -907 169 -71 -819 -3338 -3434 -3782 331 1413 474 -2785 -3163 -2131 -141 1269 1344 -20 369 1093 791 2182 825 778 453 1598 946 165 -686 -795 -702 38 1325 1699 1160 -1733 -3116 -3401 -2084 231 -55 -304 -486 -464 -387 -455 310 -112 -314 -466 -702 -247 736 1295 1138 665 604 1222 615 492 174 370 872 2034 1924 1906 423 -946 -1401 -782 937 704 331 429 276 455 14 -804 -1477 -2249 -861 -969 -1237 -1476 -2167 -1689 -1043 -490 320 267 714 846 734 -66 -639 -10 237 328 344 822 647 136 -1012 -1400 -558 -196 -506 -901 -618 -754 119 650 924 586 499 347 -238 -104 73 -281 445 146 179 -19 393 725 765 510 -388 479 459 409 64 -761 -398 -133 165 0 82 88 330 235 -143 -811 -841 -218 42 -18 -207 -844 -795 -879 83 370 134 -814 -932 -626 -46 450 499 -8 144 441 332 929 358 337 203 717 452 80 -321 -351 -311 17 596 836 572 -860 -1493 -1656 -1088 137 -35 -210 -348 -332 -280 -331 224 -81 -229 -332 -497 -178 539 978 909 534 498 1026 505 413 144 308 734 1780 1764 1759 396 -851 -1211 -681 861 682 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