File name: Pandora39s1_DearbornMI_20220625_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T223430.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220625_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220625 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220625T112121.5Z 8211.473165 152 1 48.95 2 76.95 70.14 49.39 102.36 0.00 1 0.00 1 0 17 1.741e-01 4.964e-03 7.701e-02 1.712e-03 5.781761e-01 9.242039e-04 6.574501e-03 -6.000000e+00 1.030515e-01 232.87 -2.00 3.54 -2.00 320.87 0.00e+00 2.863009e-03 4.042558e-04 1.388531e-03 -6.000000e+00 4.514853e-03 285.91 -2.00 20.00 -2.00 320.23 0.00e+00 4.313 0.001 302.00 328.00 3 1.4537e+00 3.0236e-03 5.2833e-02 -6.0000e+00 2.5888e-01 -1.0397e-02 3.9856e-03 3.1945e-02 -6.0000e+00 2.7938e-01 -9.8541e-03 3.8253e-03 1.7276e-02 -6.0000e+00 1.6601e-01 -8.2910e-03 1.8630e-03 6.1642e-03 -6.0000e+00 7.0227e-02 9.6804e-04 3.1585e-04 5.1238e-05 7.6504e-05 -6.0000e+00 4.9209e-03 6.3035e-03 5.9486e-05 10 0 0 10 0 0 93.98 22.23 0.29 0.00630 0.00868 234 52 1 5 0 209.140 26.21 20.01 22.23 30.18 12.4 1048.71 -64350 -36998 -84871 -33697 -78201 -27069 -60562 -57804 -37707 -71040 -28435 -47330 -32288 -28231 -11372 -20616 -10988 -8096 -7678 -4837 -13409 6491 -11535 -4152 -10341 -7920 -9145 -13020 -12200 -9456 -1485 -5513 599 -8519 -6014 -6815 -4531 -4177 -2815 -246 -2401 -2259 -1444 1549 912 314 -508 -549 2203 -266 2697 263 1633 2259 2056 1323 1457 551 184 276 -16 2088 1645 2051 174 991 1006 -128 1811 796 868 841 330 -54 -79 -934 -880 -1587 -1012 -1177 -1214 -956 -2150 -1336 -292 -75 477 609 920 615 791 491 -65 -107 5 -408 268 904 142 -292 -224 -669 -701 191 -1016 -1524 -637 -641 -248 480 434 127 178 58 -101 167 395 162 284 -48 -433 186 408 183 144 347 -608 882 669 -163 73 -421 -220 -180 55 -262 -218 565 -34 -41 36 15 -210 -408 -204 -793 -180 -614 -131 -455 -482 -290 -818 -228 -537 -399 -386 -162 -379 -205 -162 -165 -107 -332 134 -305 -111 -315 -249 -294 -423 -394 -329 -56 -255 30 -484 -321 -376 -276 -304 -248 -23 -255 -256 -171 183 110 39 -65 -73 296 -39 430 48 319 476 458 309 349 133 44 65 -4 560 500 687 61 337 337 -45 685 348 417 422 165 -26 -34 -371 -327 -599 -421 -575 -689 -614 -1407 -921 -213 -58 389 511 770 498 596 375 -48 -80 4 -357 268 1020 174 -360 -261 -713 -691 187 -1081 -1727 -755 -811 -339 719 662 205 287 91 -160 251 593 253 437 -77 -708 294 624 292 219 507 -868 1270 1061 -269 132 -814 -444 -382 124 -587 -503 1321 -80 -94 85 34 -451 SS 20220625T113226.4Z 8211.480861 155 1 22.99 2 75.01 71.84 47.41 104.56 0.00 1 0.00 1 0 17 8.356e-02 5.028e-03 3.644e-02 1.491e-03 5.098358e-01 7.937535e-04 5.870565e-03 -6.000000e+00 4.943184e-02 232.87 -2.00 3.54 -2.00 320.14 0.00e+00 1.796190e-03 2.727252e-04 5.051867e-04 -6.000000e+00 2.166900e-03 285.91 -2.00 20.00 -2.00 319.44 0.00e+00 3.790 0.001 302.00 328.00 3 1.5178e+00 2.3739e-03 4.6289e-02 -6.0000e+00 1.2418e-01 -1.3810e-02 2.9130e-03 2.7488e-02 -6.0000e+00 1.3402e-01 -6.5247e-03 2.5150e-03 1.3865e-02 -6.0000e+00 7.9639e-02 -8.3391e-03 1.2805e-03 4.5487e-03 -6.0000e+00 3.3679e-02 1.5953e-03 1.3334e-05 4.4491e-05 5.0950e-05 -6.0000e+00 2.3618e-03 6.5498e-03 -2.5926e-05 12 1 1 12 9 1 99.22 22.23 0.24 0.00655 0.00665 119 57 1 5 0 