File name: Pandora39s1_DearbornMI_20211001_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T210335.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20211001_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20211001 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211001T121422.5Z 7944.509982 238 1 49.33 2 82.72 101.36 25.00 135.16 0.00 1 0.00 1 0 17 6.083e-01 2.043e-02 4.324e-01 1.453e-02 8.276476e-01 8.663181e-03 9.641800e-03 -6.000000e+00 3.608322e-01 227.27 -2.00 3.54 -2.00 322.09 0.00e+00 7.887707e-03 5.324506e-03 5.435905e-03 -6.000000e+00 1.788851e-02 284.00 -2.00 20.00 -2.00 321.63 0.00e+00 7.278 0.007 302.00 328.00 3 1.5692e+00 3.5502e-02 8.7221e-02 -6.0000e+00 8.9382e-01 5.3426e-01 5.1533e-02 5.2730e-02 -6.0000e+00 9.7295e-01 -7.4353e-01 5.0524e-02 3.1261e-02 -6.0000e+00 5.7959e-01 2.8779e-01 2.2685e-02 1.2278e-02 -6.0000e+00 2.4887e-01 4.1443e-05 -6.3527e-05 4.3219e-04 2.4289e-04 -6.0000e+00 1.7979e-02 3.2118e-03 8.0605e-05 12 8 8 10 0 0 -18.33 22.25 0.51 0.00321 0.00273 48 11 1 5 0 1027.520 26.21 19.99 22.25 20.69 7.2 943.73 900000 900000 -210213 -120337 -112769 900000 -221640 55813 -232349 -142191 -177168 -129549 900000 -183637 900000 -76290 900000 48194 900000 -77521 -4453 143669 -73014 900000 -119038 900000 900000 -16997 900000 -24211 67159 41099 11710 35188 155252 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1866 -1405 -24 -851 2463 -2175 2453 -1934 14 -1683 855 -1388 -914 956 -3950 -397 -3367 1116 102 986 -2369 -1273 -2201 -1902 2272 -3529 -2097 -821 1975 -1936 -185 -2341 -89 661 -1711 807 -1362 380 -1522 2668 370 -1154 1550 1689 3170 1267 3338 740 2558 -654 -409 -84 -1067 1483 -1012 3135 -1849 1897 256 593 -1387 -347 -537 -3163 SS 20211001T122547.3Z 7944.517909 241 1 49.01 2 80.66 103.35 23.63 140.45 0.00 1 0.00 1 0 17 5.048e-01 8.225e-03 2.827e-01 4.527e-03 6.982993e-01 2.554364e-03 7.929290e-03 -6.000000e+00 2.967678e-01 227.27 -2.00 3.54 -2.00 321.61 0.00e+00 3.718529e-03 1.410488e-03 2.013630e-03 -6.000000e+00 1.360840e-02 284.00 -2.00 20.00 -2.00 321.07 0.00e+00 5.857 0.004 302.00 328.00 3 1.3814e+00 9.5621e-03 6.9027e-02 -6.0000e+00 7.3745e-01 1.7481e-02 1.3988e-02 4.0206e-02 -6.0000e+00 8.0074e-01 -6.1976e-02 1.4687e-02 2.2966e-02 -6.0000e+00 4.7273e-01 1.5095e-02 6.7484e-03 8.5276e-03 -6.0000e+00 2.0192e-01 2.2872e-04 6.9417e-05 1.3693e-04 1.2225e-04 -6.0000e+00 1.4515e-02 2.8614e-03 8.1561e-05 11 8 0 10 0 0 90.70 22.25 0.38 0.00286 0.00338 126 28 1 5 0 388.940 26.21 20.00 22.25 21.98 7.2 951.59 -186235 900000 -86768 -159555 900000 -253428 900000 -218631 900000 -156927 -89592 -161929 -126144 -62455 -82555 1841 -74473 75929 -50717 -44670 -51264 -72713 102821 -32321 133638 -76751 53162 -20667 440 -59172 -16346 -30777 -19934 12032 -9263 34558 -22490 18044 -12865 2713 3694 5749 13013 -4975 7963 -8452 15004 -266 4540 -82 6001 7439 2260 6684 -1355 6322 -1721 8293 -227 4244 3437 1788 7029 3386 4933 -1820 7324 -894 5675 1434 2430 1688 102 2667 -1580 3129 -4189 1185 -4091 -43 -2993 276 -2869 -2797 -604 -917 1400 -441 1687 -122 740 270 -240 -87 -1675 -289 -287 1278 65 434 204 -1515 -652 -1059 -1295 -1814 -257 -267 591 203 266 172 57 210 -479 584 128 770 -541 -42 -536 189 418 405 638 114 -134 381 617 -354 