File name: Pandora289s1_DeBilt_20251018_L2Fit_fout2c31d20250921p1-8.txt File generation date: 20260624T152703.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c31p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora289_OF_v3d20240910.txt Instrument calibration file used: Pandora289s1_CF_v31d20250921.txt Level 1 file used: Pandora289s1_DeBilt_20251018_L1_smca1c31d20250921p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20251018 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 341 Nominal wavelengths inside fitting window [nm]: 305.0120 305.1523 305.2926 305.4330 305.5733 305.7136 305.8539 305.9942 306.1345 306.2747 306.4150 306.5552 306.6955 306.8357 306.9759 307.1161 307.2563 307.3964 307.5366 307.6768 307.8169 307.9570 308.0971 308.2372 308.3773 308.5174 308.6575 308.7976 308.9376 309.0777 309.2177 309.3577 309.4977 309.6377 309.7777 309.9176 310.0576 310.1976 310.3375 310.4774 310.6173 310.7572 310.8971 311.0370 311.1769 311.3167 311.4566 311.5964 311.7363 311.8761 312.0159 312.1557 312.2954 312.4352 312.5750 312.7147 312.8544 312.9942 313.1339 313.2736 313.4133 313.5529 313.6926 313.8323 313.9719 314.1115 314.2512 314.3908 314.5304 314.6700 314.8095 314.9491 315.0886 315.2282 315.3677 315.5072 315.6467 315.7862 315.9257 316.0652 316.2046 316.3441 316.4835 316.6230 316.7624 316.9018 317.0412 317.1805 317.3199 317.4593 317.5986 317.7380 317.8773 318.0166 318.1559 318.2952 318.4345 318.5737 318.7130 318.8522 318.9915 319.1307 319.2699 319.4091 319.5483 319.6874 319.8266 319.9657 320.1049 320.2440 320.3831 320.5222 320.6613 320.8004 320.9395 321.0785 321.2176 321.3566 321.4956 321.6347 321.7737 321.9126 322.0516 322.1906 322.3295 322.4685 322.6074 322.7463 322.8852 323.0241 323.1630 323.3019 323.4408 323.5796 323.7184 323.8573 323.9961 324.1349 324.2737 324.4125 324.5512 324.6900 324.8287 324.9675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20251018T082624.0Z 9422.351667 962 1 5.69 2 72.67 133.63 50.02 164.28 0.00 1 0.00 1 0 17 6.793e-02 1.205e-02 3.389e-02 6.020e-03 3.896283e-01 2.983053e-03 5.023276e-03 -6.000000e+00 3.829131e-02 224.07 -2.00 3.84 -2.00 318.10 0.00e+00 1.958473e-03 4.987525e-04 1.281386e-04 -6.000000e+00 1.565981e-03 275.76 -2.00 20.00 -2.00 317.77 0.00e+00 3.308 0.001 302.00 328.00 3 3.7751e+00 7.9020e-03 3.9131e-02 -6.0000e+00 9.5047e-02 3.4585e-02 8.9146e-03 2.1368e-02 -6.0000e+00 1.0396e-01 -2.5227e-02 5.9709e-03 1.0711e-02 -6.0000e+00 6.1331e-02 1.0136e-02 3.1348e-03 3.1201e-03 -6.0000e+00 2.5481e-02 2.8897e-04 -3.8275e-04 1.6963e-04 3.2922e-05 -6.0000e+00 1.8390e-03 2.7302e-03 0.0000e+00 12 9 9 12 33 1 999.00 24.79 0.03 0.00273 -0.00015 2 3 1 5 0 1894.410 34.00 20.00 24.79 16.55 0.0 954.56 -42145 -1528 -1202 24062 16083 -37618 -30710 3439 5204 10233 -4972 -2707 -12026 -13409 7485 -467 7315 -8782 10919 -2585 272 2692 -3192 -1551 -4531 -4048 390 5901 -2225 -4302 -227 -447 6338 7936 15 -6344 -6128 -509 -3566 886 -390 192 -3387 1528 -335 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-549 1418 -784 -247 -265 -48 -28 593 927 123 1965 667 1131 221 -680 -819 614 473 423 -1558 -183 367 1046 -375 566 720 120 82 93 -2365 -1181 SU 20251018T082720.4Z 9422.352319 964 1 54.19 2 72.56 133.85 49.99 164.58 0.00 1 0.00 1 0 17 3.782e-02 8.757e-03 6.218e-03 1.150e-03 3.935228e-01 5.695458e-04 5.087041e-03 -6.000000e+00 2.131475e-02 224.07 -2.00 3.84 -2.00 318.03 0.00e+00 1.044864e-03 9.356412e-05 1.251599e-04 -6.000000e+00 8.717339e-04 275.76 -2.00 20.00 -2.00 317.71 0.00e+00 3.289 0.001 302.00 328.00 3 3.1653e+00 