File name: Pandora289s1_DeBilt_20251216_L2Fit_fout2c2d20250401p1-8.txt File generation date: 20251216T233935.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora289_OF_v3d20240910.txt Instrument calibration file used: Pandora289s1_CF_v2d20250401.txt Level 1 file used: Pandora289s1_DeBilt_20251216_L1_smca1c2d20250401p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20251216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 341 Nominal wavelengths inside fitting window [nm]: 305.0110 305.1514 305.2918 305.4321 305.5725 305.7128 305.8531 305.9934 306.1337 306.2740 306.4143 306.5545 306.6948 306.8350 306.9752 307.1155 307.2557 307.3959 307.5360 307.6762 307.8164 307.9565 308.0967 308.2368 308.3769 308.5170 308.6571 308.7972 308.9372 309.0773 309.2173 309.3574 309.4974 309.6374 309.7774 309.9174 310.0574 310.1973 310.3373 310.4772 310.6171 310.7571 310.8970 311.0369 311.1767 311.3166 311.4565 311.5963 311.7362 311.8760 312.0158 312.1556 312.2954 312.4352 312.5749 312.7147 312.8544 312.9942 313.1339 313.2736 313.4133 313.5530 313.6927 313.8323 313.9720 314.1116 314.2513 314.3909 314.5305 314.6701 314.8097 314.9492 315.0888 315.2284 315.3679 315.5074 315.6469 315.7864 315.9259 316.0654 316.2049 316.3443 316.4838 316.6232 316.7626 316.9020 317.0414 317.1808 317.3202 317.4596 317.5989 317.7383 317.8776 318.0169 318.1562 318.2955 318.4348 318.5741 318.7133 318.8526 318.9918 319.1310 319.2702 319.4094 319.5486 319.6878 319.8270 319.9661 320.1053 320.2444 320.3835 320.5226 320.6617 320.8008 320.9399 321.0789 321.2180 321.3570 321.4960 321.6351 321.7741 321.9131 322.0520 322.1910 322.3300 322.4689 322.6078 322.7467 322.8857 323.0246 323.1634 323.3023 323.4412 323.5800 323.7189 323.8577 323.9965 324.1353 324.2741 324.4129 324.5516 324.6904 324.8291 324.9679 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20251216T092849.2Z 9481.395014 676 1 3.27 2 80.32 150.84 74.15 191.65 0.00 1 0.00 1 0 17 4.881e-01 2.279e-02 3.237e-01 1.351e-02 6.931503e-01 7.050410e-03 9.238895e-03 -6.000000e+00 2.783908e-01 220.24 -2.00 3.84 -2.00 320.68 0.00e+00 8.284881e-03 2.697859e-03 4.330123e-03 -6.000000e+00 1.258171e-02 268.40 -2.00 20.00 -2.00 320.26 0.00e+00 5.679 0.004 302.00 328.00 3 2.1033e+00 2.0751e-02 6.8906e-02 -6.0000e+00 6.8303e-01 3.2251e-01 2.6331e-02 4.0720e-02 -6.0000e+00 7.4833e-01 -4.1311e-01 2.6272e-02 2.6587e-02 -6.0000e+00 4.4283e-01 1.6897e-01 1.3285e-02 1.2553e-02 -6.0000e+00 1.8646e-01 1.1272e-04 -3.2376e-04 3.6776e-04 1.8296e-04 -6.0000e+00 1.4497e-02 1.3379e-03 0.0000e+00 12 9 9 12 1 1 999.00 24.34 0.34 0.00134 -0.00109 2 5 1 5 0 1087.190 33.75 20.00 24.34 13.50 0.0 941.63 -238457 900000 17731 -23232 900000 -53966 -200620 900000 -149726 -117583 -125507 -75207 -114878 900000 68849 -40276 12967 133658 -37492 -25467 -51225 -4534 -67858 116583 155650 -1308 182573 900000 -51008 42454 -21284 34076 33896 25743 34977 144604 -10681 15736 -25034 44457 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136 -827 -553 -1481 -853 -273 49 -1147 -3268 -64 155 -642 -1483 -3314 -1272 -1001 -3414 -2122 140 -521 1822 466 -214 -910 -426 750 838 -694 1408 -10 3629 544 -103 3966 1599 2403 1845 3983 -616 -1273 -658 955 1965 -1180 -171 1089 1472 -2666 148 -1571 372 -746 1237 -2231 -1779 SU 20251216T103428.1Z 9481.440603 1190 1 35.92 2 76.59 165.73 77.55 206.68 0.00 1 0.00 1 0 17 3.139e-01 1.648e-02 1.102e-01 4.827e-03 5.396619e-01 2.482889e-03 6.991172e-03 -6.000000e+00 1.791348e-01 220.24 -2.00 3.84 -2.00 319.93 0.00e+00 4.711960e-03 7.710148e-04 1.906729e-03 -6.000000e+00 9.249811e-03 268.39 -2.00 20.00 -2.00 319.49 0.00e+00 4.209 0.002 302.00 328.00 3 4.1608e+00 6.9855e-03 5.1112e-02 -6.0000e+00 4.4187e-01 1.6563e-01 8.3822e-03 2.9985e-02 -6.0000e+00 4.8454e-01 -1.4156e-01 7.6629e-03 1.7504e-02 -6.0000e+00 2.8496e-01 5.5764e-02 4.0405e-03 7.4243e-03 -6.0000e+00 1.2018e-01 6.6864e-05 -1.2405e-03 1.4041e-04 8.4890e-05 -6.0000e+00 9.3614e-03 3.0993e-03 0.0000e+00 12 9 9 12 9 1 99.98 24.40 0.25 0.00310 -0.00622 14 2 1 5 0 2394.290 33.75 20.00 24.40 13.70 0.0 943.08 -132957 -35852 256110 900000 900000 -49080 -128195 900000 -43320 900000 900000 900000 -49999 900000 66347 -38108 -24343 2075 35678 11636 4735 4330 -21120 -1319 -16186 18049 3351 59962 27265 -16335 -3008 40147 50791 30072 -8220 1666 10985 157 -12989 1626 13959 591 -6089 -3980 -6685 -8521 -4943 6765 4220 -993 906 -460 8555 9599 -709 1678 6751 4574 2464 -8483 2985 -105 14418 9030 3109 306 229 -1311 -376 429 3552 -56 -1202 616 -754 1890 -1095 -7074 -7525 127 2788 -1589 239 -3402 -3110 -1145 1773 -1256 -1397 1093 -1937 1745 -2424 4026 753 -568 -1103 -337 383 843 -894 -978 -1238 1857 150 -1509 -1033 69 -70 60 1242 581 55 1145 953 -1277 -160 422 323 1773 1234 564 -44 -20 596 533 717 -1958 -977 206 -799 797 -1643 -195 -446 -470 -512 -157 991 521 66 464 -523 -130 -4262 -521 1204 900000 900000 -854 -4942 900000 -876 900000 900000 900000 -1528 900000 998 -1953 -1236 89 1174 514 232 214 -1350 -72 -1096 916 200 2002 1243 -1175 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7.8396e-03 2.7623e-02 -6.0000e+00 2.9683e-01 -9.5168e-02 6.4586e-03 1.4948e-02 -6.0000e+00 1.7567e-01 3.4438e-02 3.4542e-03 6.3885e-03 -6.0000e+00 7.3474e-02 1.2914e-04 -6.0297e-04 1.4006e-04 6.7523e-05 -6.0000e+00 5.6704e-03 1.6143e-04 0.0000e+00 12 9 9 12 9 1 98.86 24.41 -0.07 0.00016 -0.00437 6 2 1 5 0 2370.830 33.75 20.00 24.41 14.85 0.0 947.65 -92740 -50834 -19285 13765 900000 -84183 -76755 900000 -62676 7319 16176 56198 -35499 118255 2587 -26791 -22091 1133 -6682 11428 4749 -14782 -13691 -1618 -6850 8810 -10545 6371 1796 -10878 -7494 8153 12370 17341 -3027 -3988 -1264 -5668 -5192 3563 5758 902 -2571 77 -4540 -6550 156 4308 1675 -429 2930 2495 5458 5968 1701 1302 4342 2563 2417 -3351 1536 274 7200 4762 2009 1810 544 69 -949 324 2884 -536 63 -1081 -303 580 -2780 -3814 -4543 -548 82 -1342 459 -3259 -2260 -1417 139 -1211 -189 1154 -893 1160 -1333 1058 850 -232 -807 64 388 150 -782 -825 -1131 35 851 -855 -422 -425 -231 177 917 426 510 1073 359 60 -242 36 163 388 241 531 -13 621 251 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