File name: Pandora82s1_DeBilt_20241201_L2Fit_fout2c2d20240415p1-8.txt File generation date: 20241201T233415.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 82 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora82_OF_v3d20230727.txt Instrument calibration file used: Pandora82s1_CF_v2d20240415.txt Level 1 file used: Pandora82s1_DeBilt_20241201_L1_smca1c2d20240415p1-8.txt Full location name: Royal Netherlands Meteorological Institute (KNMI), De Bilt Short location name: DeBilt Country of location: Netherlands Location latitude [deg]: 52.1012 Location longitude [deg]: 5.1783 Location altitude [m]: 20 Local noon date: 20241201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0740 305.2147 305.3554 305.4961 305.6368 305.7774 305.9181 306.0587 306.1993 306.3400 306.4806 306.6211 306.7617 306.9023 307.0428 307.1834 307.3239 307.4644 307.6049 307.7454 307.8859 308.0264 308.1668 308.3073 308.4477 308.5881 308.7285 308.8689 309.0093 309.1497 309.2900 309.4304 309.5707 309.7110 309.8513 309.9916 310.1319 310.2722 310.4125 310.5527 310.6930 310.8332 310.9734 311.1136 311.2538 311.3940 311.5341 311.6743 311.8144 311.9546 312.0947 312.2348 312.3749 312.5150 312.6550 312.7951 312.9351 313.0752 313.2152 313.3552 313.4952 313.6352 313.7752 313.9151 314.0551 314.1950 314.3349 314.4748 314.6147 314.7546 314.8945 315.0344 315.1742 315.3141 315.4539 315.5937 315.7335 315.8733 316.0131 316.1528 316.2926 316.4323 316.5721 316.7118 316.8515 316.9912 317.1308 317.2705 317.4102 317.5498 317.6894 317.8291 317.9687 318.1083 318.2478 318.3874 318.5270 318.6665 318.8061 318.9456 319.0851 319.2246 319.3641 319.5035 319.6430 319.7824 319.9219 320.0613 320.2007 320.3401 320.4795 320.6189 320.7582 320.8976 321.0369 321.1763 321.3156 321.4549 321.5942 321.7334 321.8727 322.0120 322.1512 322.2904 322.4296 322.5688 322.7080 322.8472 322.9864 323.1255 323.2647 323.4038 323.5429 323.6820 323.8211 323.9602 324.0993 324.2383 324.3774 324.5164 324.6554 324.7944 324.9334 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241201T082241.2Z 9101.349088 74 1 53.48 2 84.35 137.49 89.61 139.35 0.00 1 0.00 1 0 25 7.412e-01 4.825e-02 3.067e-01 1.492e-02 9.342479e-01 8.823344e-03 1.124055e-02 -6.000000e+00 4.396841e-01 220.51 -2.00 3.84 -2.00 322.08 0.00e+00 -8.468633e-03 4.144490e-03 7.002503e-03 -6.000000e+00 2.096573e-02 269.92 -2.00 20.00 -2.00 321.68 0.00e+00 8.972 0.016 302.00 328.00 3 6.9497e-01 2.9718e-02 1.1336e-01 -6.0000e+00 1.0851e+00 1.7130e+00 3.5352e-02 8.1090e-02 -6.0000e+00 1.1976e+00 -2.0558e+00 2.6771e-02 2.9501e-02 -6.0000e+00 6.9760e-01 7.7798e-01 1.4458e-02 1.3200e-02 -6.0000e+00 2.9789e-01 1.3359e-05 -3.6336e-04 4.1164e-04 1.2479e-04 -6.0000e+00 2.1455e-02 9.5579e-02 12 9 8 11 32 0 21.28 23.61 0.81 0.09558 0.09285 24 3 1 5 0 2228.130 32.25 19.58 23.61 7.83 4.7 767.33 155086 28078 181234 900000 900000 -17285 -83447 15118 900000 135579 23320 131928 900000 94985 141274 900000 38501 900000 -5151 127649 122203 -55608 900000 900000 900000 144224 -483 -15979 75610 73628 91434 13727 900000 900000 394393 26648 900000 900000 65004 900000 111769 900000 174935 230149 900000 -1481 900000 -25852 146002 900000 183151 28106 900000 133717 900000 900000 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-3559 -2783 -6814 -5168 -5368 6731 1367 -690 -429 -7772 -9389 -8794 218 -1282 -4262 -3623 -3019 -5494 -2065 -198 8536 -2583 97 -2098 4150 3890 2771 -12534 1794 3352 5943 3465 11466 -6420 5370 8022 -2604 1682 4248 6833 -2362 2937 -7105 -2028 3573 504 -2570 3993 -5369 3136 -6193 900000 SS 20241201T083326.8Z 9101.356561 77 1 54.49 2 83.26 139.75 88.60 141.44 0.00 1 0.00 1 0 25 5.723e-01 2.623e-02 2.287e-01 