File name: Pandora39s1_DearbornMI_20220419_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T220252.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220419_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220419T114202.8Z 8144.487532 223 1 49.01 2 80.56 83.32 84.00 230.80 0.00 1 0.00 1 0 25 6.904e-01 4.841e-02 5.510e-01 4.273e-02 9.234198e-01 2.544704e-02 1.123263e-02 -6.000000e+00 4.093888e-01 228.67 -2.00 3.54 -2.00 321.98 0.00e+00 -7.388934e-04 1.217266e-02 9.545527e-03 -6.000000e+00 1.962748e-02 278.86 -2.00 20.00 -2.00 321.52 0.00e+00 5.807 0.004 302.00 328.00 3 3.7806e+00 9.0333e-02 9.0472e-02 -6.0000e+00 1.0200e+00 9.1138e-01 1.1212e-01 7.9956e-02 -6.0000e+00 1.1103e+00 -1.3869e+00 8.3308e-02 3.4396e-02 -6.0000e+00 6.5762e-01 6.0134e-01 4.0924e-02 7.6482e-03 -6.0000e+00 2.7782e-01 1.4279e-05 -3.0186e-03 1.1928e-03 2.2394e-04 -6.0000e+00 2.0321e-02 7.3140e-03 -1.7925e-04 12 8 8 10 0 0 99.96 22.30 0.60 0.00731 -0.01537 57 13 1 5 0 859.730 26.32 20.00 22.30 7.56 10.7 954.57 -4560 -86313 134789 -87440 900000 -201209 60226 106329 -108651 112527 -174641 900000 -2810 900000 -22147 -58150 -29641 900000 900000 -21267 2015 267664 900000 205976 900000 900000 -78366 -121584 900000 900000 -5829 165975 16552 -34525 21415 900000 65766 900000 185561 113215 176153 45175 98591 74411 114842 14893 261219 117871 36287 41055 72847 83449 54068 148417 -7203 58075 25870 79659 70530 27672 45240 2066 26992 13692 88044 24821 37068 38437 29290 13026 -815 -1621 -3914 10013 -6842 62477 58195 2801 7573 3886 34673 -6111 24636 4901 -10125 -9912 1542 1502 3353 -548 -4399 12564 -5280 12736 -2375 997 1433 -4787 -5645 -8512 1144 -982 9834 -8099 -7352 -2402 -5102 -3476 -5447 -4302 -753 1059 -4889 2120 170 4404 84 -1894 -4067 1414 1316 584 3115 4232 4237 2186 5780 2940 2749 1351 184 2874 -452 2270 -2692 1093 976 1342 -1678 -91 43 -3152 -2124 -190 -3589 5604 -3635 900000 -15210 2504 4421 -4517 4678 -11881 900000 -117 900000 -921 -2993 -1232 900000 900000 -884 84 11128 900000 8564 900000 900000 -5275 -11029 900000 900000 -242 6901 688 -2324 890 900000 2734 900000 7715 4707 7324 2536 4099 3094 4775 1032 10860 4901 2338 2601 3937 4510 4068 6171 -1089 4944 3073 5630 5132 2794 3851 281 3420 2148 7321 3706 4974 5375 4982 2849 -224 -463 -1111 2281 -1645 7298 6682 556 1646 1012 8256 -2329 8016 1987 -5069 -5237 756 752 1638 -268 -2088 4974 -2369 5295 -1263 608 1031 -4108 -5426 -8578 993 -785 6576 -6271 -5722 -1885 -4361 -3179 -5680 -5101 -988 1502 -7659 3089 245 5889 118 -2810 -6480 2200 2016 857 4253 5511 5313 2716 6767 3682 3932 2277 342 5709 -995 5205 -6949 2871 2623 3624 -4642 -236 102 -7207 -4513 SS 20220419T121123.6Z 8144.507912 240 1 12.14 2 75.15 88.17 88.24 235.76 0.00 1 0.00 1 0 17 3.320e-01 1.354e-02 3.479e-01 1.294e-02 6.625954e-01 6.976291e-03 7.623964e-03 -6.000000e+00 1.950939e-01 228.67 -2.00 3.54 -2.00 320.69 0.00e+00 3.079007e-03 2.775583e-03 1.588352e-03 -6.000000e+00 8.407356e-03 278.86 -2.00 20.00 -2.00 320.15 0.00e+00 3.824 0.001 302.00 328.00 3 4.3998e+00 2.1463e-02 5.1803e-02 -6.0000e+00 4.8717e-01 1.5900e-01 2.7813e-02 3.5792e-02 -6.0000e+00 5.2907e-01 -1.3224e-01 2.7216e-02 1.9524e-02 -6.0000e+00 