1.5071e-03 3.9112e-02 -6.0000e+00 5.2908e-02 2.9398e-02 1.6995e-03 2.1598e-02 -6.0000e+00 5.7868e-02 -1.7096e-02 1.1334e-03 1.0836e-02 -6.0000e+00 3.4140e-02 5.3973e-03 5.9498e-04 3.1557e-03 -6.0000e+00 1.4184e-02 5.3989e-04 -2.5562e-04 3.2443e-05 3.4221e-05 -6.0000e+00 1.0237e-03 3.0044e-03 0.0000e+00 11 8 0 10 0 0 99.71 24.79 0.18 0.00300 0.00108 77 8 1 5 0 703.600 34.00 20.00 24.79 16.56 0.0 954.51 -22693 -9162 -4850 2341 8040 -16635 -19866 2662 -3585 -6086 -4249 -9341 -8670 -2816 6565 -663 521 -2312 6491 -1297 1888 956 -1662 1793 -1974 -1190 289 -2325 -3370 -1473 1179 1769 4795 2274 -4312 -5356 -4412 -2275 -1882 -547 859 -700 -309 572 -1402 521 71 450 595 -702 -486 517 2524 2255 1226 620 1962 1638 329 -541 483 880 2904 3332 2609 750 -1205 -1870 -762 1147 971 494 95 184 154 -133 -1205 -2544 -3175 -1168 -781 -1287 -1706 -2307 -1588 -1231 -61 434 445 955 937 643 -700 -510 -293 -115 65 390 802 593 163 -948 -1469 -661 -41 -691 -680 -745 -1047 328 957 974 856 604 134 -247 -114 60 71 511 292 352 -105 331 527 803 197 -505 170 485 148 144 -788 -618 -173 -88 -230 39 201 435 356 -101 -505 -556 -1349 -555 -300 132 396 -974 -1221 148 -243 -456 -321 -772 -801 -295 753 -86 73 -356 970 -220 322 166 -298 326 -404 -258 63 -501 -705 -297 243 410 1123 584 -1173 -1416 -1180 -684 -636 -217 354 -318 -146 275 -695 255 35 220 291 -354 -256 274 1427 1367 738 390 1255 1062 213 -347 308 591 1979 2486 1959 569 -924 -1372 -573 896 809 444 83 166 132 -110 -907 -1912 -2425 -913 -664 -1184 -1650 -2399 -1657 -1363 -69 509 530 1113 1045 698 -739 -507 -298 -122 74 478 1036 777 218 -1228 -1739 -786 -51 -884 -885 -1015 -1447 464 1406 1518 1309 928 202 -346 -158 84 100 771 446 541 -158 495 760 1150 269 -698 231 693 225 222 -1266 -1026 -292 -152 -404 69 365 787 628 -177 -867 -946 SU 20251018T082914.5Z 9422.353640 966 1 54.99 2 72.35 134.29 49.92 165.18 0.00 1 0.00 1 0 17 3.098e-01 1.857e-02 8.803e-02 3.177e-03 3.825822e-01 1.574707e-03 4.937105e-03 -6.000000e+00 1.746336e-01 224.07 -2.00 3.84 -2.00 318.50 0.00e+00 2.299521e-03 2.928660e-04 1.377665e-04 -6.000000e+00 7.141711e-03 275.76 -2.00 20.00 -2.00 318.17 0.00e+00 3.253 0.001 302.00 328.00 3 4.9979e+00 4.1998e-03 3.8508e-02 -6.0000e+00 4.3348e-01 7.9148e-02 4.7556e-03 2.1076e-02 -6.0000e+00 4.7410e-01 -6.3967e-02 3.3384e-03 1.0607e-02 -6.0000e+00 2.7971e-01 2.9132e-02 1.7757e-03 3.1129e-03 -6.0000e+00 1.1621e-01 8.9028e-05 -8.4474e-04 9.1260e-05 3.2705e-05 -6.0000e+00 8.3868e-03 2.5231e-03 0.0000e+00 12 9 8 11 8 0 99.89 24.79 0.23 0.00252 -0.00382 19 2 1 5 0 2893.890 34.00 20.00 24.79 16.58 0.0 954.52 -62430 -5358 4589 30349 338087 -22333 -45440 41116 -6801 -18717 7572 14284 -14626 -1474 47192 -3544 9474 -7334 47729 -6903 6783 3737 -13023 10952 -4649 -15498 5313 2823 -5553 -2473 14742 8172 18109 10625 -11782 -12921 1194 4589 -11029 632 4079 -1249 -2844 2813 -3465 -3323 -2448 4200 2581 -2857 -2421 -1390 6897 4626 2256 -354 5998 4358 3409 -2146 -78 -491 9483 7463 5033 1277 -3230 -2153 225 -172 1586 -1087 -1308 658 -166 925 -3589 -5604 -7720 -2100 -263 297 -1064 -3965 -1655 -2581 1295 -449 534 136 635 328 -1408 1984 227 121 -1031 640 933 799 158 -1698 -777 -400 1116 -1449 -232 -1582 -1734 1087 1069 1123 1514 870 621 -1554 434 -490 -156 1299 970 794 -460 182 573 2072 1127 -1148 -1513 -342 -380 846 -939 -780 -175 174 -1446 -168 906 87 754 121 -437 -529 -4759 -269 222 1110 1048 -1170 -2999 1274 -386 -1276 404 735 -1124 -119 2823 -405 1042 -1016 4023 -1052 931 532 -2188 1497 -797 -3136 881 465 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