File name: Pandora289s1_DeBilt_20251211_L2Fit_fout2c31d20250921p1-8.txt File generation date: 20260624T153351.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c31p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora289_OF_v3d20240910.txt Instrument calibration file used: Pandora289s1_CF_v31d20250921.txt Level 1 file used: Pandora289s1_DeBilt_20251211_L1_smca1c31d20250921p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20251211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 341 Nominal wavelengths inside fitting window [nm]: 305.0120 305.1523 305.2926 305.4330 305.5733 305.7136 305.8539 305.9942 306.1345 306.2747 306.4150 306.5552 306.6955 306.8357 306.9759 307.1161 307.2563 307.3964 307.5366 307.6768 307.8169 307.9570 308.0971 308.2372 308.3773 308.5174 308.6575 308.7976 308.9376 309.0777 309.2177 309.3577 309.4977 309.6377 309.7777 309.9176 310.0576 310.1976 310.3375 310.4774 310.6173 310.7572 310.8971 311.0370 311.1769 311.3167 311.4566 311.5964 311.7363 311.8761 312.0159 312.1557 312.2954 312.4352 312.5750 312.7147 312.8544 312.9942 313.1339 313.2736 313.4133 313.5529 313.6926 313.8323 313.9719 314.1115 314.2512 314.3908 314.5304 314.6700 314.8095 314.9491 315.0886 315.2282 315.3677 315.5072 315.6467 315.7862 315.9257 316.0652 316.2046 316.3441 316.4835 316.6230 316.7624 316.9018 317.0412 317.1805 317.3199 317.4593 317.5986 317.7380 317.8773 318.0166 318.1559 318.2952 318.4345 318.5737 318.7130 318.8522 318.9915 319.1307 319.2699 319.4091 319.5483 319.6874 319.8266 319.9657 320.1049 320.2440 320.3831 320.5222 320.6613 320.8004 320.9395 321.0785 321.2176 321.3566 321.4956 321.6347 321.7737 321.9126 322.0516 322.1906 322.3295 322.4685 322.6074 322.7463 322.8852 323.0241 323.1630 323.3019 323.4408 323.5796 323.7184 323.8573 323.9961 324.1349 324.2737 324.4125 324.5512 324.6900 324.8287 324.9675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20251211T105927.2Z 9476.457954 1571 1 54.85 2 75.49 172.12 82.94 269.15 0.00 1 0.00 1 0 17 3.364e-01 1.680e-02 1.350e-01 3.710e-03 4.962605e-01 1.846663e-03 6.329520e-03 -6.000000e+00 1.872525e-01 220.32 -2.00 3.84 -2.00 319.51 0.00e+00 6.124030e-03 4.755484e-04 2.674641e-04 -6.000000e+00 8.093068e-03 268.92 -2.00 20.00 -2.00 319.21 0.00e+00 3.909 0.001 302.00 328.00 3 4.4637e+00 5.0327e-03 4.7079e-02 -6.0000e+00 4.6084e-01 1.4988e-01 5.8689e-03 2.7035e-02 -6.0000e+00 5.0574e-01 -1.0782e-01 5.0972e-03 1.3978e-02 -6.0000e+00 2.9891e-01 4.4580e-02 2.7594e-03 4.2695e-03 -6.0000e+00 1.2711e-01 6.8266e-05 -1.0476e-03 1.0449e-04 4.5040e-05 -6.0000e+00 9.3677e-03 1.0927e-03 0.0000e+00 12 9 8 11 40 0 100.00 24.49 0.14 0.00109 -0.00678 29 3 1 5 0 1890.950 33.75 