File name: Pandora39s1_DearbornMI_20220228_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T214424.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220228_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220228T125349.9Z 8094.537383 64 1 46.40 2 82.85 107.47 78.24 136.72 0.00 1 0.00 1 0 17 6.200e-01 2.790e-02 4.744e-01 2.013e-02 9.188967e-01 1.224856e-02 9.960987e-03 -6.000000e+00 3.708326e-01 225.29 -2.00 3.54 -2.00 322.26 0.00e+00 1.322799e-02 6.947019e-03 5.347760e-03 -6.000000e+00 1.949202e-02 273.98 -2.00 20.00 -2.00 321.87 0.00e+00 7.408 0.008 302.00 328.00 3 1.8303e+00 4.6466e-02 9.9410e-02 -6.0000e+00 9.2563e-01 9.4279e-01 6.2201e-02 8.4056e-02 -6.0000e+00 1.0157e+00 -1.3425e+00 5.9683e-02 2.7350e-02 -6.0000e+00 5.9647e-01 5.6335e-01 2.7738e-02 1.8505e-02 -6.0000e+00 2.5224e-01 2.3873e-05 -2.0171e-04 6.0260e-04 2.0573e-04 -6.0000e+00 1.8695e-02 3.8618e-03 9.8163e-05 12 9 9 12 1 1 97.50 22.27 0.53 0.00386 0.00235 25 6 1 5 0 1777.740 26.32 20.00 22.27 3.38 10.1 926.58 900000 -179191 900000 -190376 -98435 900000 -117231 900000 -98224 900000 -114555 900000 -85777 -34217 104432 900000 900000 900000 900000 -32045 900000 -8936 7980 -31584 900000 8739 900000 900000 -71222 900000 170490 900000 23046 94361 117556 105483 900000 72933 277739 71027 213935 21889 33524 95661 96321 48982 49870 85615 98761 103839 65918 76256 84414 91365 27738 56352 30551 100547 84716 8722 93681 -2353 37847 48645 37380 17398 32352 14114 20053 21244 17245 29549 -1213 17052 -4801 7674 6375 -814 13154 3183 -2448 -368 10511 290 -3054 2653 -1105 2765 -4982 2709 -2761 10029 -7169 -3283 -2830 -6699 1009 -6242 -1210 -3728 3191 -1869 2390 -430 -9135 913 -1418 -1787 -2481 1049 -2430 -287 -2985 644 -1806 -494 -1040 -2086 258 2599 189 2626 4180 167 1715 1807 -88 25 1440 1936 1958 1888 -749 64 -41 101 130 -206 202 -45 944 -1098 -3195 900000 -8554 900000 -8790 -1926 900000 -2293 900000 -1922 900000 -2241 900000 -1751 -669 2043 900000 900000 900000 900000 -899 900000 -175 156 -752 900000 171 900000 900000 -2302 900000 3335 900000 588 1846 2300 2064 900000 1427 5434 1631 4185 931 1312 2127 2141 1708 1782 2258 2547 2650 2747 3178 3518 3808 2171 3499 2341 3849 3603 739 3665 -257 3209 4243 3900 2227 3639 2013 2991 3567 3144 5082 -263 2947 -883 1157 930 -135 2230 700 -680 -116 3290 107 -1235 1071 -483 1188 -2304 1117 -1126 3414 -2878 -1359 -1353 -3836 639 -4997 -1023 -3285 2480 -1373 1503 -270 -6626 635 -1074 -1486 -2339 1104 -3040 -386 -4281 887 -2472 -649 -1389 -2947 375 3808 278 3589 5378 216 2113 2167 -106 32 2072 3233 3710 3795 -1661 152 -104 269 355 -568 554 -119 2273 -2498 -7013 SS 20220228T130418.8Z 8094.544662 67 1 49.01 2 81.01 109.32 76.96 138.72 0.00 1 0.00 1 0 17 6.940e-01 8.231e-03 2.525e-01 3.890e-03 7.914840e-01 2.172178e-03 8.712803e-03 -6.000000e+00 4.001876e-01 225.29 -2.00 3.54 -2.00 321.81 0.00e+00 7.722996e-03 1.145766e-03 1.174073e-03 -6.000000e+00 1.740893e-02 273.98 -2.00 20.00 -2.00 321.38 0.00e+00 6.070 0.004 302.00 328.00 3 7.6137e-01 7.7469e-03 7.3768e-02 -6.0000e+00 9.9351e-01 1.1847e-01 1.2193e-02 4.7308e-02 -6.0000e+00 1.0810e+00 -1.3655e-01 1.4164e-02 2.7280e-02 -6.0000e+00 6.3951e-01 