File name: Pandora39s1_DearbornMI_20220526_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T221531.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220526_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220526 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220526T115831.5Z 8181.498976 145 1 49.42 2 70.75 78.50 51.55 125.35 0.00 1 0.00 1 0 25 9.710e-02 1.936e-02 7.991e-02 5.268e-03 3.886374e-01 2.751003e-03 4.863502e-03 -6.000000e+00 5.709524e-02 231.62 -2.00 3.54 -2.00 319.75 0.00e+00 1.086562e-03 7.991784e-04 1.870474e-03 -6.000000e+00 2.487027e-03 282.93 -2.00 20.00 -2.00 319.05 0.00e+00 2.998 0.000 302.00 328.00 3 4.5896e+00 7.9224e-03 3.6917e-02 -6.0000e+00 1.4312e-01 -4.4615e-02 9.3630e-03 2.3493e-02 -6.0000e+00 1.5476e-01 5.6052e-02 7.3621e-03 1.1027e-02 -6.0000e+00 9.1899e-02 -2.7117e-02 3.8177e-03 2.8780e-03 -6.0000e+00 3.8810e-02 1.7966e-04 -5.0504e-04 1.6323e-04 3.7567e-05 -6.0000e+00 2.7449e-03 7.8573e-03 -3.2970e-04 12 9 8 11 8 0 99.99 22.24 0.27 0.00786 0.00406 60 13 1 5 0 823.530 26.21 19.99 22.24 25.64 11.9 1050.39 -22760 7649 -7908 36827 -14186 56389 -22992 -38757 -29598 -5617 -14504 -14032 41840 -12298 25608 -17867 8005 -1831 -605 -691 -5669 8753 -5333 9794 -4922 9459 -11590 7395 4317 -1692 -93 -6100 5101 -2271 452 -4812 3848 -6779 -4784 -778 -2154 -593 -2924 -1736 -1103 3444 -4870 3245 -4215 -30 2443 -588 -62 -1327 593 -895 2075 -412 1551 2884 1067 3296 1568 3040 -440 272 -730 1256 823 1800 457 303 1541 -310 1414 -1266 691 -323 1087 -686 -1454 -789 -2447 -418 -263 632 499 1525 437 1539 441 1199 1470 924 1931 290 785 360 495 -1244 -979 -1494 -854 1246 -15009 41 142 665 986 1620 616 45 39 -647 122 -639 1307 -450 1081 25 136 757 729 1250 543 900 -644 2230 922 708 102 -681 -8 -96 535 -163 39 73 -173 -608 -340 31 -621 -534 152 -187 541 -308 648 -591 -1325 -1025 -161 -467 -502 1065 -590 1030 -1190 442 -120 -41 -49 -433 587 -435 738 -456 792 -1143 597 349 -153 -9 -692 570 -278 51 -590 488 -1137 -952 -173 -532 -152 -765 -456 -302 909 -1392 856 -1210 -9 742 -192 -21 -500 228 -360 828 -168 608 1118 440 1449 773 1587 -238 138 -359 610 437 1073 301 208 1038 -203 841 -697 358 -166 572 -420 -1020 -613 -2077 -367 -247 631 524 1634 474 1586 426 1061 1215 761 1694 289 879 452 637 -1609 -1235 -1745 -930 1356 -19938 52 187 888 1396 2461 1011 76 66 -1024 179 -924 1842 -648 1631 40 223 1215 1139 1870 808 1277 -890 3020 1361 1094 170 -1196 -15 -181 1058 -343 85 155 -372 -1282 -711 62 -1216 SS 20220526T121327.6Z 8181.509348 151 1 36.50 2 68.03 80.82 49.34 129.12 0.00 1 0.00 1 0 17 2.858e-02 5.475e-03 3.237e-02 3.543e-03 3.593881e-01 1.845772e-03 4.218974e-03 -6.000000e+00 1.683843e-02 231.62 -2.00 3.54 -2.00 319.24 0.00e+00 5.575155e-04 4.526844e-04 2.213622e-04 -6.000000e+00 7.317704e-04 282.93 -2.00 20.00 -2.00 318.52 0.00e+00 2.650 0.000 302.00 328.00 3 4.0073e+00 5.1704e-03 3.2335e-02 -6.0000e+00 4.2213e-02 5.7039e-03 5.9791e-03 1.9097e-02 -6.0000e+00 4.5618e-02 1.8087e-02 4.3189e-03 9.3735e-03 -6.0000e+00 2.7087e-02 -1.6249e-02 2.2450e-03 2.7023e-03 -6.0000e+00 1.1460e-02 4.5730e-04 3.1713e-04 1.0922e-04 3.0991e-05 -6.0000e+00 8.0722e-04 3.2755e-03 2.5908e-05 12 1 1 12 1 1 100.00 22.25 0.36 0.00328 