File name: Pandora39s1_DearbornMI_20220624_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T223435.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220624_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220624 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220624T111754.9Z 8210.470774 163 1 7.92 2 77.49 69.62 45.38 115.79 0.00 1 0.00 1 0 17 5.105e-01 2.019e-02 3.773e-01 1.444e-02 6.113512e-01 7.960529e-03 7.004515e-03 -6.000000e+00 3.031357e-01 232.87 -2.00 3.54 -2.00 320.75 0.00e+00 3.117048e-03 3.346893e-03 1.801110e-03 -6.000000e+00 1.442203e-02 285.81 -2.00 20.00 -2.00 320.11 0.00e+00 4.487 0.002 302.00 328.00 3 3.7321e+00 2.5563e-02 5.5385e-02 -6.0000e+00 7.6047e-01 6.2371e-02 3.3544e-02 3.4038e-02 -6.0000e+00 8.2127e-01 -1.2552e-01 3.1257e-02 1.8621e-02 -6.0000e+00 4.8794e-01 5.0522e-02 1.5184e-02 6.6541e-03 -6.0000e+00 2.1095e-01 7.9909e-05 6.6430e-04 4.2627e-04 8.3754e-05 -6.0000e+00 1.4594e-02 5.0106e-03 1.1787e-04 12 9 9 12 1 1 999.00 22.25 0.67 0.00501 0.01000 2 4 1 5 0 2579.710 26.21 20.00 22.25 26.87 12.2 1029.04 900000 900000 900000 200118 900000 -239259 -3330 147662 33336 -98692 -144530 -90201 -24477 26411 -68336 14947 -24273 131217 -42380 143440 900000 112694 221745 81631 140817 -66046 7775 53088 4808 23047 -9644 12959 16961 91669 3402 71619 -5697 144867 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-73 2297 -1893 -1085 1542 -1077 1068 -2644 483 -212 2721 833 -1393 366 -1710 971 -2255 1378 1577 645 246 791 -1826 410 1236 -376 3074 -953 2165 -564 -840 582 -1527 -537 -1638 1357 -1546 5198 -45 132 524 941 -983 -164 -2413 -2909 1301 -1055 2197 1708 2690 -1945 -102 -2170 576 -426 SS 20220624T112347.0Z 8210.474850 166 1 49.00 2 76.47 70.52 44.42 117.22 0.00 1 0.00 1 0 17 2.771e-01 9.346e-03 2.582e-01 8.065e-03 5.831856e-01 4.547060e-03 6.700327e-03 -6.000000e+00 1.656125e-01 232.87 -2.00 3.54 -2.00 321.03 0.00e+00 2.542502e-03 2.067427e-03 2.175201e-03 -6.000000e+00 8.948534e-03 285.81 -2.00 20.00 -2.00 320.41 0.00e+00 4.172 0.001 302.00 328.00 3 3.8043e+00 1.5233e-02 5.2451e-02 -6.0000e+00 4.2063e-01 -3.7612e-02 2.0365e-02 3.3592e-02 -6.0000e+00 4.5641e-01 3.2834e-02 1.9807e-02 1.8219e-02 -6.0000e+00 2.6606e-01 -2.3243e-02 9.5573e-03 6.0626e-03 -6.0000e+00 1.1536e-01 1.0404e-04 6.4645e-04 2.5311e-04 8.3067e-05 -6.0000e+00 8.1557e-03 8.1936e-03 6.6105e-05 12 8 8 10 0 0 99.88 22.25 0.59 0.00819 0.01305 70 16 1 5 0 699.960 26.21 20.00 22.25 27.29 12.3 1031.48 900000 900000 -109719 900000 -67189 -150469 -44421 900000 900000 900000 900000 900000 -58392 -43769 -38633 -46786 163307 59039 39332 -13234 -2593 -58684 68078 39079 19067 11556 11053 3182 -26875 30382 -33678 9697 7329 16443 -22996 30220 1562 -13076 22958 -7376 4316 -9501 6330 3982 1243 -4182 1106 606 867 11738 -5089 6187 -2809 2719 -1207 -156 1406 97 -2256 -55 6333 2519 4687 1069 5661 1035 1830 697 917 -274 -397 3850 -3286 -248 -2735 573 -415 -1854 -1453 -2820 1022 -970 -1844 -937 352 -443 -377 -187 1556 1159 -1536 -58 -1376 -407 -947 -348 411 1583 -762 253 524 -1911 52 8 1208 -870 -175 -1495 10 1148 1172 -73 -176 163 -200 198 670 400 428 -573 -371 -752 660 -365 437 752 107 1126 -139 -213 -347 -389 -1078 -759 234 -645 119 982 985 -133 626 -446 -894 900000 