237 -75 -321 -147 -39 83 -265 709 -151 -30 -254 130 -268 -971 900000 -383 -768 900000 -3049 900000 -2367 900000 -1133 -395 -1623 -1163 -401 -828 11 -956 335 -630 -555 -699 -1254 454 -441 589 -1877 399 -290 6 -1424 -315 -827 -560 261 -241 596 -776 499 -598 129 197 325 725 -343 495 -641 933 -20 351 -7 518 714 253 784 -184 832 -253 1101 -32 569 486 287 1227 693 1050 -411 1518 -211 1396 424 785 574 35 838 -473 808 -1100 303 -1250 -15 -1270 130 -1540 -1601 -363 -590 853 -282 1146 -81 458 158 -137 -52 -1132 -206 -239 1208 68 456 203 -1394 -543 -878 -1149 -1716 -253 -283 684 265 387 269 91 323 -710 822 181 1129 -849 -68 -876 297 630 591 892 155 -178 519 937 -616 453 -156 -709 -343 -90 205 -672 1815 -392 -75 -603 312 -621 SS 20211001T123525.4Z 7944.524600 246 1 48.90 2 78.93 105.05 22.59 145.31 0.00 1 0.00 1 0 17 2.571e-01 5.449e-03 1.176e-01 2.022e-03 6.080692e-01 1.095711e-03 6.956911e-03 -6.000000e+00 1.491294e-01 227.27 -2.00 3.54 -2.00 321.14 0.00e+00 3.798226e-03 5.215839e-04 1.457036e-03 -6.000000e+00 6.612772e-03 284.00 -2.00 20.00 -2.00 320.57 0.00e+00 5.023 0.002 302.00 328.00 3 9.5174e-01 3.7228e-03 5.8875e-02 -6.0000e+00 3.6982e-01 -3.1464e-03 5.0784e-03 3.3328e-02 -6.0000e+00 4.0082e-01 -2.0274e-02 5.0676e-03 1.9026e-02 -6.0000e+00 2.3902e-01 -4.1326e-03 2.4260e-03 7.6135e-03 -6.0000e+00 1.0219e-01 8.2339e-04 2.1689e-04 6.0747e-05 9.4530e-05 -6.0000e+00 7.2542e-03 2.5072e-03 6.7786e-05 11 1 0 11 8 0 53.40 22.25 0.27 0.00251 0.00414 292 65 1 5 0 167.290 26.21 20.00 22.25 23.16 7.3 958.47 -94293 -92803 -5083 -99398 -80840 -124149 -35593 -101201 -23849 -91533 -60045 -44588 -53661 -9240 -50225 -24024 -41715 -17368 -29880 -24194 -24732 -16040 -18089 -19171 -14611 -25506 -14421 -33162 -18067 -16768 -6893 -1317 -10872 1096 -11386 -1504 -8934 -1256 -2251 -1249 -1704 -1851 5311 -314 3056 -2305 3482 219 2794 2484 2914 3144 1832 2921 2114 2848 654 1759 -607 1794 1873 1288 4098 2557 1725 516 1492 -25 788 891 901 614 99 562 -499 -475 -2263 -1339 -1579 -1347 -857 -867 -1819 -1504 -560 -659 553 467 742 457 617 1078 -401 306 -708 -172 171 956 19 -62 -97 -1034 -294 78 -728 -1716 -758 -573 -115 421 354 117 181 191 -99 193 397 309 300 -349 -551 156 497 59 408 286 -269 789 526 -226 27 -326 -226 -14 -29 -115 -336 653 -42 -158 34 -168 -9 -537 -600 -14 -697 -443 -1074 -140 -876 -107 -872 -447 -337 -570 -81 -787 -344 -805 -292 -617 -500 -526 -318 -390 -456 -356 -733 -377 -1022 -484 -494 -220 -47 -467 44 -501 -61 -441 -69 -152 -100 -146 -170 480 -31 298 -244 357 24 314 302 394 473 306 525 405 565 136 361 -125 359 392 300 1055 712 505 150 425 -7 258 334 372 265 43 228 -188 -161 -734 -436 -575 -577 -426 -491 -1139 -998 -395 -497 414 360 572 357 449 731 -265 205 -531 -141 162 1025 23 -73 -108 -1063 -275 72 -731 -1848 -854 -690 -150 607 540 189 294 301 -148 287 587 457 470 -577 -915 250 768 88 609 412 -378 1124 796 -386 50 -656 -458 -30 -67 -278 -838 1647 -104 -393 80 -375 -20 SS 20211001T124131.2Z 7944.528833 249 1 48.75 2 77.85 106.14 22.00 148.58 0.00 1 0.00 1 0 25 1.773e-01 4.802e-03 5.995e-02 1.428e-03 5.644601e-01 7.603382e-04 6.428055e-03 -6.000000e+00 1.028391e-01 227.27 -2.00 3.54 -2.00 320.85 0.00e+00 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