File name: Pandora39s1_DearbornMI_20220630_L2Fit_fout2c4d20210608p1-8.txt File generation date: 20250217T223511.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 39 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora39_OF_v3d20200924.txt Instrument calibration file used: Pandora39s1_CF_v4d20210608.txt Level 1 file used: Pandora39s1_DearbornMI_20220630_L1_smca1c4d20210608p1-8.txt Full location name: Dearborn MI - Salina Elementary School (AQS-26-163-0033) Short location name: DearbornMI Country of location: USA Location latitude [deg]: 42.3067 Location longitude [deg]: -83.1488 Location altitude [m]: 181 Local noon date: 20220630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.1016 305.2419 305.3822 305.5225 305.6628 305.8031 305.9434 306.0837 306.2239 306.3642 306.5044 306.6446 306.7848 306.9250 307.0652 307.2054 307.3455 307.4857 307.6258 307.7659 307.9061 308.0462 308.1862 308.3263 308.4664 308.6064 308.7465 308.8865 309.0265 309.1665 309.3065 309.4465 309.5865 309.7264 309.8664 310.0063 310.1462 310.2861 310.4260 310.5659 310.7058 310.8456 310.9855 311.1253 311.2651 311.4049 311.5447 311.6845 311.8243 311.9641 312.1038 312.2435 312.3833 312.5230 312.6627 312.8024 312.9420 313.0817 313.2214 313.3610 313.5006 313.6402 313.7799 313.9194 314.0590 314.1986 314.3381 314.4777 314.6172 314.7567 314.8962 315.0357 315.1752 315.3147 315.4542 315.5936 315.7330 315.8725 316.0119 316.1513 316.2906 316.4300 316.5694 316.7087 316.8481 316.9874 317.1267 317.2660 317.4053 317.5445 317.6838 317.8231 317.9623 318.1015 318.2407 318.3799 318.5191 318.6583 318.7974 318.9366 319.0757 319.2149 319.3540 319.4931 319.6322 319.7712 319.9103 320.0494 320.1884 320.3274 320.4664 320.6054 320.7444 320.8834 321.0224 321.1613 321.3003 321.4392 321.5781 321.7170 321.8559 321.9948 322.1336 322.2725 322.4113 322.5501 322.6890 322.8278 322.9666 323.1053 323.2441 323.3828 323.5216 323.6603 323.7990 323.9377 324.0764 324.2151 324.3538 324.4924 324.6311 324.7697 324.9083 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220630T114233.3Z 8216.487885 97 1 6.75 2 73.55 73.40 84.14 60.97 0.00 1 0.00 1 0 25 1.867e-01 1.643e-02 2.163e-01 1.458e-02 4.739158e-01 7.665583e-03 5.793397e-03 -6.000000e+00 1.105561e-01 232.88 -2.00 3.54 -2.00 319.75 0.00e+00 2.539489e-03 2.297511e-03 2.332789e-03 -6.000000e+00 4.850067e-03 286.37 -2.00 20.00 -2.00 319.02 0.00e+00 3.474 0.001 302.00 328.00 3 4.5660e+00 2.2227e-02 4.3391e-02 -6.0000e+00 2.7770e-01 1.6972e-02 2.6423e-02 2.7593e-02 -6.0000e+00 2.9961e-01 -6.6728e-02 2.0711e-02 1.3779e-02 -6.0000e+00 1.7808e-01 2.1717e-02 1.0694e-02 3.9217e-03 -6.0000e+00 7.5406e-02 1.0549e-04 9.8038e-04 4.3176e-04 5.7276e-05 -6.0000e+00 5.2755e-03 4.3606e-03 