5.632e-03 8.434625e-01 3.032982e-03 1.058569e-02 -6.000000e+00 3.199754e-01 220.51 -2.00 3.84 -2.00 321.70 0.00e+00 5.859890e-03 1.466716e-03 4.725460e-03 -6.000000e+00 1.423717e-02 269.92 -2.00 20.00 -2.00 321.32 0.00e+00 7.781 0.010 302.00 328.00 3 6.7828e-01 1.0094e-02 9.2695e-02 -6.0000e+00 7.8759e-01 7.8380e-01 1.3952e-02 5.2593e-02 -6.0000e+00 8.6152e-01 -1.0714e+00 1.4575e-02 3.0259e-02 -6.0000e+00 5.0931e-01 4.3951e-01 7.0218e-03 1.1344e-02 -6.0000e+00 2.2038e-01 5.5483e-05 -9.6902e-05 1.4603e-04 1.9313e-04 -6.0000e+00 1.5092e-02 9.6712e-02 12 8 8 10 0 0 64.52 23.63 0.59 0.09671 0.09598 62 7 1 5 0 878.840 32.25 20.33 23.63 8.08 4.7 768.49 -120967 -138991 -53880 -65977 900000 -188806 -219891 -166510 900000 137708 -70211 -96898 144763 52226 1949 900000 -62304 263413 -38482 -19345 -40423 -65059 207622 53670 47031 46612 -56381 -89027 -28790 -21155 58317 7564 47308 74062 -2530 5030 23464 58097 40124 97243 31712 91337 61811 37334 33036 8622 74101 -5504 16214 79802 33784 21993 60261 58588 52272 95391 7016 26298 997 2573 13904 22080 13113 6870 17523 9911 26337 8473 5701 4769 8354 16326 4099 8040 125 -4357 -9394 15830 2482 7342 -4520 7167 1575 -438 5325 852 -1578 -3716 2885 -549 2491 -3941 -3968 -5378 -4466 -3024 -416 -75 -840 34 -3420 -5302 -3808 -3503 -2570 -3698 -2718 -2297 -2191 -877 -605 2296 -984 -354 -793 199 355 403 -1714 1751 2139 2337 2447 4463 179 1628 2470 404 817 1439 1331 -165 794 -717 -416 375 246 -1081 610 -1216 -630 -1595 900000 -2897 -4161 -645 -757 900000 -6594 -10861 -5068 900000 756 -911 -2079 795 417 31 900000 -2300 1446 -1190 -483 -1170 -2370 1139 643 610 605 -1941 -4042 -761 -633 960 242 1220 1382 -94 182 798 1658 1630 2508 1671 2757 2544 1947 1813 615 2847 -495 1255 3635 2744 2197 4465 4695 4590 5549 974 2858 133 337 1763 2957 2231 1369 3135 1909 4481 1869 1493 1411 2499 4462 1183 2012 30 -1002 -2305 3397 741 2506 -2032 3233 800 -219 2684 471 -920 -2229 1576 -319 1315 -2158 -2250 -3188 -3120 -2468 -390 -79 -930 36 -3359 -4675 -3143 -3076 -2385 -3656 -2885 -2694 -2697 -1231 -938 3604 -1589 -549 -1183 293 545 654 -2748 2922 3381 3530 3584 6181 252 2192 3360 644 1401 2780 2834 -356 1799 -1775 -1021 937 623 -2797 1601 -3019 -1444 -3464 900000 SS 20241201T084526.9Z 9101.364895 80 1 54.38 2 82.10 142.30 87.54 143.80 0.00 1 0.00 1 0 17 6.002e-01 1.563e-02 1.635e-01 2.891e-03 7.729138e-01 1.511901e-03 9.612725e-03 -6.000000e+00 3.334151e-01 220.51 -2.00 3.84 -2.00 321.23 0.00e+00 4.988941e-03 6.814049e-04 3.264115e-03 -6.000000e+00 1.454275e-02 269.92 -2.00 20.00 -2.00 320.84 0.00e+00 6.800 0.007 302.00 328.00 3 6.7623e-01 4.8104e-03 8.0755e-02 -6.0000e+00 8.1828e-01 2.7353e-01 6.9507e-03 4.6268e-02 -6.0000e+00 8.9369e-01 -3.6950e-01 7.9520e-03 2.9127e-02 -6.0000e+00 5.2961e-01 1.4864e-01 3.8423e-03 1.2377e-02 -6.0000e+00 2.3021e-01 1.6004e-04 6.0219e-04 7.4502e-05 1.5306e-04 -6.0000e+00 1.5797e-02 9.6238e-02 12 8 8 10 0 0 32.19 23.67 0.44 0.09624 0.10076 115 12 1 5 0 472.830 32.25 19.56 23.67 8.39 4.7 771.63 -162723 -223943 -122983 -137877 900000 -272142 -286182 -206755 -107369 -115026 -207269 -93299 -73129 -69676 -34991 123915 -74964 108053 -89686 -59818 -62866 -106545 17861 -37775 44203 25706 -52806 -71495 -43892 -43326 13745 -25781 60140 16476 12519 -23957 634 1889 5981 16139 14309 24236 13317 15492 10178 3504 11581 -5869 2950 16205 14877 6328 15585 12501 18621 23223 2903 10325 -1163 254 6574 10491 8057 3687 6456 6327 6662 2125 3093 2426 1528 3999 1591 1874 -1545 -1617 -3532 -1650 -2108 1897 -1980 -375 -1006 -1723 120 -500 -500 -222 2002 -379 421 -2247 -2138 -2899 -1874 -1388 701 684 139 -225 -1648 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