File name: Pandora289s1_DeBilt_20260213_L2Fit_fout2c31d20250921p1-8.txt File generation date: 20260624T154044.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c31p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 289 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora289_OF_v3d20240910.txt Instrument calibration file used: Pandora289s1_CF_v31d20250921.txt Level 1 file used: Pandora289s1_DeBilt_20260213_L1_smca1c31d20250921p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20260213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 341 Nominal wavelengths inside fitting window [nm]: 305.0120 305.1523 305.2926 305.4330 305.5733 305.7136 305.8539 305.9942 306.1345 306.2747 306.4150 306.5552 306.6955 306.8357 306.9759 307.1161 307.2563 307.3964 307.5366 307.6768 307.8169 307.9570 308.0971 308.2372 308.3773 308.5174 308.6575 308.7976 308.9376 309.0777 309.2177 309.3577 309.4977 309.6377 309.7777 309.9176 310.0576 310.1976 310.3375 310.4774 310.6173 310.7572 310.8971 311.0370 311.1769 311.3167 311.4566 311.5964 311.7363 311.8761 312.0159 312.1557 312.2954 312.4352 312.5750 312.7147 312.8544 312.9942 313.1339 313.2736 313.4133 313.5529 313.6926 313.8323 313.9719 314.1115 314.2512 314.3908 314.5304 314.6700 314.8095 314.9491 315.0886 315.2282 315.3677 315.5072 315.6467 315.7862 315.9257 316.0652 316.2046 316.3441 316.4835 316.6230 316.7624 316.9018 317.0412 317.1805 317.3199 317.4593 317.5986 317.7380 317.8773 318.0166 318.1559 318.2952 318.4345 318.5737 318.7130 318.8522 318.9915 319.1307 319.2699 319.4091 319.5483 319.6874 319.8266 319.9657 320.1049 320.2440 320.3831 320.5222 320.6613 320.8004 320.9395 321.0785 321.2176 321.3566 321.4956 321.6347 321.7737 321.9126 322.0516 322.1906 322.3295 322.4685 322.6074 322.7463 322.8852 323.0241 323.1630 323.3019 323.4408 323.5796 323.7184 323.8573 323.9961 324.1349 324.2737 324.4125 324.5512 324.6900 324.8287 324.9675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20260213T103331.3Z 9540.439946 1403 1 5.67 2 67.63 158.91 84.69 205.18 0.00 1 0.00 1 0 25 6.503e-02 8.614e-03 2.621e-02 3.188e-03 5.002730e-01 1.583960e-03 6.423533e-03 -6.000000e+00 3.659775e-02 223.53 -2.00 3.84 -2.00 318.42 0.00e+00 8.625822e-04 2.935533e-04 1.880957e-04 -6.000000e+00 1.499086e-03 266.76 -2.00 20.00 -2.00 318.11 0.00e+00 2.606 0.000 302.00 328.00 3 3.3377e+00 4.2155e-03 3.7825e-02 -6.0000e+00 9.0738e-02 2.9023e-02 4.7763e-03 2.7202e-02 -6.0000e+00 9.9264e-02 -1.9884e-02 3.4265e-03 1.3823e-02 -6.0000e+00 5.8586e-02 8.5581e-03 1.8458e-03 4.0722e-03 -6.0000e+00 2.4381e-02 7.3320e-04 -2.6915e-04 8.6640e-05 4.2730e-05 -6.0000e+00 1.7601e-03 -5.1261e-04 0.0000e+00 12 9 1 12 1 1 -49.86 24.20 0.23 -0.00051 -0.00254 6 7 1 5 0 809.830 33.50 19.98 24.20 8.60 0.1 922.04 -31064 -5170 -25169 -5935 -3686 -28711 -47260 -2156 -11394 -10270 8756 -10913 -7664 1572 5978 -7147 -8424 -6979 8045 1527 2851 1823 247 -3129 1673 -618 -5419 766 -3512 -3876 1204 2185 2001 1967 -1103 -6818 -2541 -4420 -2097 2211 277 -2123 327 1687 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176 -521 139 430 -72 825 -79 634 30 837 894 1176 404 -984 647 945 981 537 -1440 -873 -436 -56 -220 -30 1106 138 481 -330 -1179 -1051 SU 20260213T103455.0Z 9540.440914 1405 1 54.41 2 67.55 159.27 84.77 205.46 0.00 1 0.00 1 0 17 1.312e-01 1.232e-02 3.031e-02 2.142e-03 4.953724e-01 1.065576e-03 6.327870e-03 -6.000000e+00 7.380018e-02 223.53 -2.00 3.84 -2.00 318.94 0.00e+00 2.069916e-03 2.312583e-04 2.213792e-04 -6.000000e+00 3.023910e-03 266.76 -2.00 20.00 -2.00 318.63 0.00e+00 2.598 0.000 302.00 