0.00566 138 42 1 5 0 261.330 26.21 20.00 22.25 26.40 11.9 1055.61 8812 -11498 11230 6069 -13802 7841 -9471 7835 4535 2454 -4650 -1528 -1727 -4089 -226 -4108 3600 -610 -1698 -4233 2999 -834 -1370 -1307 -3858 1979 -4479 -3819 -3492 7658 -235 814 730 -628 -2667 -1684 -10 -1860 1344 -991 -2056 -1470 -792 -1191 -447 -251 -1181 1324 -1322 2502 45 130 548 859 990 318 2141 -185 1168 329 1286 783 1355 938 43 -329 591 396 1248 208 -109 1557 104 287 -259 -425 419 -709 373 -800 -837 -991 -1315 -1680 -722 -577 -546 143 387 648 246 481 59 565 110 -226 720 545 45 -657 242 -1061 225 156 -346 -962 -730 -486 -462 550 130 114 -120 479 -221 -126 411 160 460 -66 -324 -95 227 20 668 485 -318 1299 560 84 -177 -542 -306 -97 113 -266 -37 871 120 -287 -21 -247 -435 264 -439 365 193 -492 227 -356 281 186 103 -212 -74 -98 -279 -17 -345 299 -56 -166 -442 296 -86 -149 -152 -487 245 -589 -472 -412 834 -31 116 114 -101 -416 -263 -2 -383 309 -272 -624 -466 -258 -395 -148 -83 -391 424 -436 819 16 51 227 377 452 150 1012 -89 544 154 620 411 775 578 27 -193 327 219 737 140 -80 1184 80 211 -177 -262 235 -390 216 -532 -631 -833 -1141 -1541 -703 -600 -597 160 434 698 247 463 53 496 104 -227 803 679 60 -877 302 -1237 243 171 -410 -1217 -966 -677 -682 864 210 190 -195 763 -329 -177 567 230 699 -108 -540 -155 361 31 970 674 -426 1715 796 130 -293 -939 -543 -171 211 -527 -76 1798 251 -592 -42 -470 -805 SS 20220526T142407.5Z 8181.600087 233 1 0.75 2 44.04 103.78 37.11 173.19 0.00 1 0.00 1 0 17 1.099e-02 8.430e-03 7.634e-03 5.272e-03 1.901925e-01 2.784026e-03 2.311067e-03 -6.000000e+00 6.477305e-03 231.63 -2.00 3.54 -2.00 314.91 0.00e+00 3.376034e-04 2.313090e-04 1.990200e-05 -6.000000e+00 2.813716e-04 282.94 -2.00 20.00 -2.00 314.32 0.00e+00 1.389 0.000 302.00 328.00 3 3.0104e+00 7.1844e-03 1.6949e-02 -6.0000e+00 1.6239e-02 1.8817e-02 7.9409e-03 9.9555e-03 -6.0000e+00 1.7546e-02 -2.6430e-03 4.5381e-03 4.8315e-03 -6.0000e+00 1.0418e-02 -2.0053e-03 1.9907e-03 1.3484e-03 -6.0000e+00 4.4101e-03 5.4545e-03 4.3706e-04 1.5347e-04 1.8443e-05 -6.0000e+00 3.1034e-04 2.9543e-05 2.4509e-05 12 9 1 12 1 1 999.00 22.25 0.25 0.00003 0.00331 1 38 1 5 0 289.360 26.32 20.00 22.25 29.18 12.1 1072.04 -32 -1546 -729 -3373 495 -2339 -967 2696 113 1267 -2566 762 -3019 901 1693 -1059 583 -474 1562 -1192 3111 811 2969 251 -51 828 -972 1171 255 1304 -447 2540 -68 -1053 -2287 -513 -867 -729 -492 -1660 -1039 -200 9 -1959 -361 -905 -1099 -467 -349 906 -643 1439 964 1429 1085 1319 1084 -316 636 65 1346 294 1949 1362 -371 116 290 -146 451 -9 -651 480 144 681 718 -739 -317 -1366 -360 -1017 -299 -872 -2267 -1838 -1196 -915 -690 161 140 260 1215 633 314 673 1233 381 767 23 -258 -766 -274 -1428 -80 148 -882 -1057 179 -242 -511 996 380 148 -432 1036 -722 604 788 328 864 -348 -177 217 571 -305 -451 336 -886 1731 501 475 -340 503 -296 473 -16 -169 -77 315 -601 114 769 -513 -1314 -11 -544 -260 -1118 146 -697 -304 909 41 453 -932 277 -1219 381 766 -511 284 -239 795 -624 1569 415 1527 135 -29 471 -553 622 131 651 -231 1345 -38 -597 -1259 -277 -503 -455 -347 -1270 -833 -161 8 -1616 -297 -743 -897 -366 -271 693 -512 1163 803 1239 948 1166 972 -280 560 58 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