20.00 24.49 15.15 0.0 948.11 900000 33222 -22918 900000 900000 -57384 -81212 -91388 -70632 154855 226401 20135 -48104 180081 95649 -42712 -10931 773 17907 15797 -725 -9147 -28166 6636 -2768 7439 -15842 35625 -2588 -10710 -3061 -1296 24144 17230 -5285 -10137 1453 3092 -5745 7090 7039 5769 1673 5866 -5899 -7563 -7551 4819 1341 -4022 882 -1481 7975 8799 76 1391 4777 5645 -883 -7484 1412 537 12915 6989 4156 2380 1483 -2365 -567 -704 3380 -325 -1818 603 365 2305 -4661 -7141 -6224 -1029 1405 -1830 -518 -2676 -1994 -991 2074 -1420 -564 1182 -1922 1756 -2718 2160 884 -974 -1711 323 299 1766 -52 -487 -1474 43 209 -1555 157 -978 -810 959 547 1071 456 1827 668 -1364 -784 -624 -40 719 1133 875 30 834 369 551 1032 -2003 -645 48 133 1158 -650 -783 -561 -461 -1152 7 991 461 428 58 -323 -563 900000 408 -539 900000 900000 -1619 -2878 -3933 -2759 672 819 364 -2018 977 1522 -3244 -684 47 984 937 -52 -721 -2669 456 -222 568 -1541 2036 -213 -972 -280 -137 2305 1919 -738 -1426 184 436 -1072 1380 1550 1402 407 1416 -1635 -2171 -2205 1263 370 -1209 268 -503 2706 3182 32 589 2005 2361 -388 -3435 596 243 5737 3681 2224 1309 855 -1362 -334 -427 2212 -237 -1373 433 246 1389 -2718 -4376 -3878 -627 975 -1502 -429 -2428 -1899 -992 2143 -1484 -594 1202 -2077 1704 -2539 1833 787 -983 -1846 388 373 2304 -67 -628 -1726 47 237 -1919 202 -1243 -1087 1378 813 1701 749 2899 1012 -2103 -1153 -924 -62 1097 1789 1383 46 1306 563 806 1430 -2771 -914 74 216 1992 -1112 -1394 -1054 -866 -2276 13 1979 923 831 113 -595 -1021 SU 20251211T110203.9Z 9476.459768 1579 1 7.28 2 75.43 172.73 83.34 269.64 0.00 1 0.00 1 0 17 2.175e-01 1.508e-02 1.620e-01 7.846e-03 4.949656e-01 3.899486e-03 6.307738e-03 -6.000000e+00 1.219632e-01 220.32 -2.00 3.84 -2.00 319.18 0.00e+00 3.622565e-03 9.136634e-04 2.484360e-04 -6.000000e+00 5.200992e-03 268.92 -2.00 20.00 -2.00 318.87 0.00e+00 3.896 0.001 302.00 328.00 3 3.8129e+00 1.0542e-02 4.6879e-02 -6.0000e+00 3.0049e-01 7.2910e-02 1.2184e-02 2.6865e-02 -6.0000e+00 3.2970e-01 -5.8185e-02 1.0164e-02 1.3868e-02 -6.0000e+00 1.9418e-01 2.6246e-02 5.5298e-03 4.2234e-03 -6.0000e+00 8.1417e-02 1.3804e-04 -5.4514e-04 2.2005e-04 4.4754e-05 -6.0000e+00 6.1352e-03 1.7622e-03 0.0000e+00 12 9 9 12 1 1 999.00 24.50 0.22 0.00176 -0.00233 2 2 1 5 0 2425.610 33.75 20.00 24.50 15.08 0.0 947.79 -147158 -2440 115744 900000 900000 88971 -12252 900000 -75564 7806 80467 10518 -20987 55562 -13807 10955 12799 -23572 23284 9856 -5288 12090 -11908 12655 -15124 -3663 -3642 21479 11912 -10389 -132 8621 20445 16474 2024 -3132 -2260 5025 -2587 -3917 4768 -1500 -5097 3858 1363 4024 -5302 -2108 2370 -4494 1738 2802 6166 6069 -691 181 688 1563 1690 -2537 611 -2255 