190.160 26.21 20.00 22.23 31.03 12.4 1052.60 -25197 -40565 -16287 -37295 -40714 -25086 -24584 -14853 -22817 -18238 -23728 -16411 -6439 -9596 -10507 -14523 2371 -5387 2836 2322 -882 -2692 1450 -4459 -4979 -1662 -5430 -7361 -2028 -506 -579 1992 305 -3318 -1705 -3950 -2988 -2340 -1638 -1797 -1729 -1006 -1056 -1156 -202 -420 -186 1065 -1537 845 844 524 1446 1259 1028 653 680 -297 291 255 620 952 1939 2284 612 227 595 5 1136 1115 561 816 430 293 341 -865 -424 -1857 -255 -1102 -1234 -1066 -1979 -1449 -770 -425 90 526 666 940 669 1032 440 228 198 -367 300 632 122 -438 -315 -964 -334 442 -852 -1170 -832 -615 -250 501 322 252 -6 102 -113 172 447 201 587 -214 -484 37 368 49 196 399 -369 963 455 -100 -87 -256 -132 -43 112 -146 -158 499 -59 -169 19 -141 -187 -271 -520 -187 -499 -527 -285 -307 -192 -326 -265 -383 -282 -123 -235 -314 -520 79 -211 110 95 -38 -120 66 -234 -281 -95 -325 -432 -112 -30 -39 151 24 -283 -138 -334 -282 -262 -222 -287 -306 -188 -207 -231 -41 -86 -38 221 -338 192 211 145 430 404 348 212 227 -100 103 90 210 353 796 1023 285 102 260 2 553 619 344 520 273 177 190 -439 -199 -883 -131 -662 -855 -771 -1570 -1212 -686 -404 89 536 679 920 612 874 355 186 176 -373 323 765 160 -575 -390 -1099 -352 466 -976 -1425 -1063 -835 -341 744 521 426 -11 164 -170 246 638 298 924 -358 -819 61 587 76 289 562 -538 1409 684 -166 -149 -463 -248 -85 222 -306 -343 1095 -131 -366 39 -278 -378 SS 20220625T114307.8Z 8211.488285 158 1 21.45 2 73.13 73.47 45.53 106.77 0.00 1 0.00 1 0 17 5.084e-02 5.255e-03 1.866e-02 1.120e-03 4.595441e-01 5.883321e-04 5.326159e-03 -6.000000e+00 3.007893e-02 232.87 -2.00 3.54 -2.00 319.72 0.00e+00 1.367025e-03 1.746672e-04 5.205246e-04 -6.000000e+00 1.318063e-03 285.91 -2.00 20.00 -2.00 318.99 0.00e+00 3.392 0.001 302.00 328.00 3 1.3369e+00 1.7076e-03 4.1509e-02 -6.0000e+00 7.5562e-02 -1.3865e-02 2.0312e-03 2.4669e-02 -6.0000e+00 8.1547e-02 -5.4809e-03 1.6278e-03 1.2271e-02 -6.0000e+00 4.8456e-02 -7.6287e-03 8.4319e-04 3.7411e-03 -6.0000e+00 2.0497e-02 2.9409e-03 6.1173e-05 3.3386e-05 4.1613e-05 -6.0000e+00 1.4366e-03 5.3663e-03 -2.6211e-06 12 1 1 12 1 1 99.74 22.23 0.23 0.00537 0.00583 197 101 1 5 0 107.450 26.21 19.99 22.23 31.41 12.4 1055.76 -15054 -20952 -11898 -20445 -14347 -23301 -11212 -13856 -10893 -16280 -14622 -11922 -14430 -6743 -7537 -1492 -3177 -1976 -692 -674 -1189 -2737 -1691 -3943 -1780 -1351 -1886 -4543 -2491 -586 -448 521 -32 -2529 -2999 -2669 -3298 -786 -876 -1918 -1002 -1382 -240 -1643 349 -483 416 -82 -642 563 799 436 1246 1289 793 1068 297 436 305 772 1131 1544 2054 1772 426 371 734 -292 1356 941 231 757 258 669 37 -238 -654 -1011 -448 -1053 -1264 -983 -1909 -1459 -602 -495 212 344 800 627 562 713 -278 209 135 -26 367 764 -61 -432 -299 -896 -481 318 -769 -1647 -839 -567 -186 495 336 121 78 108 -69 314 450 226 441 -101 -391 18 407 66 379 419 -209 992 672 -190 11 -269 -187 -50 87 -215 -193 577 -43 -150 -13 -190 -314 -239 -393 -210 -369 -226 -409 -193 -278 -237 -396 -363 -324 -487 -256 -345 -73 -172 -115 -42 -39 -71 -169 -109 -281 -133 -105 -147 -348 -183 -45 -39 51 -3 -293 -334 -302 -421 -116 -158 -410 -234 -344 -62 -435 91 -129 111 -22 -178 162 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