File name: Pandora39s1_DearbornMI_20220620_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T223058.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220620_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220620 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220620T160250.5Z 8206.668640 366 1 48.93 2 26.75 127.66 81.32 251.79 0.00 1 0.00 1 0 17 7.678e-03 6.125e-03 5.466e-04 3.275e-04 1.592675e-01 1.721402e-04 1.938890e-03 -6.000000e+00 4.542611e-03 232.86 -2.00 3.54 -2.00 315.60 0.00e+00 2.767317e-04 1.648484e-05 2.990081e-05 -6.000000e+00 1.986932e-04 285.46 -2.00 20.00 -2.00 314.91 0.00e+00 1.119 0.000 302.00 328.00 3 2.3819e+00 4.4864e-04 1.3925e-02 -6.0000e+00 1.1413e-02 -7.4145e-03 4.9719e-04 8.4220e-03 -6.0000e+00 1.2318e-02 -1.1368e-03 2.8392e-04 4.0795e-03 -6.0000e+00 7.3176e-03 -3.5000e-03 1.2658e-04 1.1275e-03 -6.0000e+00 3.0943e-03 1.4249e-02 2.8115e-04 9.6951e-06 1.4669e-05 -6.0000e+00 2.1697e-04 4.6546e-03 -2.2375e-05 10 0 0 10 0 0 99.93 22.20 0.28 0.00465 0.00677 728 162 1 5 0 67.200 26.21 20.01 22.20 29.76 12.4 1051.57 -861 -872 -975 -2575 -1031 -564 -21 938 273 -864 -1095 213 -779 -212 236 -602 209 491 818 946 437 835 1345 448 517 703 -137 -4 545 1633 1177 1552 1190 -1585 -1784 -953 -1705 -832 -384 -942 -1150 -642 -595 -947 -124 -518 -695 -243 -688 431 658 433 924 878 523 961 676 367 635 610 1037 1172 1370 1106 -295 -195 119 -372 1058 376 -31 346 -19 530 1 -181 -189 -560 197 -801 -1206 -1286 -2196 -1447 -823 -712 -249 -14 250 179 202 446 -61 723 654 138 504 804 -55 -552 -185 -779 -305 472 -550 -1228 -597 -594 -296 461 246 145 67 120 -2 320 464 262 603 142 -356 34 306 92 568 631 18 1289 759 224 218 -230 -103 89 231 -97 -262 430 -160 -329 -145 -480 -651 -247 -262 -287 -696 -246 -131 -5 255 81 -264 -326 64 -261 -79 96 -239 84 200 341 404 188 356 584 204 244 339 -65 -2 240 698 524 722 537 -730 -837 -444 -808 -454 -247 -696 -842 -483 -457 -731 -95 -391 -509 -185 -506 313 497 346 707 701 428 792 565 306 519 500 877 1056 1318 1112 -293 -176 99 -299 887 356 -32 370 -20 548 1 -159 -161 -451 162 -679 -1140 -1328 -2429 -1545 -935 -866 -318 -19 330 227 238 476 -64 715 669 154 574 1001 -73 -721 -228 -898 -333 527 -672 -1602 -809 -784 -405 657 367 218 96 160 -3 388 554 325 798 190 -496 48 416 129 749 791 22 1500 926 290 294 -320 -145 129 326 -146 -407 679 -258 -523 -224 -723 -960 SS 20220620T160941.6Z 8206.673398 370 1 49.03 2 25.77 130.43 82.47 252.99 0.00 1 0.00 1 0 17 7.642e-03 6.142e-03 7.086e-04 4.270e-04 1.579315e-01 2.238232e-04 1.917505e-03 -6.000000e+00 4.521021e-03 232.86 -2.00 3.54 -2.00 315.52 0.00e+00 2.977090e-04 2.125788e-05 2.481406e-05 -6.000000e+00 1.977578e-04 285.46 -2.00 20.00 -2.00 314.83 0.00e+00 1.110 0.000 302.00 328.00 3 2.8875e+00 5.8279e-04 1.3800e-02 -6.0000e+00 1.1359e-02 -3.2123e-03 6.4568e-04 8.3414e-03 -6.0000e+00 1.2260e-02 -9.5730e-04 3.6872e-04 4.0326e-03 -6.0000e+00 7.2829e-03 -3.8529e-03 1.6416e-04 1.1135e-03 -6.0000e+00 3.0795e-03 8.6832e-03 2.9599e-04 1.2631e-05 1.4551e-05 -6.0000e+00 2.1595e-04 4.9265e-03 -2.0948e-05 10 0 0 10 0 0 99.97 22.20 0.26 0.00493 0.00715 475 106 1 5 0 103.200 26.21 20.00 22.20 30.21 12.5 1055.56 -941 -770 -1252 -2525 -1073 -585 42 797 