1.2774e-04 12 9 9 12 1 1 999.00 22.22 0.02 0.00436 0.01173 1 3 1 5 0 3290.910 26.21 20.00 22.22 28.53 12.4 1034.35 -72353 -43112 60858 -24111 -6098 -91420 -53860 50653 -31850 -13313 -96637 -9003 -27800 -10606 -18513 37302 -29923 -29763 -8027 9056 -23362 279 21150 13951 18814 -11899 13814 -21747 2035 -9130 -26111 41868 -13201 11408 15934 392 -1328 22163 3320 11425 -140 -6906 13709 -8724 -7982 5315 9926 7387 -4280 4678 1449 792 -2852 5752 5309 4121 2711 -763 -990 6169 171 835 597 2533 401 328 4576 821 -1390 1953 3401 1820 -1287 1109 3442 2183 -2540 2839 -3415 -28 -1259 -3627 -4684 -139 1960 -137 -2148 1564 -724 -764 -174 -1141 -2513 -1535 -1035 -457 213 1400 -882 -736 -623 -3406 2006 1728 -2780 -1337 -322 -494 508 418 -229 1261 356 -12 -623 -279 1895 2071 -931 941 349 2015 1161 -1480 940 -666 853 413 489 -398 1550 -440 379 -328 -1304 60 -392 -426 -228 214 843 -40 -1034 -2181 -1124 865 -500 -102 -3327 -1531 720 -906 -331 -5284 -251 -1091 -428 -931 1273 -2094 -2246 -518 515 -1865 18 1191 870 1183 -1060 952 -2045 148 -794 -2956 2839 -1668 1204 1533 45 -166 2702 570 2117 -31 -1729 2909 -2361 -2168 1282 2298 1774 -1180 1240 433 261 -1015 2013 1952 1582 1078 -312 -398 2304 71 375 289 1312 216 169 2186 413 -780 1167 2194 1243 -899 720 2078 1203 -1360 1478 -1994 -18 -923 -2962 -4060 -122 1803 -134 -2247 1625 -772 -784 -170 -1045 -2272 -1376 -972 -468 240 1706 -1181 -979 -781 -4144 2216 1935 -3401 -1661 -417 -662 723 633 -369 2080 586 -18 -949 -412 2735 3026 -1451 1519 575 3197 1853 -2337 1381 -980 1190 587 733 -645 2594 -793 687 -611 -2553 123 -810 -897 -484 439 1680 -78 -1992 SS 20220630T114933.0Z 8216.492743 101 1 18.82 2 72.31 74.47 83.04 62.04 0.00 1 0.00 1 0 17 1.557e-01 8.947e-03 1.424e-01 7.003e-03 4.613458e-01 3.700796e-03 5.408625e-03 -6.000000e+00 9.213294e-02 232.88 -2.00 3.54 -2.00 319.80 0.00e+00 3.188387e-03 1.124802e-03 7.559567e-04 -6.000000e+00 4.045183e-03 286.37 -2.00 20.00 -2.00 319.06 0.00e+00 3.245 0.001 302.00 328.00 3 4.5768e+00 1.0782e-02 4.0508e-02 -6.0000e+00 2.3142e-01 4.9208e-02 1.2832e-02 2.4781e-02 -6.0000e+00 2.4973e-01 -4.9599e-02 1.0181e-02 1.2740e-02 -6.0000e+00 1.4843e-01 1.1031e-02 5.2651e-03 4.6212e-03 -6.0000e+00 6.2809e-02 1.2705e-04 -5.7167e-04 2.0975e-04 5.2130e-05 -6.0000e+00 4.4006e-03 6.6326e-03 2.5708e-05 12 9 1 12 1 1 99.90 22.22 0.46 0.00663 0.00234 6 4 1 5 0 2664.310 26.21 20.00 22.22 28.85 12.6 1036.47 73212 455 -47497 -49852 -37335 -36994 -51657 88682 12350 7039 -53431 -41062 26754 3098 5879 -22820 39781 -3099 5326 15118 -12474 -1934 -13375 -1139 -12760 11749 -4420 1603 -16565 -4929 -4549 11748 1067 -2782 -2287 -11923 -9265 -8060 2769 -5541 6298 5292 -2265 -2218 645 1631 873 3309 901 -640 1729 1182 2999 2447 -1015 -1425 