328.00 3 4.7640e+00 2.8640e-03 3.7648e-02 -6.0000e+00 1.8297e-01 5.4448e-02 3.2788e-03 2.7071e-02 -6.0000e+00 2.0019e-01 -5.0504e-02 2.5974e-03 1.3841e-02 -6.0000e+00 1.1815e-01 2.4115e-02 1.4125e-03 4.1238e-03 -6.0000e+00 4.9151e-02 1.7685e-04 -7.4439e-04 5.8819e-05 4.2410e-05 -6.0000e+00 3.5506e-03 1.8012e-03 0.0000e+00 12 8 8 10 0 0 99.99 24.20 0.16 0.00180 -0.00379 61 6 1 5 0 891.800 33.75 19.97 24.20 8.56 0.1 921.96 -38519 -22421 -26302 33563 34328 -3751 -78179 44763 -63393 -26429 47624 -13499 -26091 -1967 23135 -8808 -17940 -11831 12663 1981 3900 -338 -7896 -8426 -6820 3713 1175 11069 229 -4815 8911 -1285 15288 6453 -9178 -10368 8669 -3217 -5607 6117 334 -2184 -4269 237 -3499 1670 -3868 -1415 1653 1417 1073 2025 5347 4309 -1541 2503 2730 554 1817 -1099 578 2334 6399 3300 3224 2168 -426 -3557 -626 880 1165 300 -733 1531 310 -625 -2589 -3335 -4677 -694 -360 -933 -549 -2798 -2574 -925 686 32 245 523 712 1356 -1160 -116 -1139 -123 -378 107 917 995 -284 -723 -2165 -1041 159 -333 -789 -729 -1229 399 987 692 774 1341 1035 -973 -353 -181 -39 669 491 426 228 586 577 1335 6 -1107 -283 344 -95 418 -1022 -495 -385 135 -488 164 303 360 402 257 -901 -492 -1006 -595 -786 547 516 -77 -3414 645 -3086 -961 856 -474 -1199 -88 996 -617 -1544 -1041 934 172 344 -31 -795 -894 -775 406 134 1117 25 -553 959 -178 2079 1041 -1732 -1906 1340 -641 -1272 1477 97 -713 -1499 82 -1269 581 -1437 -517 595 526 425 797 2238 1963 -784 1275 1432 300 955 -580 300 1256 3662 2001 2099 1435 -275 -2277 -406 632 872 243 -613 1218 235 -468 -1779 -2165 -3146 -502 -280 -835 -505 -2826 -2572 -964 749 37 286 598 775 1365 -1175 -111 -1139 -127 -443 133 1185 1361 -386 -957 -2614 -1187 186 -417 -1052 -958 -1716 564 1522 1090 1249 2101 1614 -1444 -499 -257 -58 1049 759 657 358 881 839 1952 9 -1522 -400 505 -147 690 -1773 -845 -693 244 -929 318 590 696 754 476 -1592 -850 SU 20260213T103858.6Z 9540.443734 1413 1 54.79 2 67.34 160.31 85.03 206.29 0.00 1 0.00 1 0 17 2.170e-01 1.453e-02 5.940e-02 2.416e-03 4.925611e-01 1.199969e-03 6.277139e-03 -6.000000e+00 1.221412e-01 223.53 -2.00 3.84 -2.00 318.86 0.00e+00 1.698763e-03 2.554175e-04 2.180024e-04 -6.000000e+00 5.001523e-03 266.76 -2.00 20.00 -2.00 318.56 0.00e+00 2.575 0.000 302.00 328.00 3 5.0358e+00 3.2204e-03 3.7353e-02 -6.0000e+00 3.0283e-01 7.2609e-02 3.6847e-03 2.6870e-02 -6.0000e+00 3.3125e-01 -5.6972e-02 2.8696e-03 1.3720e-02 -6.0000e+00 1.9551e-01 2.5691e-02 1.5568e-03 4.0778e-03 -6.0000e+00 8.1388e-02 1.3709e-04 -4.3658e-04 6.6748e-05 4.2422e-05 -6.0000e+00 5.8723e-03 -2.5630e-03 0.0000e+00 12 9 8 11 40 0 99.93 24.20 0.20 -0.00256 -0.00584 30 3 1 5 0 1826.310 33.75 19.95 24.20 8.51 0.1 922.13 -37235 -11970 -15838 23909 42251 -13070 -77316 182305 -77135 7646 90066 -9879 -30426 35625 37474 -19890 -23185 -9410 14454 232 5527 -697 -10741 -4544 -4434 9610 977 15064 850 -11281 7027 4467 16908 6726 -8977 -10557 13700 -4554 -7901 3401 1377 -2740 -4262 375 -3203 3057 -5815 356 1260 879 232 3563 6320 4679 -2255 2446 4449 -46 1991 -1926 1739 1692 7590 3748 3034 2648 -786 -3378 -707 273 2073 -573 -1756 1130 1295 -263 -3070 -3361 -5099 -1537 485 -1354 87 -2858 -2640 -883 631 -64 373 374 -22 1469 -1950 871 -1061 -442 -932 132 325 813 -432 -523 -2117 -17 203 -473 -894 -827 -1543 494 1294 906 1292 1401 1317 -1341 -660 -148 -285 1006 937 917 412 347 194 1206 113 -1331 -581 473 1 565 -1164 -575 -163 -131 -539 -39 549 216 358 421 -899 -421 -1062 -316 -470 473 647 -323 -3681 730 -4745 218 1168 -368 -1599 1192 1519 -1688 -2279 -874 1131 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