559 -914 -845 -100 -612 -234 391 -734 211 421 821 1043 289 854 1203 567 587 654 -141 -91 605 1498 1090 1373 1250 -1604 -1761 -1033 -1817 -747 -407 -837 -1106 -535 -735 -893 -135 -524 -645 -374 -632 301 815 406 952 864 578 1056 659 371 553 660 978 1175 1360 1169 -283 -159 169 -332 1074 443 -22 333 55 495 41 -108 -130 -538 129 -768 -1214 -1264 -2186 -1428 -829 -805 -283 10 296 74 292 416 -6 712 674 100 473 763 -87 -539 -227 -770 -344 482 -579 -1086 -630 -625 -289 439 254 132 112 77 -27 283 460 310 555 158 -457 66 255 102 571 650 42 1360 800 160 240 -228 -133 97 239 -79 -238 429 -192 -302 -153 -456 -667 -268 -229 -366 -674 -253 -135 10 215 164 -276 -248 -30 -202 -85 156 -313 91 185 368 478 134 390 561 277 273 310 -66 -43 262 630 477 628 604 -791 -810 -472 -923 -400 -257 -606 -859 -427 -600 -731 -109 -420 -500 -278 -455 214 600 317 772 730 501 851 539 302 479 573 808 1034 1278 1146 -274 -140 148 -282 951 408 -22 348 58 499 38 -100 -108 -422 104 -687 -1116 -1270 -2351 -1596 -987 -953 -352 12 379 91 333 464 -6 684 670 109 564 923 -112 -683 -270 -927 -393 562 -687 -1373 -828 -857 -411 650 365 191 168 106 -34 359 572 372 712 219 -661 95 360 139 729 788 53 1649 1016 200 314 -306 -181 135 350 -123 -356 654 -299 -463 -228 -710 -1018 SS 20220620T161537.8Z 8206.677521 373 1 49.35 2 24.95 132.97 83.48 254.02 0.00 1 0.00 1 0 17 1.341e-02 7.761e-03 1.069e-02 5.452e-03 1.676708e-01 2.849146e-03 1.990153e-03 -6.000000e+00 7.933410e-03 232.86 -2.00 3.54 -2.00 316.23 0.00e+00 4.899525e-04 3.102567e-04 1.123779e-04 -6.000000e+00 3.470106e-04 285.46 -2.00 20.00 -2.00 315.48 0.00e+00 1.103 0.000 302.00 328.00 3 6.9685e+00 7.4755e-03 1.4011e-02 -6.0000e+00 1.9932e-02 3.5188e-02 8.3080e-03 8.7103e-03 -6.0000e+00 2.1513e-02 -1.5829e-03 4.7720e-03 4.2093e-03 -6.0000e+00 1.2780e-02 -4.7962e-03 2.1793e-03 1.1666e-03 -6.0000e+00 5.4039e-03 1.4237e-04 3.2669e-04 1.6291e-04 1.4291e-05 -6.0000e+00 3.7893e-04 5.0938e-03 -1.1035e-05 11 8 0 10 0 0 99.88 22.20 0.59 0.00509 0.00755 18 4 1 5 0 2741.300 26.21 19.99 22.20 30.74 12.5 1058.91 526 -223 942 -3961 3648 -1402 -5943 -2647 2593 2247 -3082 3226 -3205 674 1730 686 1058 -574 1228 2405 1466 -1677 1513 -1165 1058 -765 250 -2608 -3445 1465 912 425 1653 -2373 -1462 -2077 -1062 -140 641 27 -1676 441 -466 -726 -126 -155 -1147 632 -828 -1418 -869 416 1090 1636 1065 1409 1701 376 23 274 1258 -200 1754 1645 561 -623 -823 -637 668 380 43 1286 -72 1360 177 -805 -215 -1055 -830 -2038 -398 -2383 -1312 -1049 -285 -62 -110 274 1078 322 -88 262 -709 -1333 -419 -656 -475 739 491 -233 -113 -1392 -67 -850 -449 -689 -197 33 -343 1155 131 256 747 447 -957 -296 140 394 426 -404 291 641 767 -49 444 632 -809 702 546 -771 -18 -579 -442 156 301 170 -180 902 53 139 -301 -842 -489 118 -53 216 -860 657 -261 -1238 -591 595 526 -741 780 -873 197 552 234 366 -207 446 885 546 -639 572 -471 433 -325 103 -1064 -1315 524 340 167 679 -1007 -573 -819 -457 -69 357 17 -1170 311 -339 -530 -91 -111 -800 416 -535 -918 -584 291 792 1231 822 1098 1335 297 18 213 1003 -172 1588 1554 521 -534 -678 -507 554 340 42 1289 -73 1313 161 -694 -166 -772 -624 -1715 -366 -2343 -1354 -1130 -325 -75 -142 362 1420 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