4.2443e-02 6.5046e-03 1.4377e-02 -6.0000e+00 2.7157e-01 3.0638e-04 1.7004e-04 1.1281e-04 1.7441e-04 -6.0000e+00 1.9612e-02 3.6541e-03 5.5015e-05 11 9 0 11 8 0 25.60 22.27 0.30 0.00365 0.00493 191 42 1 5 0 256.580 26.32 20.00 22.27 4.21 10.0 932.28 -289411 -235509 -240861 -102354 -261032 -273878 -238765 -227372 900000 -245866 -170713 -96641 -107400 -182897 -48406 -69121 -66858 -72076 -58592 -10006 -68620 -22120 -74512 -58200 -56696 4349 -42006 -38523 -29567 -31398 -8886 -24506 787 -22840 -32284 -19768 -8786 4861 2667 -5093 -8083 -5970 -6077 -4797 1324 11095 10033 -530 11745 6539 7100 4531 5936 8365 6579 8177 5962 1276 -1247 1595 -319 4358 7009 8360 4099 6037 3252 -880 5550 3865 2894 2944 1855 -99 792 -855 -643 -546 -889 -536 -1441 883 -2993 -1534 -975 -812 16 52 1961 327 844 522 -499 -987 -340 -1354 -450 1169 -29 -134 -488 -741 -400 435 -1541 -1483 -1270 -1056 -468 166 326 -253 18 -175 -131 320 558 295 -28 -95 -282 597 654 381 399 369 -256 1079 786 -175 -64 -263 -45 -9 19 -211 -180 686 -149 -127 -62 -101 -306 -2561 -1439 -1675 -388 -2035 -2481 -1660 -1581 900000 -2487 -899 -367 -520 -2582 -235 -510 -563 -729 -568 -63 -795 -163 -989 -711 -729 34 -505 -446 -330 -423 -122 -485 14 -558 -844 -467 -209 121 79 -194 -358 -281 -306 -248 67 529 509 -32 678 440 514 382 547 826 705 899 687 153 -149 185 -40 580 1057 1424 740 1073 606 -181 1198 977 813 859 537 -27 197 -195 -139 -124 -234 -170 -546 377 -1468 -791 -534 -472 9 31 1191 195 467 274 -260 -544 -212 -958 -372 1101 -30 -142 -487 -669 -325 345 -1324 -1347 -1220 -1096 -536 214 473 -381 28 -276 -198 465 811 448 -45 -150 -464 933 981 553 557 500 -341 1476 1222 -301 -123 -551 -101 -22 48 -545 -478 1829 -400 -327 -157 -239 -695 SS 20220228T131554.1Z 8094.552710 72 1 49.03 2 79.00 111.40 75.60 141.00 0.00 1 0.00 1 0 17 3.629e-01 5.721e-03 1.789e-01 1.893e-03 6.780794e-01 1.022142e-03 7.521572e-03 -6.000000e+00 2.087540e-01 225.29 -2.00 3.54 -2.00 321.32 0.00e+00 3.577706e-03 4.786534e-04 9.329553e-04 -6.000000e+00 8.952192e-03 273.98 -2.00 20.00 -2.00 320.88 0.00e+00 5.056 0.002 302.00 328.00 3 7.5147e-01 3.3778e-03 6.1117e-02 -6.0000e+00 5.1709e-01 3.7781e-02 4.8357e-03 3.7288e-02 -6.0000e+00 5.6226e-01 -3.1588e-02 5.4246e-03 2.1586e-02 -6.0000e+00 3.3379e-01 -1.7761e-03 2.5971e-03 9.2962e-03 -6.0000e+00 1.4199e-01 8.9087e-04 3.1061e-04 5.5877e-05 1.0746e-04 -6.0000e+00 1.0228e-02 3.2739e-03 5.9077e-05 11 1 0 11 8 0 21.95 22.27 0.31 0.00327 0.00561 336 75 1 5 0 145.880 26.32 20.00 22.27 5.02 10.1 937.59 -21898 -182324 -585 -173872 -79263 -180273 44280 -121466 -76634 -82574 -131143 -40881 -109986 -24878 -67494 -13736 -51891 -28305 -2907 -23945 -12931 -46319 1419 -30775 -5601 -34410 -8901 -31341 -9589 -11729 -5512 -2876 -15526 -2866 -7867 2160 -13416 -2386 -1020 1273 4261 -2976 2594 -2832 4537 810 3191 1519 1944 2779 400 3143 1728 4457 -217 3651 789 1125 516 1151 1511 729 3863 2012 3118 1324 2337 294 1428 1276 275 1077 -954 971 -1305 361 -1508 -662 -992 -1580 -432 -1455 -1639 -1971 -737 -935 392 434 931 691 372 1136 -867 493 -310 -289 22 1022 362 -238 99 -788 -211 -143 -545 -1891 -625 -729 -309 498 321 128 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