4310 1583 3424 -287 1776 2251 2962 2841 -574 1578 327 -271 3087 1081 893 713 -1856 -403 -311 -2792 762 -1460 -313 -1457 -548 -2609 -2213 -1014 -900 -464 -134 1369 807 694 542 -899 -696 -878 -516 -1048 645 400 201 -733 263 -739 574 -118 -728 -727 -1528 -280 237 519 564 -18 -109 413 234 544 802 -752 481 19 373 201 220 -309 527 -216 -119 1099 845 801 -495 -393 -924 -502 242 -193 136 864 -146 -322 -35 42 -428 565 8 -1298 -1307 -829 -821 -1383 711 225 142 -1956 -1492 624 107 238 -1349 1424 -184 308 830 -881 -123 -1001 -80 -1069 835 -355 121 -1410 -397 -416 1037 117 -327 -255 -1478 -1246 -1264 471 -1153 1283 1152 -555 -554 158 402 218 813 231 -174 501 376 1009 886 -397 -576 1679 630 1311 -114 718 988 1384 1447 -308 790 160 -135 1608 653 593 477 -1265 -267 -190 -1575 383 -740 -170 -920 -379 -2070 -1894 -906 -830 -455 -138 1432 851 707 514 -828 -602 -757 -478 -1064 730 496 260 -953 330 -860 633 -132 -850 -900 -2004 -373 336 797 908 -30 -181 653 358 785 1146 -1132 737 30 612 325 345 -485 781 -309 -168 1549 1251 1262 -852 -694 -1697 -959 473 -401 283 1817 -313 -675 -72 83 -838 SS 20220630T115440.2Z 8216.496298 104 1 36.17 2 71.40 75.25 82.24 62.81 0.00 1 0.00 1 0 17 7.287e-02 7.237e-03 7.544e-02 4.625e-03 4.286421e-01 2.437573e-03 5.002814e-03 -6.000000e+00 4.311523e-02 232.88 -2.00 3.54 -2.00 319.77 0.00e+00 3.147319e-03 7.261007e-04 4.898497e-04 -6.000000e+00 1.892973e-03 286.37 -2.00 20.00 -2.00 319.03 0.00e+00 3.095 0.001 302.00 328.00 3 4.5018e+00 7.0828e-03 3.8209e-02 -6.0000e+00 1.0830e-01 7.4634e-04 8.4079e-03 2.3028e-02 -6.0000e+00 1.1686e-01 -1.3497e-02 6.6246e-03 1.1809e-02 -6.0000e+00 6.9462e-02 -2.0755e-03 3.4293e-03 4.6692e-03 -6.0000e+00 2.9394e-02 1.6753e-04 1.1937e-04 1.4097e-04 4.9566e-05 -6.0000e+00 2.0593e-03 6.0136e-03 1.1281e-05 12 9 1 12 1 1 92.81 22.22 0.28 0.00601 0.00691 13 4 1 5 0 2570.770 26.21 20.00 22.22 28.89 12.5 1036.20 18141 -7806 -33881 10456 12394 -17343 -32990 26596 -35900 16233 -4798 671 -5557 9548 -6572 -22041 -8383 -4345 -5496 -4258 2195 -9840 12997 1786 1111 -1881 -8667 -3300 -8159 10105 502 4492 4547 5293 -4468 -9375 -7400 -5087 5580 -2438 816 -3745 1208 -2267 54 -1259 1671 -2430 -1611 2396 213 3409 191 3702 858 2226 494 -1140 -197 247 1612 814 1085 2457 624 294 178 593 1735 1091 423 839 -170 1567 -1888 723 -342 -1153 -782 -1577 -458 -921 -2777 -2235 -178 -299 277 548 1213 504 307 1300 -151 492 -357 -118 398 297 157 -745 -229 -1006 -289 94 -860 -995 -1130 -1091 -419 652 848 -104 -144 102 -154 678 675 -43 765 -362 -327 -322 649 134 356 207 403 903 904 -194 48 175 -581 217 -376 3 -48 528 -56 -421 171 -264 -336 260 -154 -891 172 185 -336 -812 422 -1127 331 -119 18 -188 337 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