900000 -998 900000 -528 -1928 -349 900000 900000 900000 900000 900000 -748 -615 -639 -937 1283 537 471 -270 -51 -1982 732 614 394 272 265 80 -876 653 -1547 339 299 639 -1221 1021 80 -885 1331 -687 399 -1031 646 427 140 -487 131 71 106 1449 -790 954 -518 515 -252 -33 306 21 -497 -12 1341 612 1260 315 1720 320 555 221 307 -106 -170 1640 -1487 -103 -1069 204 -140 -644 -560 -1235 500 -548 -1147 -613 244 -331 -295 -151 1230 885 -1123 -39 -898 -269 -694 -291 391 1693 -900 295 574 -1955 48 8 1194 -929 -195 -1812 13 1556 1740 -115 -277 248 -286 282 949 592 643 -910 -590 -1168 1021 -550 624 1030 142 1523 -209 -342 -612 -730 -2134 -1579 513 -1510 284 2373 2390 -316 1402 -959 -1866 SS 20220624T113441.7Z 8210.482427 169 1 48.72 2 74.56 72.19 42.65 119.97 0.00 1 0.00 1 0 25 1.597e-01 8.700e-03 2.172e-01 8.800e-03 5.175058e-01 4.799333e-03 6.123317e-03 -6.000000e+00 9.545431e-02 232.87 -2.00 3.54 -2.00 320.62 0.00e+00 3.638695e-03 1.868115e-03 1.841633e-03 -6.000000e+00 4.262586e-03 285.81 -2.00 20.00 -2.00 319.95 0.00e+00 3.687 0.001 302.00 328.00 3 4.4834e+00 1.5110e-02 4.6269e-02 -6.0000e+00 2.3967e-01 3.2136e-02 1.8985e-02 2.9080e-02 -6.0000e+00 2.5900e-01 -4.1237e-02 1.6950e-02 1.5759e-02 -6.0000e+00 1.5296e-01 1.0112e-02 8.4570e-03 5.5979e-03 -6.0000e+00 6.4801e-02 8.6964e-05 3.9976e-04 2.7370e-04 7.7114e-05 -6.0000e+00 4.6046e-03 9.1231e-03 3.4697e-05 11 9 0 11 8 0 99.95 22.25 0.55 0.00912 0.01213 42 9 1 5 0 1159.780 26.21 20.00 22.25 27.90 12.2 1034.61 900000 -10154 -47201 66033 900000 -82966 900000 -49346 -67186 -43803 10343 -11858 -32512 5091 -20828 38824 20820 -15263 21208 -6841 13447 -28121 12811 -16486 37604 25662 -15653 -22133 40704 -17316 3112 6626 11057 -1667 -3982 1870 2498 10705 -2365 2814 -7052 -15 4494 3738 10220 -6714 1048 -5859 -7364 -545 -82 -2140 -3839 6601 860 3459 -133 802 3114 -41 1388 94 3448 3339 1293 2930 2090 -3275 2797 340 954 204 -3626 723 -1179 2963 -482 -2639 -1065 372 -1613 -460 -2290 -1580 1231 -777 1454 -412 1527 -1819 583 60 -877 226 126 -116 243 365 83 615 191 -1358 20 -796 -688 -2164 -1317 -128 220 1010 371 1147 22 611 96 -19 -689 206 -97 472 -323 -582 759 -293 881 -672 -31 469 1400 43 -117 -536 -446 -485 -454 526 -273 -63 172 240 434 -490 58 900000 -91 -607 566 900000 -1358 900000 -712 -1283 -700 106 -166 -697 93 -575 711 503 -552 595 -255 416 -1332 425 -787 1158 890 -823 -1197 1222 -969 165 390 701 -119 -277 131 187 880 -269 356 -1043 -2 658 564 1469 -1166 170 -1041 -1369 -100 -17 -485 -958 1594 231 933 -38 225 837 -11 398 30 1191 1265 510 1092 768 -1298 1144 156 476 107 -1949 367 -560 1218 -191 -1070 -468 187 -954 -291 -1601 -1161 942 -648 1245 -370 1346 -1594 464 44 -650 167 98 -103 246 416 101 748 220 -1451 20 -792 -733 -2478 -1576 -161 298 1484 597 1910 37 970 143 -28 -988 305 -154 777 -540 -953 1188 -446 1264 -941 -42 638 2061 71 -209 -1019 -883 -969 -966 1169 -629 -149 405 548 942 -1022 121 SS 20220624T114526.4Z 8210.489889 172 1 48.87 2 72.66 73.83 40.96 122.84 0.00 1 0.00 1 0 17 4.407e-02 5.168e-03 9.971e-03 5.508e-04 4.592866e-01 2.894098e-04 5.293841e-03 -6.000000e+00 2.608015e-02 232.87 -2.00 3.54 -2.00 319.82 0.00e+00 1.602344e-03 8.917009e-05 3.989798e-04 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