File name: Pandora39s1_DearbornMI_20210920_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T205541.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20210920_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20210920 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210920T122321.2Z 7933.516218 247 1 48.87 2 78.83 99.11 109.07 276.38 0.00 1 0.00 1 0 17 4.019e-01 1.135e-02 2.722e-01 7.621e-03 6.011852e-01 4.185047e-03 7.083630e-03 -6.000000e+00 2.358106e-01 228.53 -2.00 3.54 -2.00 321.22 0.00e+00 3.497662e-03 2.055544e-03 3.112931e-03 -6.000000e+00 1.089638e-02 285.36 -2.00 20.00 -2.00 320.65 0.00e+00 4.983 0.002 302.00 328.00 3 3.2408e+00 1.4516e-02 5.9817e-02 -6.0000e+00 5.8550e-01 2.6453e-02 1.9708e-02 3.6743e-02 -6.0000e+00 6.3414e-01 -6.9359e-02 1.9102e-02 1.9614e-02 -6.0000e+00 3.7719e-01 1.5606e-02 9.0893e-03 6.0961e-03 -6.0000e+00 1.6190e-01 8.6871e-05 2.6715e-04 2.3279e-04 1.0187e-04 -6.0000e+00 1.1550e-02 2.4550e-03 5.0465e-05 12 8 8 10 0 0 97.95 22.28 0.51 0.00246 0.00446 33 7 1 5 0 1480.730 26.32 20.00 22.28 28.26 6.3 984.51 -144407 900000 -56573 900000 -159596 900000 -184937 -84016 -173793 -73550 -110301 -2405 -99837 -98516 -79588 -81282 84348 -70903 22177 -31260 7324 -27785 66005 35992 -55775 52765 -26563 78443 -44473 67081 -7121 -8928 -17815 -3338 19879 -9199 19401 -14904 29818 -6669 20394 4205 7294 6723 1144 18052 -5373 13814 3687 8225 -2047 8637 9746 -2487 1518 -1327 6175 2693 6430 -3791 9182 3077 1456 7134 -2783 6549 -3839 6487 262 5473 -592 3504 -204 462 -1315 -3829 3675 -446 4186 -102 -1461 -519 -1411 -20 -590 -2078 -1453 1246 -1136 960 -358 2280 1002 -874 1222 -2114 1143 -102 -657 -1513 660 -581 315 -374 -2645 -2193 -1174 -476 -1144 1482 159 395 34 94 261 -406 1044 -509 514 268 -322 634 489 762 -196 996 -440 1048 132 823 332 -735 -474 132 8 -207 -255 393 238 -340 174 -531 -160 -1430 900000 -420 900000 -1976 900000 -3320 -681 -3550 -646 -1365 -18 -1669 -2073 -1724 -2113 627 -2063 299 -697 124 -619 669 535 -2037 748 -773 847 -1514 906 -220 -332 -827 -140 640 -404 721 -932 1458 -557 1452 377 668 637 117 1598 -615 1351 418 957 -294 1240 1398 -438 272 -254 1125 506 1139 -741 1647 649 354 1822 -816 1706 -1099 1731 82 1864 -236 1397 -84 178 -473 -1275 1065 -136 1361 -41 -689 -276 -828 -12 -392 -1495 -1092 939 -879 702 -248 1437 613 -557 844 -1736 1048 -108 -761 -1770 715 -581 287 -343 -2658 -2328 -1303 -562 -1480 2072 248 651 52 150 395 -593 1500 -773 819 448 -546 1035 775 1162 -289 1400 -607 1460 205 1421 587 -1406 -950 278 18 -493 -628 979 599 -835 404 -1176 -341 SS 20210920T122942.2Z 7933.520627 250 1 47.17 2 77.68 100.22 110.17 277.48 0.00 1 0.00 1 0 17 1.776e-01 5.869e-03 1.960e-01 4.005e-03 5.570822e-01 2.156328e-03 6.397463e-03 -6.000000e+00 1.035210e-01 228.53 -2.00 3.54 -2.00 320.89 0.00e+00 1.890774e-03 9.425792e-04 8.047699e-04 -6.000000e+00 4.624145e-03 285.36 -2.00 20.00 -2.00 320.25 0.00e+00 4.550 0.002 302.00 328.00 3 2.7477e+00 7.0051e-03 5.3452e-02 -6.0000e+00 2.5735e-01 -2.3207e-02 9.2404e-03 3.0094e-02 -6.0000e+00 2.7865e-01 -7.7769e-03 8.7965e-03 1.5933e-02 -6.0000e+00 1.6616e-01 -1.0468e-02 4.2983e-03 5.4379e-03 -6.0000e+00 7.1421e-02 2.2523e-04 3.7976e-04 1.2210e-04 6.4222e-05 -6.0000e+00 5.0349e-03 1.9170e-03 8.1128e-05 12 1 1 12 9 1 86.94 22.29 0.29 0.00192 0.00477 59 14 1 5 0 783.140 26.32 20.00 22.29 28.54 6.3 986.20 900000 -83678 -9448 -110403 41216 30434 -15003 -70706 -47259 -22404 -78418 -26762 -24334 18586 -28187 -8674 -22076 -4521 -15251 -25188 -25093 1571 -4408 -7925 -21415 -8039 3932 -9066 -8571 11249 2550 4362 6730 11999 -14062 -7235 -21204 -5564 1597 -3583 961 -1318 2494 -3791 613 -2626 2067 421 3588 4051 1295 3115 427 3253 746 5050 -743 1508 67 -1420 1095 213 1604 607 2451 -1316 2572 -1031 1994 1879 520 1126 -797 262 -548 -425 -606 -801 798 -863 -1846 -57 -1030 -2274 -905 -392 50 710 886 1049 757 1035 -508 358 -564 -22 288 878 -130 -170 -47 -1085 -506 -631 -411 -1495 -536 -759 -503 765 295 281 355 386 -301 291 229 115 280 -258 -616 -123 321 -301 667 664 -73 818 415 -96 65 -57 -223 -64 -34 -45 -419 534 25 -297 155 -94 -143 900000 -772 -44 -1333 161 119 -75 -703 -419 -167 -1086 -257 -285 178 -530 -157 -509 -96 -390 -751 -766 37 -119 -242 -806 -280 123 -312 -292 343 100 179 307 543 -796 -391 -1484 -398 130 -366 105 -157 301 -500 79 -356 272 58 496 596 217 569 87 702 175 1178 -189 374 17 -353 277 60 463 196 802 -434 802 -343 706 763 236 530 -379 117 -227 -159 -229 -305 305 -392 -982 -34 -673 -1599 -673 -310 41 603 753 859 580 737 -351 249 -434 -20 289 992 -161 -211 -55 -1173 -502 -628 -438 -1708 -640 -970 -693 1068 454 454 575 601 -445 408 320 167 432 -420 -1016 -197 496 -452 1022 980 -105 1189 617 -160 119 -109 -453 -136 -76 -101 -974 1258 59 -692 366 -211 -311 SS 20210920T123526.4Z 7933.524611 253 1 48.99 2 76.64 101.24 111.17 278.48 0.00 1 0.00 1 0 17 1.357e-01 5.294e-03 6.350e-02 1.851e-03 5.180827e-01 9.859770e-04 5.978824e-03 -6.000000e+00 7.906285e-02 228.53 -2.00 3.54 -2.00 320.68 0.00e+00 2.611917e-03 4.013795e-04 8.159647e-04 -6.000000e+00 3.509650e-03 285.36 -2.00 20.00 -2.00 320.03 0.00e+00 4.220 0.001 302.00 328.00 3 1.7794e+00 3.1392e-03 4.9580e-02 -6.0000e+00 1.9656e-01 -3.4915e-02 4.0177e-03 2.7777e-02 -6.0000e+00 2.1279e-01 5.5785e-03 3.7006e-03 1.4681e-02 -6.0000e+00 1.2687e-01 -1.4698e-02 1.8326e-03 5.3485e-03 -6.0000e+00 5.4166e-02 8.3979e-04 1.6032e-04 5.6593e-05 6.4464e-05 -6.0000e+00 3.8295e-03 2.3420e-03 4.1956e-05 10 0 0 10 0 0 95.08 22.28 0.31 0.00234 0.00355 216 48 1 5 0 226.780 26.32 20.00 22.28 28.89 6.3 989.43 -35649 -47781 -37639 -53709 -62248 7352 -66123 1352 -47327 -17597 -53059 -21497 -30220 -17662 1444 -22253 3298 -20979 -2908 -444 735 -8867 -8660 -596 -14029 -1758 -12345 7590 -4569 1934 -2813 -2121 1907 -4288 -1994 -10031 -913 -4967 -513 -3440 -318 -2245 -333 1108 -940 1645 -977 3282 -1023 2778 2000 1595 1119 1322 1434 433 1183 -1474 872 -917 1620 1141 1949 3076 386 1632 256 701 466 1629 285 900 200 105 -335 -1167 -77 -2320 501 -1973 -761 -926 -2091 -1391 -978 -74 44 653 625 959 662 904 143 340 296 -394 599 708 115 -602 -237 -950 -404 112 -822 -1211 -857 -605 -482 604 338 248 -3 179 110 95 709 -110 512 -390 -503 9 279 190 219 553 -378 1128 296 -81 -162 -218 -131 -77 122 -257 -51 323 94 -260 123 -157 -124 -277 -474 -353 -562 -663 40 -824 10 -624 -184 -758 -283 -491 -316 26 -592 75 -668 -83 -13 22 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