File name: Pandora39s1_DearbornMI_20210812_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T203802.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20210812_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20210812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210812T141914.8Z 7894.596699 153 1 6.58 2 50.56 107.58 97.33 84.54 0.00 1 0.00 1 0 17 1.091e-02 7.377e-03 8.804e-03 4.719e-03 2.020336e-01 2.463228e-03 2.424717e-03 -6.000000e+00 6.436466e-03 231.91 -2.00 3.54 -2.00 315.95 0.00e+00 8.938328e-04 2.585091e-04 4.213715e-05 -6.000000e+00 2.858339e-04 288.38 -2.00 20.00 -2.00 315.18 0.00e+00 1.571 0.000 302.00 328.00 3 5.1179e+00 6.4259e-03 1.8755e-02 -6.0000e+00 1.6117e-02 -2.0205e-02 7.1429e-03 1.0632e-02 -6.0000e+00 1.7395e-02 8.2561e-03 4.1001e-03 5.1200e-03 -6.0000e+00 1.0361e-02 -6.3623e-03 1.8716e-03 1.5197e-03 -6.0000e+00 4.4049e-03 5.5097e-04 7.8667e-04 1.3903e-04 1.7957e-05 -6.0000e+00 3.0822e-04 2.3430e-03 9.8008e-06 12 9 1 12 1 1 999.00 22.36 0.32 0.00234 0.00825 2 5 1 5 0 2133.600 26.32 20.00 22.36 29.50 5.1 998.56 -2218 1765 -2798 -393 -1126 -1985 469 -389 1764 -3575 -1608 -4585 -182 -1021 1839 581 -49 3275 -1482 -743 21 969 -295 511 -275 139 716 788 -533 639 2026 1609 256 -177 -1273 -1323 -1175 -2158 543 -730 -374 224 -280 576 -1273 -274 -1330 925 -1170 183 297 453 1827 1003 940 271 1281 -414 676 10 1265 1431 1444 1330 -321 422 -800 -852 1211 358 -15 235 -134 1087 1032 -417 -114 -2321 468 -1498 -1352 -882 -2204 -1251 -1164 -502 -217 -229 449 1 255 808 -1134 129 906 -931 347 750 67 -1129 43 -379 -1482 676 -115 -910 -508 -402 79 397 656 569 108 -70 247 84 462 -164 752 257 -321 217 679 548 -391 688 214 665 156 394 241 -50 -259 -26 691 62 -357 -28 291 -337 -92 -501 -1010 -509 412 -676 -84 -227 -398 95 -88 427 -933 -404 -1238 -51 -324 612 210 -18 1223 -580 -297 9 381 -121 217 -122 63 318 325 -216 254 837 687 118 -82 -557 -581 -552 -1157 327 -482 -264 159 -205 420 -943 -199 -955 646 -813 126 215 338 1411 796 764 226 1069 -340 555 8 1047 1267 1342 1267 -304 374 -683 -728 1047 333 -15 238 -136 1073 973 -378 -96 -1888 384 -1360 -1300 -904 -2380 -1372 -1336 -600 -267 -285 558 2 301 886 -1185 130 949 -1037 413 938 87 -1464 54 -447 -1716 787 -142 -1158 -674 -546 109 566 960 842 157 -97 327 106 574 -213 1015 358 -457 307 955 757 -527 891 271 829 201 525 330 -70 -366 -37 1011 94 -554 -45 465 -535 -144 -763 -1539 SS 20210812T142901.3Z 7894.603487 156 1 6.76 2 48.85 109.71 95.61 86.18 0.00 1 0.00 1 0 17 1.016e-02 7.403e-03 5.934e-03 3.327e-03 2.020771e-01 1.740674e-03 2.447093e-03 -6.000000e+00 5.993298e-03 231.91 -2.00 3.54 -2.00 315.80 0.00e+00 2.203796e-04 1.760613e-04 6.398702e-05 -6.000000e+00 2.662619e-04 288.38 -2.00 20.00 -2.00 315.04 0.00e+00 1.517 0.000 302.00 328.00 3 4.7020e+00 4.5314e-03 1.8347e-02 -6.0000e+00 1.5007e-02 -8.3998e-03 5.0345e-03 1.0611e-02 -6.0000e+00 1.6200e-02 -2.8430e-03 2.8850e-03 5.1410e-03 -6.0000e+00 9.6488e-03 -3.8249e-03 1.3075e-03 1.4090e-03 -6.0000e+00 4.1003e-03 8.8082e-04 2.5785e-04 9.7734e-05 1.8260e-05 -6.0000e+00 2.8714e-04 5.0798e-03 9.0790e-06 12 9 1 12 1 1 99.76 22.36 0.28 0.00508 0.00702 4 8 1 5 0 1316.760 26.32 20.00 22.36 30.12 5.1 1002.74 697 -1547 -1597 -2931 -1071 1793 -1334 2833 -826 -1349 -3158 599 -2397 -625 908 500 1239 572 1449 39 192 80 1560 256 276 1199 119 775 -958 2229 614 952 939 -708 -2733 -1442 -1365 -1712 -1 -828 -1356 -1204 -6 -844 182 -468 -576 -465 -1302 1060 123 787 1402 652 51 1397 1565 75 1089 116 1634 715 1274 1170 -238 520 -375 -61 18 957 290 450 -229 255 90 -774 -104 -1116 481 -1197 -784 -1442 -2913 -1920 -614 -850 -2 21 355 834 278 678 -284 480 754 221 454 1506 207 -847 -100 -1170 -663 -258 -382 -1239 -775 -459 -398 764 192 426 359 90 57 152 65 319 804 250 -358 -112 570 75 816 656 -81 572 810 -152 6 -279 -624 -16 358 120 -268 717 -141 -508 -169 -309 -529 167 -399 -408 -688 -231 371 -295 668 -220 -371 -867 165 -726 -209 322 190 480 230 575 16 80 33 656 114 128 566 56 335 -407 909 257 422 443 -339 -1250 -653 -660 -937 -1 -559 -991 -885 -4 -635 135 -346 -427 -333 -916 753 90 589 1095 522 42 1157 1311 64 896 97 1386 638 1183 1111 -225 471 -326 -52 16 903 293 460 -236 258 88 -701 -87 -919 404 -1074 -761 -1468 -3125 -2139 -706 -1026 -3 26 442 1019 323 751 -298 490 779 245 529 1868 268 -1095 -124 -1394 -764 -304 -466 -1580 -1007 -622 -551 1080 279 626 520 125 75 192 81 412 1057 347 -506 -158 798 103 1083 849 -100 713 1031 -202 9 -386 -879 -23 520 180 -411 1115 -225 -798 -262 -466 -795 SS 20210812T143507.2Z 7894.607723 160 1 40.08 2 47.80 111.09 94.54 87.19 0.00 1 0.00 1 0 17 8.473e-03 6.140e-03 1.697e-03 8.459e-04 1.948795e-01 4.409803e-04 2.355236e-03 -6.000000e+00 4.996682e-03 231.91 -2.00 3.54 -2.00 316.23 0.00e+00 2.490157e-04 4.927075e-05 7.518443e-05 -6.000000e+00 2.220130e-04 288.38 -2.00 20.00 -2.00 315.43 0.00e+00 1.486 0.000 302.00 328.00 3 3.7712e+00 1.1547e-03 1.7882e-02 -6.0000e+00 1.2511e-02 -1.7301e-02 1.2861e-03 1.0256e-02 -6.0000e+00 1.3506e-02 1.0277e-03 7.4131e-04 4.9658e-03 -6.0000e+00 8.0444e-03 -4.2897e-03 3.4159e-04 1.3628e-03 -6.0000e+00 3.4183e-03 2.3390e-03 2.5688e-04 2.5047e-05 1.7155e-05 -6.0000e+00 2.3943e-04 5.0915e-03 -1.2028e-05 12 1 1 12 1 1 99.37 22.35 0.34 0.00509 0.00702 72 20 1 5 0 546.670 26.32 20.01 22.35 30.51 5.1 1005.34 -1081 -548 -1054 -3306 -1812 -1295 -690 689 -102 -1441 -1497 -491 -1032 122 147 -333 454 403 820 960 221 1057 1478 588 516 829 -175 76 209 1309 1408 1266 1327 -1281 -2328 -1425 -2096 -1227 -442 -800 -1134 -585 -499 -865 -235 -495 -428 -324 -641 284 713 361 908 1066 617 1169 699 358 484 488 1090 1350 1755 1418 -126 -307 -62 -571 793 345 140 468 154 632 74 -337 -499 -807 -129 -1043 -1203 -1227 -2202 -1559 -812 -696 -214 145 407 265 201 424 -246 412 400 24 457 784 35 -456 -263 -852 -593 220 -437 -1178 -545 -616 -287 594 416 345 275 111 -83 105 223 217 503 251 -257 55 367 204 488 669 -224 897 658 77 210 -268 -231 -53 251 15 -156 491 -57 -235 -132 -494 -765 -228 -121 -232 -673 -327 -230 -131 143 -23 -341 -348 -117 -275 36 48 -108 149 137 285 343 80 378 541 228 208 342 -71 29 80 492 553 484 539 -532 -914 -557 -911 -616 -262 -503 -770 -409 -358 -624 -167 -351 -295 -215 -417 183 481 259 680 834 497 951 579 296 393 397 912 1120 1559 1324 -117 -261 -52 -474 688 314 139 482 159 626 69 -305 -409 -628 -103 -936 -1118 -1251 -2413 -1662 -921 -845 -273 178 502 336 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