7958 4122 2161 71 -155 -2192 666 1067 1031 640 778 1533 -272 570 -3029 -3916 -6432 -843 137 -1889 1231 -2445 -1100 -310 771 -381 -47 417 -1478 1941 -1271 1199 -757 -1053 -1972 414 500 999 -355 -1898 -1234 734 512 -1180 -951 -499 -1275 425 585 963 1046 1065 402 -1209 -500 -151 559 -251 1245 1605 513 604 452 1256 159 -1878 -583 894 349 -47 -99 -649 -646 481 -433 -304 -226 239 513 -221 -447 -192 -8697 -45 885 900000 900000 680 -234 900000 -3468 167 862 241 -770 1190 -739 545 705 -2037 1353 693 -449 869 -1093 949 -1619 -373 -376 1692 1011 -1112 -14 969 2377 2167 308 -484 -353 834 -514 -942 1197 -438 -1630 1164 429 1253 -1686 -718 786 -1512 585 1023 2397 2545 -327 88 345 783 833 -1276 299 -1112 3942 2369 1363 46 -96 -1336 413 689 750 468 581 1185 -201 380 -1893 -2504 -4337 -561 106 -1585 1109 -2300 -1081 -321 793 -417 -52 452 -1560 1959 -1222 1076 -720 -1052 -2272 499 634 1335 -472 -2349 -1442 852 583 -1464 -1182 -648 -1765 599 863 1519 1693 1685 605 -1814 -715 -218 841 -385 1952 2502 781 928 675 1788 229 -2679 -812 1360 565 -78 -170 -1119 -1178 881 -837 -601 -432 472 980 -402 -802 -339 SU 20251211T110248.1Z 9476.460279 1581 1 15.42 2 75.42 172.91 83.46 269.78 0.00 1 0.00 1 0 17 1.592e-01 1.246e-02 6.689e-02 4.478e-03 4.987821e-01 2.225209e-03 6.367915e-03 -6.000000e+00 8.923318e-02 220.32 -2.00 3.84 -2.00 319.22 0.00e+00 3.844835e-03 5.268055e-04 2.466842e-04 -6.000000e+00 3.732405e-03 268.92 -2.00 20.00 -2.00 318.92 0.00e+00 3.892 0.001 302.00 328.00 3 3.7143e+00 6.0054e-03 4.6968e-02 -6.0000e+00 2.1988e-01 9.3307e-02 6.9363e-03 2.7051e-02 -6.0000e+00 2.4125e-01 -7.6218e-02 5.7854e-03 1.3930e-02 -6.0000e+00 1.4203e-01 3.1562e-02 3.1511e-03 4.2284e-03 -6.0000e+00 5.9287e-02 1.5123e-04 -7.2104e-04 1.2497e-04 4.5119e-05 -6.0000e+00 4.4444e-03 2.0085e-03 0.0000e+00 12 9 9 12 1 1 99.98 24.50 0.20 0.00201 -0.00341 10 4 1 5 0 1400.940 33.75 20.00 24.50 15.05 0.0 947.74 -122680 16296 -22372 50008 900000 -28342 -59375 900000 -63003 1037 49710 8496 -39500 27848 23006 -14172 -13156 -1974 9041 4040 9971 -7123 -6869 23155 2897 2354 -8047 7073 5971 -3886 -985 5203 11611 7515 -4862 -7513 2816 -5988 -4386 1319 4819 2576 -5913 4291 -1775 -2725 -6526 1841 3382 -3955 2235 631 7451 2606 -225 244 2648 2474 1110 -3076 1331 -473 7229 2407 3391 2342 684 -2390 -1722 1882 1258 389 -628 1578 489 963 -2258 -3430 -4606 -1706 -1250 -606 -479 -2769 -1529 -890 -780 -254 365 68 -278 1226 -1165 1249 14 -1493 -503 813 623 1239 -6 -273 -1826 -36 224 -532 -428 111 -447 671 362 165 890 917 -63 -849 -1097 -630 340 905 -74 763 -102 860 571 847 151 -995 -439 16 201 576 -1469 106 -138 173 -386 34 955 325 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