File name: Pandora39s1_DearbornMI_20210815_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T204141.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20210815_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20210815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210815T111406.9Z 7897.468135 61 1 26.77 2 84.85 75.88 154.61 1.92 0.00 1 0.00 1 0 25 7.761e-01 1.145e-01 5.514e-01 7.913e-02 9.212772e-01 5.021571e-02 1.021075e-02 -6.000000e+00 4.839481e-01 231.80 -2.00 3.54 -2.00 322.15 0.00e+00 -3.417695e-02 1.906261e-02 9.105642e-03 -6.000000e+00 2.847089e-02 288.44 -2.00 20.00 -2.00 321.53 0.00e+00 9.584 0.017 302.00 328.00 3 1.2613e+00 1.7700e-01 1.3340e-01 -6.0000e+00 1.2085e+00 1.7891e+00 2.1103e-01 1.3118e-01 -6.0000e+00 1.3113e+00 -1.9079e+00 1.2181e-01 2.6554e-02 -6.0000e+00 7.7762e-01 5.9391e-01 6.7518e-02 3.0523e-02 -6.0000e+00 3.4025e-01 4.7198e-06 6.8756e-03 2.5141e-03 4.1609e-04 -6.0000e+00 2.4969e-02 5.3975e-04 1.4706e-04 12 9 9 12 1 1 -50.60 22.32 1.25 0.00054 0.05221 6 3 1 5 0 3799.540 26.32 19.99 22.32 24.31 5.2 967.33 -52401 900000 100371 900000 900000 7713 900000 74099 900000 -65304 900000 900000 244732 900000 319047 900000 -4790 119826 10322 900000 -70405 900000 2297 900000 900000 147951 900000 -18221 900000 -84595 900000 28534 900000 41265 -20949 -5738 -46302 900000 900000 900000 -13425 213285 900000 900000 235356 -2810 900000 -72330 900000 21269 900000 -65019 900000 61421 900000 78641 -44807 50938 40229 900000 14565 36697 75036 900000 53914 -19448 277622 28700 188024 26715 100677 -15829 900000 11454 58902 20547 203120 73514 13250 168143 42775 84134 13328 99255 50838 4171 64659 23159 74368 -5756 128545 3259 -3639 35805 26827 16238 -8265 23873 -10144 29827 -14352 1590 -33780 6119 -15266 -23620 -22482 -6489 34493 -17234 18710 -2729 1137 -2032 4620 -3495 3954 3835 -18634 18872 -8543 15142 5588 19285 1583 17757 -590 -9386 11252 3748 7676 -5176 3255 2002 1027 1511 -7011 4560 -6813 6662 -433 1462 -3305 -6693 900000 7692 900000 900000 591 900000 5679 900000 -10248 900000 900000 18756 900000 24451 900000 -437 9183 791 900000 -10278 900000 202 900000 900000 11339 900000 -1815 900000 -13275 900000 2187 900000 3163 -1927 -462 -6387 900000 900000 900000 -2521 16346 900000 900000 18037 -323 900000 -15798 900000 2038 900000 -17085 900000 5649 900000 6931 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5.9078e-02 3.2415e-02 -6.0000e+00 6.8542e-01 2.0036e-01 2.6006e-02 1.5053e-02 -6.0000e+00 2.9533e-01 4.6471e-05 -1.2756e-04 4.5328e-04 2.4794e-04 -6.0000e+00 2.0569e-02 4.2383e-03 4.9460e-05 12 8 8 10 0 0 94.85 22.32 0.60 0.00424 0.00328 72 16 1 5 0 684.290 26.32 19.99 22.32 25.29 5.2 974.05 900000 900000 900000 -222455 -271531 900000 -49128 900000 -145212 -287129 900000 -220584 -199118 -6779 900000 900000 -139184 -83201 900000 900000 900000 146722 -80089 -24237 -136053 161439 -45668 -109297 166912 900000 30411 161517 -79318 182344 247499 -60797 -30384 4193 -5810 -15804 81047 23704 24957 15871 -35249 -7529 -8353 23445 6087 31037 4401 27975 72535 39609 42916 12604 12674 11172 -7797 12172 20572 7142 10083 38914 16565 -2110 4392 -6450 14032 8379 6518 15546 -4410 23243 -2684 2501 7358 -4469 14242 -3529 -484 -5275 -459 -1827 1826 -2393 2474 236 778 2522 1016 3833 -3527 -1012 -1930 -2559 -2134 -2627 3255 2 -2601 -1032 510 -291 -2699 -4556 -2192 677 45 -1275 -991 377 -741 595 511 -573 1386 -309 1489 -672 -85 -662 1482 1696 174 881 -35 1593 1196 301 459 -284 -896 94 554 -521 -257 1032 -46 -281 -66 -617 -431 900000 900000 900000 -3328 -4062 900000 -735 900000 -2172 -5076 900000 -3300 -2979 -101 900000 900000 -2650 -1245 900000 900000 900000 2195 -1198 -363 -3515 2415 -683 -2229 2497 900000 455 2416 -2804 2728 3702 -1819 -744 86 -158 -559 1334 677 747 540 -2061 -348 -409 893 298 1308 275 1560 2861 2370 2626 1080 1103 972 -795 1010 1651 738 1179 3916 2230 -344 687 -1094 2366 1577 1373 3101 -1050 4267 -529 459 1231 -813 2731 -902 -143 -1894 -174 -749 772 -1122 1156 116 380 1170 448 1558 -1521 -452 -999 -1582 -1559 -2253 2909 2 -2361 -833 366 -206 -2082 -3800 -1899 620 47 -1523 -1237 506 -1032 809 671 -737 1765 -419 2097 -1003 -124 -933 2126 2346 236 1151 -45 2120 1825 495 849 -579 -1969 218 1380 -1391 -704 2834 -128 -753 -166 -1454 -968 SS 20210815T113742.3Z 7897.484517 67 1 29.56 2 80.59 79.74 154.10 14.28 0.00 1 0.00 1 0 17 5.376e-01 8.168e-03 2.561e-01 4.015e-03 7.079260e-01 2.259772e-03 8.177345e-03 -6.000000e+00 3.191463e-01 231.80 -2.00 3.54 -2.00 321.49 0.00e+00 3.280223e-03 1.222083e-03 3.647951e-03 -6.000000e+00 1.490579e-02 288.44 -2.00 20.00 -2.00 320.90 0.00e+00 5.816 0.004 302.00 328.00 3 1.0078e+00 8.3009e-03 7.0547e-02 -6.0000e+00 7.9836e-01 6.3007e-02 1.2040e-02 4.4410e-02 -6.0000e+00 8.6208e-01 -7.9247e-02 1.2221e-02 2.4171e-02 -6.0000e+00 5.1206e-01 1.9029e-02 5.6478e-03 7.5111e-03 -6.0000e+00 2.1779e-01 3.2761e-04 4.6973e-04 1.1724e-04 1.1733e-04 -6.0000e+00 1.5311e-02 2.3370e-03 7.3392e-05 12 9 1 12 9 1 76.28 22.32 0.33 0.00234 0.00587 89 33 1 5 0 326.580 26.32 20.01 22.32 26.21 5.1 978.42 -217574 -3162 -186347 -29045 -232372 900000 -169950 -171515 -131726 -94296 900000 -193926 1440 -162468 260643 -53850 -47102 -50775 -33019 48851 -24227 2674 -77238 52871 -59549 51490 -35300 -22355 -51083 -11309 -28448 -16836 1028 -20583 6848 -9064 6000 -14087 2109 6616 6018 7175 -3237 6027 -3438 1282 5730 3385 -1975 1288 8862 855 12099 -800 5020 759 4705 1235 2507 5011 1386 5715 567 8556 193 4593 1414 3063 3415 -141 2034 137 2607 847 2324 -1369 -15 -2776 -2723 -1337 -1247 -212 -3076 -1215 -1362 -3 -93 483 735 117 604 319 -549 -1593 655 -1013 898 384 -103 -196 -628 -815 -737 1151 -1554 -1267 -1160 -400 -191 682 417 -279 207 -44 279 -156 506 425 319 -173 25 499 588 415 -93 -140 -446 1059 611 -63 -39 -440 -69 -267 204 -501 -110 602 -23 -2 167 -140 -327 -1703 -12 -1326 -114 -2398 900000 -1089 -1282 -825 -443 900000 -2967 6 -3122 1020 -537 -503 -632 -376 287 -276 26 -1649 373 -1271 423 -641 -350 -1091 -185 -678 -431 26 -674 166 -264 171 -592 93 334 345 439 -233 408 -262 96 426 271 -163 113 812 96 1338 -110 698 115 709 192 376 729 219 962 115 1811 47 1055 338 755 936 -46 719 51 944 294 727 -401 -4 -803 -893 -516 -565 -100 -1657 -686 -825 -2 -63 332 504 78 374 186 -315 -958 432 -792 802 397 -117 -224 -680 -803 -663 1010 -1495 -1289 -1248 -460 -241 888 608 -438 328 -68 410 -221 715 627 499 -283 40 780 886 604 -131 -204 -636 1539 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