3.1264e-01 4.2970e-02 1.3491e-02 6.9143e-03 -6.0000e+00 1.3152e-01 6.5910e-05 -2.8367e-04 3.6619e-04 8.7017e-05 -6.0000e+00 9.4916e-03 5.2482e-03 -1.2062e-04 12 9 9 12 1 1 99.98 22.30 0.32 0.00525 0.00312 3 4 1 5 0 2990.810 26.32 20.00 22.30 7.83 10.7 956.60 -74933 -92470 -194358 39843 -155544 -92684 900000 -64927 -27041 41822 -82415 151000 -18570 -35838 -69712 -19452 21007 -39976 900000 110 44254 463 42195 -50954 66687 -38328 7987 -22584 -21586 8971 -12162 -9467 -9250 -14601 31030 -7089 4567 3508 -10404 8365 -7062 10512 -5602 438 528 2854 8098 -859 -9117 5613 5204 5889 3541 1331 7163 589 -2576 -7935 2963 2646 -877 6514 6510 1942 12691 -822 4163 112 1879 637 -154 891 4562 2090 3672 2191 -2094 -4481 -177 -427 -1910 -2676 -1359 -1561 -756 -2562 399 -214 -170 220 2856 1599 669 14 -565 -462 320 1539 -364 -705 -427 -991 -1812 -862 -2509 -2441 2103 -801 -608 -1220 173 353 -859 1071 -1138 -117 1755 1840 887 639 -1752 -315 860 795 1262 713 641 1489 90 -831 558 -785 706 38 382 279 -575 97 -514 -220 -501 34 -54 -945 -1166 -5393 503 -2698 -1169 900000 -819 -341 528 -1126 1905 -234 -603 -1970 -409 331 -1230 900000 3 698 11 732 -2249 1051 -1740 230 -855 -817 281 -565 -487 -543 -942 1268 -416 268 248 -996 786 -861 1149 -754 57 69 375 1033 -124 -1508 865 900 1125 731 305 1633 149 -687 -2209 718 637 -228 1734 1968 685 4179 -303 1455 42 744 292 -78 463 2240 988 1554 875 -821 -1835 -78 -214 -1135 -1763 -965 -1178 -604 -2212 338 -187 -148 189 2225 1180 480 11 -470 -428 341 1786 -466 -904 -514 -1121 -1886 -883 -2782 -2766 2400 -1007 -807 -1814 272 586 -1453 1719 -1766 -177 2598 2825 1407 1055 -2948 -504 1349 1201 1812 991 889 2104 139 -1410 996 -1522 1377 79 817 631 -1307 223 -1184 -500 -1076 71 -107 SS 20220419T123830.9Z 8144.526746 256 1 48.93 2 70.13 92.74 92.37 240.12 0.00 1 0.00 1 0 17 6.637e-02 5.189e-03 1.015e-02 4.972e-04 5.037004e-01 2.590789e-04 5.862864e-03 -6.000000e+00 3.865828e-02 228.67 -2.00 3.54 -2.00 319.85 0.00e+00 1.591029e-03 7.976995e-05 2.567518e-04 -6.000000e+00 1.670902e-03 278.86 -2.00 20.00 -2.00 319.27 0.00e+00 2.910 0.000 302.00 328.00 3 7.8169e-01 7.4053e-04 3.9177e-02 -6.0000e+00 9.6353e-02 1.7247e-02 8.9139e-04 2.6608e-02 -6.0000e+00 1.0444e-01 -1.2214e-02 7.7521e-04 1.3448e-02 -6.0000e+00 6.2016e-02 -6.5235e-03 4.0267e-04 4.4265e-03 -6.0000e+00 2.6296e-02 7.3311e-03 -2.2661e-04 1.4606e-05 4.8601e-05 -6.0000e+00 1.8731e-03 3.3588e-03 -6.0503e-05 10 0 0 10 0 0 99.78 22.30 0.24 0.00336 0.00166 877 195 1 5 0 55.780 26.32 20.00 22.30 8.38 10.8 961.15 -22379 -17716 -20809 -21830 -25587 -24539 -26366 -20096 -19841 -19585 -17716 -17515 -10415 -9373 -5223 -5510 -4407 -1136 -3004 -99 -3043 -1434 -3004 -2961 -3591 -3197 -4467 -4754 -4403 -3061 -307 -543 252 -3374 -3491 -2977 -3470 -1775 -1556 -1726 -1936 -966 -914 -753 188 -186 -20 -68 -227 650 1074 599 1245 1149 698 1180 698 126 170 682 1126 1455 1928 1958 629 551 811 -117 1241 597 338 594 22 514 62 -148 -290 -850 -239 -881 -1070 -1066 -1996 -1455 -912 -610 -110 257 584 514 661 834 283 605 469 23 395 876 -51 -427 -205 -694 -236 451 -774 -1356 -747 -759 -340 322 157 -13 67 106 5 350 527 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